甲醛还原Pt/TiO2催化剂用于温和条件下高效催化氧化甲醛（英文）

通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差.     

Differential retardation of organic matter maturation by overpressure

Thetraditionalhydrocarbongenerationmodeldoesnottakeintoaccounttheeffectofpressure[1].Astotheroleofpressureinorganicmattermaturationandpetroleumgeneration,threeconflictingopinionshaveeverbeenproposed:(1)Increasingpressurehasnodetectableeffectonorganic-mattermaturation[1,2];(2)increasingpressureenhanceshydrocarbon-thermaldestruction[3];(3)increasingpressuresignificantlyretardsorganic-mattermaturationandhydrocarbongeneration[4,5].Therearemorethan180overpressuredbasinsintheworld.Theroleofoverpress…     

热化学硫酸盐还原作用对碳酸盐岩气藏的化学改造——以川东北地区长兴组-飞仙关组气藏为例

目前在川东北地区长兴组—飞仙关组已发现普光、渡口河、铁山坡、罗家寨等多个高含H2S的大、中型气田。通过天然气地球化学特征、流体包裹体盐度和岩心及薄片的镜下详细观察后认为,川东北地区长兴组—飞仙关组的大多数气藏遭受了热化学硫酸盐还原作用(TSR)的化学改造,TSR的改造主要表现在3个方面:1使C2 重烃相对于CH4、12C相对于13C优先被消耗,造成天然气干燥系数变大和碳同位素变重;2由于TSR产生的大量淡水的加入,使气藏的原生地层水被稀释,造成地层水盐度降低;3TSR相关流体(烃类和H2S等)与储层岩石之间的相互作用使储层被溶蚀和硬石膏发生蚀变,造成储层孔隙度增大,从而对改善其物性具有重要意义。     

Natural gas generation model and its response in accumulated fluids in the Yinggehai basin

The generation of natural gases is much more complicated in comparison with liquid petro-leum in that natural gases could be generated from both humic and sapropelic organic matter at different stages and that natural gases could be organic and inorganic …     

Structure and Fluid Transportation Performance of Faults in the Changxing-Feixianguan Formation,Xuanhan County,Northeastern Sichuan Basin

On the basis of field observations, microscopic thin-sections and laboratory data analysis of ten faults in Xuanhan County area, northeastern Sichuan Basin, central China, the internal and megascopic structures and tectonite development characteristics are mainly controlled by the geomechanical quality in brittle formation of the Changxing-Feixianguan Formation. The fluid transportation performance difference between the faults formed by different geomechanics or different structural parts of the same fault are controlled by the mcgascopic structure and tectonite development characteristics. For instance, the extension fault structure consists of a tectonite breccia zone and an extension fracture zone. Good fluid transportation performance zones are the extension fracture zone adjacent to the tectonite breccia zone and the breccia zone formed at the early evolutionary stage. The typical compression fault structure consists of a boulder-clay zone or zones of grinding gravel rock, compression foliation, tectonite lens, and dense fracture development. The dense fracture development zone is the best fluid transporting area at a certain scale of the compression fault, and then the lens, grinding gravel rock zone and compression foliation zones are the worst areas for hydrocarbon migration. The typical tensor-shear fault with a certain scale can be divided into boulder-clay or grinding gravel rock zones of the fault, as well as a pinnate fractures zone and a derivative fractures zone. The grinding gravel rock zone is the worst one for fluid transportation. Because of the fracture mesh connectivity and better penetration ability, the pinnate fractures zone provides the dominant pathway for hydrocarbon vertical migration along the tensor-shear fault.     

Diagenesis and Restructuring Mechanism of Oil and Gas Reservoir in the Marine Carbonate Formation,Northeastern Sichuan:A Case Study of the Puguang Gas Reservoir

Abstract: Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Puguang gas reservoir has experienced two periods of diagenesis and restructuring since the Late Indo-Chinese epoch. One is the fluid transfer controlled by the tectonic movement and the other is geochemical reconstruction controlled by thermochemical sulfate reduction (TSR). The middle Yanshan epoch was the main period that the Puguang gas reservoir experienced the geochemical reaction of TSR. TSR can recreate the fluid in the gas reservoir, which makes the gas drying index higher and carbon isotope heavier because C2+ (ethane and heavy hydrocarbon) and 12C (carbon 12 isotope) is first consumed relative to CH4 and 13C? (carbon 13 isotope). However, the reciprocity between fluid regarding TSR (hydrocarbon, sulfureted hydrogen (H2S)?, and water) and reservoir rock results in reservoir rock erosion and anhydrite alteration, which increases porosity in reservoir, thereby improving the petrophysical properties. Superimposed by later tectonic movement, the fluid in Puguang reservoir has twice experienced adjustment, one in the late Yanshan epoch to the early Himalayan epoch and the other time in late Himalayan epoch, after which Puguang gas reservoir is finally developed.     

Source Rocks for the Giant Puguang Gas Field, Sichuan Basin: Implication for Petroleum Exploration in Marine Sequences in South China

Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized: low sulfur content, low reflectance (LSLR) solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance (HSHR) solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China.     

高邮凹陷汉留1号断层输导通道的时空分布特征

汉留1号断层是苏北盆地高邮凹陷深凹带北侧边界断层。为了明确该断层输导通道的时间与空间分布特征,通过断层面几何形态、关键时期断层活动速率计算,阐释了汉留1号断层在两个油气主运移时期的输导能力,判识了输导通道的空间位置。研究表明,汉留1号断层在三垛组沉积期活动速率>25 m/Ma,断层开启具有输导能力,另一方面,汉留1号断层的断层面存在3个明显的凸面和2个凹面区域,因此,在该沉积期该断层在3个凸面区域发育3条输导通道。而在随后的盐城组至今的沉积期,断层活动强度减弱,活动速率<10 m/Ma,输导能力弱,垂向上主要起封闭作用。因此,空间上断层通道发育于断层面凸面位置;时间上,断层活动速率>25 m/Ma时通道开启,<10 m/Ma时通道关闭。就聚集而言,断层通道开启时油气沿断层向上运移聚集于上部滚动背斜圈闭中,闭合时聚集于下部断层圈闭中。     

油气幕式成藏及其驱动机制和识别标志

连续稳态流动和周期性(幕式)瞬态流动是沉积盆地流体的 2种流动方式。幕式流体流动是压力和应力的作用引起地层周期性破裂或断裂、先存裂隙周期性开启的结果。幕式成藏是沉积盆地中油气与地层水组成的混相、不连续流体的多期次充注/聚集过程,超压顶界面附近、底辟和深断裂附近是幕式成藏的有利场所。与油气稳态连续聚集过程相比,幕式成藏更快,大 中型油气田可在较短的时间内形成,根据传统模式难以成藏的年轻圈闭可成为有效的勘探目标。幕式流体流动的主要特征是流体成份和流动过程的不连续性、流体流动过程中温度、压力的快速变化及流体流动的多期性和周期性。流体的时空非均质性、流体流动的瞬态温度响应和运移相态分异及其揭示的多期流体相互作用是幕式成藏的有效识别标志。     

Paleo-oil-Water Contact and Present-Day Gas-Water Contact： Implication for Evolution History of Puguang Gas Field, Sichuan Basin, China

The Puguang (普光) gas field is the largest gas field found in marine carbonate in China.The Puguang gas field experienced complicated evolution history from paleo-oil pool to gas pool.The purpose of this article is to reveal the evolution history of Puguang gas field through systematic study on the relationship between paleo-oil-water contact (POWC) and present-day gas-water contact (PGWC).POWC was recognized by observing the change of relative content of residual solid bitumen in the cores,and PGWC was observed using log and drilling stem test data.Two types of relationship between POWC and PGWC were observed in the Puguang gas field:POWC is above PGWC,and POWC is below PGWC.The former is normal as oil cracking may cause gas-water contact to move downward.The latter can be interpreted by lateral gas re-migration and re-accumulation caused by changes in structural configuration.The relationship between POWC and PGWC suggests that during oil charge,the southwestern and northwestern parts of the Puguang gas field were structurally lower than the northeastern and southeastern parts.Thrusting from Xuefengshan (雪峰山) since Yanshanian movement and from Dabashan (大巴山) since Himalayan movement resulted in the relative uplift of the southwestern and northwestern parts of the Puguang structure,which significantly changed the structural configuration.Based on the paleo-structure discussed in this article,the most probable migration directions of paleo-oil were from the northwest to the southeast and from the southwest to the northeast.Consequently,the evolution history of the Puguang gas field can be divided into three stages,namely,oil charging (200-170 Ma),cracking oil to gas (155-120 Ma),and gas pool adjustment (1200-0Ma).