Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.     

Can cod farming affect cod fishing? A system evaluation of sustainability

The cod resources in the Barents Sea constitute the most important fisheries in Norway. In order to reduce resource allocation conflicts among different gear and vessel groups and to ensure profit for all participants throughout the value chain, the sector is thoroughly organized. The institutions established to ensure long-term sustainability, have been developed within the framework of a joint Norwegian–Russian fisheries management regime. However, due to a very high fishing mortality, the cod stock is now under severe pressure. In addition, a major part of the cod fisheries is highly seasonal and unable to be a stable supplier to neither the land-based industry nor demanding international markets. In parallel, cod farming is expected to become a new emerging industry, with potential to copy the success of farmed Atlantic salmon. Many actors within the cod fisheries fear the future competition from the growing cod farming sector. With reference to important attributes that characterize the cod fisheries and cod farming, this paper discusses how a future farming industry may affect the traditional cod fisheries. Moreover, we discuss how the fisheries may be forced to organize in the future to encounter the expected competition from cod farming.     

The effects of oil exploration and production in the northern North Sea: Part 2—microbial biodegradation of hydrocarbons in water and sediments, 1978–1981

The potential of heterotrophs to degrade aromatic hydrocarbons derived from oil in water and sediments in the northern North Sea around the Brent, Beryl, Forties and Murchison oilfields and at a number of stations, from the Forties field to the Firth of Forth, was estimated using 1-¹⁴C naphthalene and 7, 10-¹⁴C benzo(a)pyrene. The degradation of uniformly labelled ¹⁴C mixed 1-amino acids was used as a measure of total heterotrophic activity. Results showed that microorganisms have the potential to degrade the smaller aromatic hydrocarbon molecules rapidly in the water column and in surface sediments. Close to the Beryl platform, where diesel-washed drill cuttings have been continuously dumped, the rate of input of hydrocarbons to the sediment has exceeded the rate of degradation. Mineralization of benzo(a)pyrene, estimated in the sediments only, was minimal. Close to production platforms the biodegradation rate of mixed 1-amino acids showed no increase comparable with that found for naphthalene, suggesting that existing microbial populations had not increased but adapted to degrade oil in water and sediments.     

An evaluation of systems for the integrated assessment of capture fisheries

Integrated fishery assessments are intended to take an integrated and wholistic view of fisheries management, to provide comprehensive systems-based evaluations of the sustainability of individual fisheries and their products. Using guidance derived from decision theory and management science, we develop 18 criteria to evaluate the likely effectiveness of nine integrated fishery assessment systems. The assessment systems do not consistently consider four key criteria: the socio-economic impacts of fisheries, the provision of food security, the local relevance of the assessment to the fishery under assessment, and the independent peer review of assessment outcomes. Other important areas of weakness include the lack of appropriate consultation processes relating to both the design of the assessment system and the outcomes of fishery assessments, and limitations in the quality of data and information used in assessments. Improvements will be needed in these areas across all the systems we evaluated if fishers, consumers, managers and other stakeholders are to be provided with consistently reliable assessment outcomes, and an assurance of the sustainability of capture fisheries.     

Detection of DNA damage in mussels and sea urchins exposed to crude oil using comet assay

The single-cell microgel electrophoresis assay or the comet assay was used to evaluate DNA damage of dispersed crude oil on sea urchins (Strongylocentrotus droebachiensis) and mussels (Mytilus edulis L.). Sea urchins were exposed to 0.06 and 0.25 mg/L dispersed crude oil in a continuous flow system, while the mussels were exposed to 0.015, 0.06 and 0.25 mg/L dispersed crude oil. Sea urchin coelomocytes and mussel haemocytes were sampled after 4 and 5 weeks exposure, respectively. In the sea urchin coelomocytes, there was a significant concentration-related increase in the percentage of DNA in comet tail. In mussel haemocytes, there was a significantly higher percentage of DNA in comet tail for all treatments compared to the control. The responses were concentration-related up to 0.06 mg/L oil. The two highest exposure concentrations of mussels were not significantly different from each other. These results indicate that the comet assay can be used for biomonitoring of DNA damage in marine invertebrates following oil contamination.     

Retrograde fluid infiltration in the high-grade Modum Complex South Norway: evidence for age,source and REE mobility

The high-grade metamorphic basement of the Modum Complex, South Norway,exhibits retrogradation and alteration due to late stage fluid infiltration.Extensive alteration zones of albite-and calcite-rich veining occur especiallywithin and around numerous metagabbros. The gabbros, intruded at 1224±15Ma, are now partly altered to amphibolites due to the subsequent high-grade metamorphism.Two generations of albite-rich rocks have been recognized: (1) a fine-grained, foliated type;(2) a coarse-grained, crosscutting type. Both types show a typical greenschist facies mineralassemblage; albite ± actinolite ± chlorite ± talc. The calcite veins/dykesrepresent a younger generation of veins than both albite-rich types. U–Pb data for spheneof type (1) yielded an age of 1080±3 Ma, determining a point on the retrogradeP-T-t path of the Modum Complex. Increasing albitisation of themetagabbros leads to a decrease in(¹⁴³ND/¹⁴⁴Nd)_oand an increase in (⁸⁷Sr/⁸⁶)_o.Albite- and calcite-rich samples show negative _Nd and positive _Sr, suggesting that fluids which interacted with the metagabbros originated from a crustal reservoir. The Nd and Sr isotopic data show disequilibrium at the microscale as well as at the macroscale. Negative Sm–Nd model ages of the albite-rich rocks demonstrate that rare-earth elements (REEs) were mobile and fractionated during albitisation.     

Far-infrared spectral observations of Saturn and its rings

The spectrum of Saturn and its rings between 45 and 115 μm has been measured at an average resolving power of 14 from the NASA Lear Jet. The combined brightness temperature of the rings and planetary disk decreases beyond 65 μm, in disagreement with previous results. A brightness temperature of 65 ± 10°K is obtained for the planetary disk in the 80–110-μm wavelength range if a large-particle, constant-emissivity model is assumed for the rings. The possible effects of small particles in the rings are briefly considered.     

Interpretation of single-well tracer tests using fractional-flow dimensions. Part 1: Theory and mathematical models

Generalized equations using fractional-flow dimensions were derived to estimate the Darcy and seepage velocities obtained from the point-dilution and the single-well injection-withdrawal field tests conducted in fractured-rock aquifers. Seepage velocities can only be estimated from single-well tests if the hydraulic conductivity and the hydraulic gradient are known a priori. However, if a radial-convergent test is also performed between two boreholes, the kinematic porosity can be estimated and be used to estimate the seepage velocity from the single-well test results. To apply the generalized equations, the flow dimension and the extent of the flow region must be known. Therefore, the generalized radial flow (GRF) model of Barker (1988; a generalized radial flow model for hydraulic tests in fractured rock. Water Resour Res 24(10):1796–1804) is used to estimate the flow dimension because of its wide range of applications. A pumping test performed on the boreholes will yield an estimate of the fractional-flow dimension by applying the GRF model. Electronic Publication     

Gneiss-Water Interaction and Water Evolution During the Early Stages of Dissolution Experiments at Room Temperature

Gneiss-distilled water interaction at room temperature was investigated with batch-reactors to study water-rock reaction and geochemical evolution of the aqueous phase with time. The ion concentrations in water were controlled not only by the dissolution of primary minerals, but also by the precipitation of secondary minerals. The decreasing fraction sizes of gneiss could favor dissolution and precipitation simultaneously. Ca^2 and K^ were the major cations, and HCO3^- was the major anion in water. All the ions except Ca^2 increased in concentration with time. The Ca^2 release from the rock to the aqueous phase was initially much faster than the release of K^ , Na^2 and Mg^2 . But after about 5 - 24 hours, the Ca^2 concentrations in water decreased very slowly with time and became relatively stable. During the experiment, the water varied from the Ca-( K)-HCO3-type water to the K-Ca-HCO3-type water, and then to the K-(Ca, Na)-HCO3-type water. The water-gneiss interaction was dominated by the dissolution of Kfeldspar in the solution. The remaining secondary minerals were mainly kaolinite, illite and K (Mg) -mica.