Etude des inclusions fluides du système N2-CO2 de dolomites et de quartz de Tunisie septentrionale. Données de la microcryoscopie et de l'analyse à la microsonde à effet Raman

Optical and analytical studies were performed on 400 N₂ + CO₂ gas bearing inclusions in dolomites and quartz from Triassic outcrops in northern Tunisia. Other fluids present include brines (NaCl and KCl bearing inclusions) and rare liquid hydrocarbons. At the time of trapping, such fluids were heterogeneous gas + brine mixtures. In hydrocarbon free inclusions the $\text{N}{}_2\text{(N}{}_2\text{+ CO}{}_2\text{)}$ mole ratio was determined using two different non-destructive and punctual techniques: Raman microprobe analysis, and optical estimation of the volume ratios of the different phases selected at low temperatures. In the observed range of compositions, the two methods agree reasonably well.The N₂ + CO₂ inclusions are divided into three classes of composition: (a) $\text{N}{}_2\text{(N}{}_2\text{+ CO}{}_2\text{)}\text{> 0,57}$: Liquid nitrogen is always visible at very low temperature and homogenisation occurs in the range ?151°C to ? 147°C (nitrogen critical temperature) dry ice (solid CO₂) sublimates between ?75°C and ?60°C; (b) $\text{0,20 <}\text{N}{}_2\text{(N}{}_2\text{+ CO}{}_2\text{)}\text{? 0,57}$: liquid nitrogen is visible at very low temperature but dry ice melts on heating; liquid and gas CO₂ homogenise to liquid phase between ?51°C to ?22°C; (c) $\text{N}{}_2\text{(N}{}_2\text{+ CO}{}_2\text{)}\text{? 0,20}$: liquid nitrogen is not visible even at very low temperature (?195°C) and liquid and gas CO₂ homogenise to liquid phase between ?22°C and ?15°C. The observed phases changes are used to propose a preliminary phase diagram for the system CO₂-N₂ at low temperatures.Assuming additivity of partial pressures, isochores for the CO₂-N₂ inclusions have been computed. The intersection of these isochores with those for brine inclusions in the same samples may give the P and T of trapping of the fluids.     

Analysis of Standard Reference Materials for Zr,Nb, Hf and Ta by ICP-MS after Lithium Metaborate Fusion and Cupferron Separation*

Results are presented of the determination of Zr, Nb, Hf and Ta in 74 standard reference materials by inductively coupled plasma mass spectrometry (ICP-MS). Samples are decomposed by fusion with lithium metaborate and the analytes are separated prior to analysis by precipitation of their cupferrates. Calibration is made using synthetic solutions and internal standardization with Ru (for Zr and Nb) and Re (for Hf and Ta). Accuracy is assessed by comparison with recommended values and precision is evaluated by replicate analyses of five SRMs.     

Radiation-enhanced release of uranium from accessory minerals in crystalline rocks

Implantation of low energy (~ 1 keV/amu) Pb ions, simulating α-recoils, greatly increases the dissolution rate of U-bearing minerals in aqueous solutions above a critical dose $\text{~5 × 10}{}^{12}\text{ions·cm}{}^{\mathrm{?2}}$. A Monte-Carlo code of etching indicates that this phenomenon corresponds to a percolation threshold due to the accumulation of ion-induced defects above a critical concentration. Such a radiationenhanced dissolution could be produced by α-recoil damage in U-rich accessory minerals of sufficient U-content and/or age. Therefore, this process could be the primary source of this element in the formation of U ores associated with crystalline rocks.     

Dual-porosity elastoplastic analyses of non-isothermal one-dimensional consolidation

A numerical solution, using the finite difference method, and based on a porothermo-elasto-plastic formulation for dual-porosity one-dimensional consolidation has been presented. The model is fully coupled to ensure the interactive behavior of fluid flow, heat flow and solid deformations in the conservation of momentum, mass and energy equations. A bi-linear stress-strain relationship is used to accommodate elastoplastic deformation behavior. A double effective stress law, proposed by Elsworth and Bai (1992), is applied to describe constitutive relationships among the stresses, pressures and temperatures. In order to examine the dual-porosity and thermal effects on the soil consolidation individually, isothermal and non-isothermal consolidations for a dual-porosity column are analyzed. In comparison to the single porosity approach, the present study shows that the pore pressure dissipation is faster and Mandel's effect (Mandel, 1953) is more pronounced at early times of the source disturbance for dual-porosity consolidation. One of the significant parameters affecting the dual-porosity consolidation is the fracture spacing (fracture density); the smaller the fracture spacing, the faster the column drainage.     

Quaternary strike-slip faults in southeastern spain

The Gibraltar Arc (Western Mediterranean Sea) is traversed by a NE-trending fault system that extends from northern Morocco to southeastern Spain. In this area, three main faults (the Carboneras, Palomares and Alhama de Murcia faults) have been active in Quaternary time. The faults are characterized by left-lateral strike-slip motion. The Quaternary faulting and current seismicity in this part of the Meditterranean area are related to a collision-type tectonics produced by the northwestward relative motion of the African Plate toward the European Plate.     

The Kenna ureilite: an ultramafic rock with evidence for igneous,metamorphic, and shock origin

The Kenna ureilite was found in February, 1972 near the town of Kenna, Roosevelt County, New Mexico U.S.A., weighed 10.9 kg, and measured 26.7 × 14.7 × 14.2 cm; it is the seventh known ureilite. The meteorite is composed of xenoblastic olivine (Fo_79.2), commonly rimmed by forsterite (Fo₉₉), and pigeonite (En₇₃Wo₉Fs₁₈), in a volumetric ratio of 3:1, set in a matrix of three carbon polymorphs (graphite, lonsdaleite, and diamond) plus nickel-iron metal and troilite. Some thin metalliferous veins penetrating silicate grains contain secondary inclusions of melt with high-calcium clinopyroxene (high-Ca, Mg-rich augite to augite), andesine, K-feldspar, chromite, and siliceous CaO- and alkali-rich glasses of variable compositions.Textural, mineralogical and fabric information suggest a complex history for Kenna, involving igneous, metamorphic and shock processes. The rock appears to have originated as an ultramafic cumulate whose texture and structure was modified by adcumulus processes and by solution and redeposition in a weak deviatoric stress field. A strong mineral elongation lineation was produced during this high-temperature phase accompanied by mild plastic deformation of olivine on the system 0kl[100]. Superimposed on this original texture and fabric are processes resulting from light to moderate (50–250 kbar) shock deformation, as manifested by fracturing of the silicates, slip parallel to (001) in olivine, and twin and translation gliding parallel to (100) in the clinopyroxene. Lonsdaleite and diamond probably formed during this shock phase, which may be associated with the break-up of the parent body, but the relative time of introduction of the carbon-rich matrix is still unresolved.     

Double Porosity Finite Element Method for Borehole Modeling

Summary. This paper considers the mechanical and hydraulic response around an arbitrary oriented borehole drilled in a naturally fractured formation. The formation is treated as a double porosity medium consisting of the primary rock matrix as well as the fractured systems, which are each distinctly different in porosity and permeability. The poro-mechanical formulations that couple matrix and fracture deformations as well as fluid flow aspects are presented. A double porosity and double permeability finite element solution for any directional borehole drilled in the fractured porous medium is given. Compared with conventional single-porosity analyses, the proposed double-porosity solution has a larger pore pressure in the matrix and a smaller tensile stress in the near-wellbore region. The effects of time, fracture, mud weight, and borehole inclination in the double-porosity solution are parametrically studied to develop a better understanding of physical characteristics governing borehole problems.     

Numerical modelling of coupled flow and deformation in fractured rock specimens

A dual-porosity poroelastic model is extended to represent behaviour in cylindrical co-ordinates for the evaluation of flow-deformation effects in cylindrical laboratory samples incorporating a central wellbore or non-repeating axisymmetric injection on the periphery. Nine-node quadratic elements are used to represent mechanical deformation, while eight-node linear elements are used to interpolate the pressure fields, which offers significant advantages over the behaviour of other non-conforming elements. The model presented is validated against simplified analytical results, and extended to describe the behaviour of homogeneous and heterogeneous laboratory specimens subjected to controlled triaxial state of stress and injection tests. Apparent from the results is the significant influence of stress-deformation effects over system behaviour. Copyright © 1999 John Wiley & Sons, Ltd.     

Analysis of Stress-dependent Permeability in Nonorthogonal Flow and Deformation Fields

Summary The stress-dependent permeability of porous-fractured media is examined where principal stresses do not coincide with the principal permeabilities. This condition is the norm, and may arise when either flow is controlled at the local level due to the presence of inclined bedding partings or oblique fractures, or as a result of the evolving loading environment. Permeability response is controlled by shear and normal stiffnesses of fractures, frictional dilation coefficients, skeletal and grain modulii, initial permeabilities and stress state. For parameters representative of intact and fractured rocks, hydrostatic loading modes are shown to have the greatest effect in the pre-failure regime. Shear dilation effects are small, primarily controlled by the selected magnitudes of shear stiffnesses and dilation coefficients. The resulting stress-permeability relationships, which cover both fractured and intact media, are examined in a numerical study of fluid flow injected across the diameter of a cylindrical core with inclined fabric, subjected to various loading configurations. This is used to produce relationships that allow one to reduce flow test data in non-standard specimen geometries, where effective stress changes are simultaneously applied. These results confirm the significant impact of inclination of the rock fabric with respect to both flow and loading geometry on the evolving permeability field.