The influence of aerosol particle composition on cloud droplet formation

A difference in partitioning between cloud droplets and interstitial air for two chemical species (elemental carbon and sulphur) with different expected behaviour in nucleation scavenging was observed in clouds at Mt. Kleiner Feldberg (825 m asl), near Frankfurt, Germany. The fraction of sulphur incorporated in cloud droplets was always higher than the fraction of elemental carbon. This difference in partitioning has also been observed in fog but under different pollution conditions in the Po Valley, Italy. Both these studies were based on bulk samples. In the present study at Kleiner Feldberg, impactor samples of the particles in the interstitial air and the cloud droplet residuals were taken and a single particle analysis was done on the samples. It was found that, for a given particle size, the majority of particles forming cloud droplets were soluble and that insoluble particles preferentially remained in the interstitial air.     

Atlantic watermass and circulation response to persistent freshwater forcing in two coupled general circulation models

The sensitivity of the Atlantic circulation and watermasses to biases in the convergence of moisture into the basin is examined in this study using two different general circulation models. For a persistent positive moisture flux into the tropical Atlantic, the average salinity and temperature in the basin is reduced, mainly below mid-depths and in high latitudes. A transient reduction in the Atlantic overturning strength occurs in this case, with a recovery timescale of 1–2 centuries. In contrast, a similar amount of freshwater directed into the Subpolar North Atlantic results in a persistent reduction in overturning and an increase in basin heat and salt content. In the unperturbed pre-industrial simulations, the Atlantic is unambiguously warmer and saltier than historical observations below mid-depths and in the Nordic Seas. The models’ tropical freshwater flux sensitivities project strongly onto the spatial pattern of this bias, suggesting a common atmospheric deficiency. The integrated Atlantic plus Arctic surface freshwater flux in these models is between ?0.5 and ?0.6 Sv, compared with an observational estimate of ?0.28 Sv. Our results suggest that shortcomings in the models’ ability to reproduce realistic bulk watermass properties are due to an overestimation of the inter-basin moisture export from the tropical Atlantic.     

A geochemical aid to igneous rock type identification in deeply weathered terrain

A technique employing Ti, Zr and Cr to aid in the identification of primary igneous rock type in deeply weathered situations is described. The method is based on Ti/Zr ratio which is little affected either by primary alteration or weathering and adequately defines compositional fields for major igneous rock types. For volcanic rocks Ti/Zr ratios are rhyolite <4< dacite <12< andesite <60< basalt. Ultramafic rocks cannot be discriminated from mafic rocks by Ti/Zr ratio but are generally distinguished by high Cr.     

Numerical simulations of the Mediterranean sea outflow: impact of the entrainment parameterization in an isopycnic coordinate ocean model

Gravity current entrainment is essential in determining the properties of the interior ocean water masses that result from marginal sea overflows. Although the individual entraining billows will be unresolvable in large-scale ocean models for the foreseeable future, some large-scale simulations are now being carried out that do resolve the intermediate scale environment which may control the rate of entrainment. Hallberg [Mon. Wea. Rev. 128 (2000) 1402] has recently developed an implicit diapycnal mixing scheme for isopycnic coordinate ocean models that includes the Richardson number dependent entrainment parameterization of Turner [J. Fluid Mech. 173 (1986) 431], and which may be capable of representing the gravity current evolution in large-scale ocean models. The present work uses realistic regional simulations with the Miami Isopycnic Coordinate Ocean Model (MICOM) to evaluate ability of this scheme to simulate the entrainment that is observed to occur in the bottom boundary currents downstream of the Mediterranean outflow. These simulations are strikingly similar to the observations, indicating that this scheme does produce realistic mixing between the Mediterranean outflow and the North Atlantic Central Water. Sensitivity studies identify the critical Richardson number below which vigorous entrainment occurs as a particularly important parameter. Some of these experiments also show meddies detaching from the Mediterranean undercurrent at locations that appear to be highly influenced by topographic features.     

Authigenic carbonate mineral formation in the Pagassitikos palaeolake during the latest Pleistocene, central Greece

The Pagassitikos Gulf in Greece is a semi-enclosed bay with a maximum depth of 102 m. According to the present-day bathymetric configuration and the sea level during the latest Pleistocene, the gulf would have been isolated from the open sea, forming a palaeolake since ~32 cal. ka b.p. Sediment core B-4 was recovered from the deepest sector of the gulf and revealed evidence of a totally different depositional environment in the lowest part of the core: this contained light grey-coloured sediments, contrasting strongly with overlying olive grey muds. Multi-proxy analyses showed the predominance of carbonate minerals (aragonite, dolomite and calcite) and gypsum in the lowest part of the core. Carbonate mineral deposition can be attributed to autochthonous precipitation that took place in a saline palaeolake with high evaporation rates during the last glacial–early deglacial period; the lowest core sample to be AMS ¹⁴C dated provided an age of 19.53 cal. ka b.p. The palaeolake was presumably reconnected to the open sea at ~13.2 cal. ka b.p. during the last sea-level rise, marking the commencement of marine sedimentation characterised by the predominance of terrigenous aluminosilicates and fairly constant depositional conditions lasting up to the present day.     

南海南部SA09-040孔孢粉记录及古气候

依据南海低纬地区SA09-040孔高分辨率的孢粉记录,自下至上划分了4个孢粉组合带。从孢粉成分的变化,重建了22.25ka B P以来的植被与气候变化历史。结果表明:孢粉主要来源于婆罗洲和周围岛屿,孢粉1带(22.25～16.6ka B P),低山雨林植被发育,为暖热气候,从测年时间看,当时为末次冰期晚期。孢粉2带(16.6～10.82ka B P,为末次冰消期),植被以热带低山雨林和低地雨林为主,针叶的松数量较多,当时的气温比现在低。孢粉3带(全新世早期,10.82～6.43ka B P),植被以热带低山雨林和低地雨林为主,针叶松属数量减少,气温比前期升高,海平面也上升。孢粉4带(全新世中晚期,6.43ka B P至今),全新世中期为炎热、湿润的气候环境,全新世晚期可能与婆罗洲现今的植被景观相近,为热、湿的气候环境。     

Unusual nickel mineralisation at Nullagine,Western Australia

Nickel mineralisation occurs in shears in Archaean serpentinised peridotite near Nullagine, Western Australia. The principal nickel minerals are millerite, polydymite and pecoraite, which occur chiefly as concentrations of nodular grains, mostly between 1 and 5 mm in diameter. The polydymite represents a replacement of millerite, and is in turn partly replaced by gaspéite. The pecoraite grains generally contain several percent chromium, and are frequently rimmed by millerite‐containing magnetite. A similar type of nodule consists of nullaginite (Ni₂(OH)₂CO₃). Other major minerals in the shears include various types of serpentine and magnesite, coarse chlorite, and apatite. The assemblage is cut by late veinlets of gaspéite, pecoraite, otwayite (Ni₂(OH)₂CO₃.H₂O), and nullaginite. Trace amounts of barite, cinnabar, parkerite, shandite, breithauptite, and nickeloan greenockite are also present.

The bulk of the mineralisation is attributed to the effects of hydrothermal and/or metasomatic activity along shears in the serpentine. Concretionary magnesite in some of the shears is believed to be the result of Tertiary weathering. The late veinlets of nickel minerals and the replacement of millerite and polydymite are attributed to supergene effects.     

大兴安岭中南段中生代成矿物质的深部来源与背景

大兴安岭是我国北方一个重要的多金属成矿带。本文从成矿的物质来源和构造作用两方面讨论大兴安岭的成矿系统。Sr、Nd、O、Pb同位素的研究显示大兴安岭成矿物质的深部来源,大兴安岭晚中生代壳幔混熔花岗质岩石组成及其构造环境的研究,表明它们是在板内非造山的伸展环境下形成的A型花岗岩。与南岭花岗岩及其成矿作用的对比研究,将加深对大兴安岭中生代成矿特征的认识。深部构造特征也进一步印证了大兴安岭的成岩-成矿的背景。     

Do predatory fish of benthic crustaceans vary between kelp and barren reef habitats in northeastern New Zealand?

Fish assemblages that included known predators of benthic crustaceans were compared between kelp and barren habitats in northeastern New Zealand using baited underwater video census methods. The benthic-feeding fish were observed in winter, spring/summer and autumn, as well as during night-time in spring/summer. Overall, the fish assemblages varied between barren and kelp habitat, being most marked in winter. Individual benthic-feeding species, such as grey mao mao (Scorpis lineolatus) and leatherjacket (Meuschenia scaber) were associated with barren habitat, while the spotted wrasse (Notolabrus celidotus) was more strongly associated with kelp habitat. The results suggest that changes in habitats on coastal reefs affect populations of species that are benthic predators, which may in turn influence the distribution and abundance of their prey species, such as juvenile spiny lobsters.