The chemical composition and sources of the bulk deposition on Lake Kinneret (The Sea of Galilee), Israel

The chemical composition of the bulk deposition into Lake Kinneret, Israel was determined for the three hydrological years from 1992 to 1995. The fluxes of the elements and ions in the bulk deposition around the lake are fairly uniform although some local effects due to anthropogenic activity are observed; temporal effects are more pronounced. Na and Cl fluxes are greatly affected by rainfall that has passed over the Mediterranean Sea whilst Ca fluxes increase during dust storm episodes. The amount of each of the determined constituents entering the lake was calculated. The major chemical constituent entering the lake (except Ca) is SO₄ whose main source is long-range transport from Europe. Enrichment factor analysis shows that the insoluble portion of the bulk deposition has the same characteristics as regional (and Saharan) dust storms, whilst the soluble portion is strongly affected by the marine environment. Significant additions to the previously known input of nitrogen and phosphorous enter the lake due to bulk deposition: 10% for nitrogen and 40% for phosphorous. The Pb content of the lake sediments correlates with Pb usage in petrol. Full experimental results are given in the electronic appendices.     

Lead and strontium isotopes as monitors of experimental granitoid mineral dissolution

Flow-through dissolution experiments were carried out on crushed granitoid rock (the Elat Granite) and three mineral separates (plagioclase, perthite, and biotite + chlorite) from this rock at pH 1 and 25°C. Major element concentrations were combined with Pb and Sr isotopic analyses of starting materials and output solutions and together enabled us to elucidate several important mechanisms related to granitoid rock weathering. We observed an initial stage of rock dissolution (<200 hours of reaction) that was characterized by elemental release from traces of calcite and/or apatite and to a lesser extent from the interlayer sites of biotite. Dissolution in the interval of 200 to 400 h was dominated by the release of elements from the interlayer sites of biotite, and at 400 to 1000 h of reaction the chemistry of output solutions was dominated by the release of elements from tetrahedral and octahedral sites of biotite as well as from plagioclase. After 1000 h, the dissolution of plagioclase, and to a lesser extent biotite, dominated the composition of elements released by the rock. We demonstrate that Pb and Sr isotope ratios in the output solutions can be used to identify each of these stages of dissolution. By comparing our experimental results on the release of Pb and Sr isotopes with field measurements of Pb and Sr isotopes in soil chronosequences from the Wind River and the Sierra Nevada Mountains (USA), we are able to show that similar isotopic patterns appear in both the pH 1 experiments and in soils formed under natural conditions at higher pH. By combining these experimental results with previous field studies, we are able to estimate the duration of most of these stages of granitoid weathering under natural conditions in temperate climates. In soils older than a few hundred years and younger than 10,000 yr the release of elements from interlayer sites of biotite controls the weathering flux. Soils between 10,000 and 100,000 yr old are dominated by biotite and plagioclase weathering, with biotite weathering controlling the first part of this period and plagioclase dominating the later part. After more than 100,000 yr, plagioclase, and to a lesser degree biotite, dominate the weathering flux within these granitoid soils.     

Kinetics of gypsum crystal growth from high ionic strength solutions: A case study of Dead Sea - seawater mixtures

Gypsum precipitation kinetics were examined from a wide range of chemical compositions , ionic strengths (4.75-10 m) and saturation state with respect to gypsum (1.16-1.74) in seeded batch experiments of mixtures of Ca²⁺-rich Dead Sea brine and -rich seawater. Despite the variability in the experimental solutions, a single general rate law was formulated to describe the heterogeneous precipitation rate of gypsum from these mixtures:

     

Trapping of airborne dust by mosses in the Negev Desert,Israel

Airborne silt and clay containing calcium carbonate, quartz, clays, marine nannoplankton, and aquatic diatoms are trapped among stems of mosses in the Negev Highlands Desert. The mosses were studied in an area with 70 mm mean annual rainfall. They grow over the particles covering them and trap additional dust as it comes, resulting in the accumulation of loess sediments. The mosses protect the accumulated soil from erosion by wind or water. Remnants of the moss leaves and stems were found at a depth of 15 mm and more. No particles or minerals typical to basalt were found in the moss-trapped soil. The function of cushiony mosses may be used to explain the processes of loess trapping and protection in larger areas in moister areas such as the Northern Negev. Microscopic fossils in the dust may be used as guides to the origin of the (aeolian) sediments.     

Environmental dust: A tool to study the patina of ancient artifacts

Dust is a significant, albeit under-recognized, component of ancient patinas that accumulates on exposed surfaces of artifacts. Dust storms are ubiquitous in the Levant; however, often unnoticed substances such as minerals, microfossils and pollen can be found within the patina of an artifact, preserving its geological signature. Modern anthropogenic aerosol sources are often characterized by the presence of heavy metals. Pollen from fruits and shrubs that are not indigenous, if found in the patina, can be used to differentiate recent artifacts from those of antiquity. Archaeological materials that are exposed to local environmental and depositional processes in a tel, a cave or soil, may accrete in a patina over time and may have some dust components reflective of the environmental record. The scores of unprovenanced looted antiquities have necessitated the need to differentiate a genuine artifact from a modern fraud. Since the geological component of the dust in the Levant is known, and the climate and its attendant wind patterns apparently were quite constant during recent millennia times, the dust in the patinas of a true artifact is easy to differentiate from patinas containing modern dust. Both contemporary and historical dust can serve as tools to authenticate an artifact.     

Quartz precipitation kinetics at 180°C in NaCl solutions—Implications for the usability of the principle of detailed balancing

The kinetics of heterogeneous quartz precipitation were determined at 180°C and a pH near 4 as a function of the degree of super saturation and dissolved NaCl concentrations. Stirred batch reactors were used and the changes in H₄SiO₄ concentrations over time were used to model the reaction rates. As the change in concentration in the batch experiment is not linear with time during all sampling intervals, the precipitation rates were retrieved by fitting the experimental observations to a forward model, i.e., a model that uses a prescribed rate law and compares the results with the experiments. Quartz precipitation occurs via an overall reaction, and therefore one can not presuppose the applicability of the predictions of Transition State Theory (TST). Therefore, different functions describing the dependence of the rate on deviation from equilibrium were examined in the forward model. The obtained precipitation rates were within error the same, regardless of the function that was used.By substituting the prediction of TST into the forward model, the change of quartz precipitation rate (at 180°C, pH 4 and ionic strength of 0.1M) with deviation from equilibrium was found to be

     

The dissolution kinetics of a granite and its minerals—Implications for comparison between laboratory and field dissolution rates

The present study compares the dissolution rates of plagioclase, microcline and biotite/chlorite from a bulk granite to the dissolution rates of the same minerals in mineral-rich fractions that were separated from the granite sample. The dissolution rate of plagioclase is enhanced with time as a result of exposure of its surface sites due to the removal of an iron oxide coating. Removal of the iron coating was slower in the experiment with the bulk granite than in the mineral-rich fractions due to a higher Fe concentration from biotite dissolution. As a result, the increase in plagioclase dissolution rate was initially slower in the experiment with the bulk granite. The measured steady state dissolution rates of both plagioclase (6.2 ± 1.2 × 10⁻¹¹ mol g⁻¹ s⁻¹) and microcline (1.6 ± 0.3 × 10⁻¹¹ mol g⁻¹ s⁻¹) were the same in experiments conducted with the plagioclase-rich fraction, the alkali feldspar-rich fraction and the bulk granite.Based on the observed release rates of the major elements, we suggest that the biotite/chlorite-rich fraction dissolved non-congruently under near-equilibrium conditions. In contrast, the biotite and chlorite within the bulk granite sample dissolved congruently under far from equilibrium conditions. These differences result from variations in the degree of saturation of the solutions with respect to both the dissolving biotite/chlorite and to nontronite, which probably was precipitating during dissolution of the biotite and chlorite-rich fraction. Following drying of the bulk granite, the dissolution rate of biotite was significantly enhanced, whereas the dissolution rate of plagioclase decreased.The presence of coatings, wetting and drying cycles and near equilibrium conditions all significantly affect mineral dissolution rates in the field in comparison to the dissolution rate of fully wetted clean minerals under far from equilibrium laboratory conditions. To bridge the gap between the field and the laboratory mineral dissolution rates, these effects on dissolution rate should be further studied.