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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff
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We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
对于改进的Encke方法,选择适当的参考轨道是一个关键.然而,对于人造地球卫星长弧轨道计算,目前所给出的几种参考轨道均需要逐段校正,这将给定轨问题带来附加的复杂性.本文将仔细探讨如何选择参考轨道和减少校正次数. 相似文献
3.
This paper presents an on-line trained neural net work controller for ship track-keeping problems. Following a brief review of the ship track-keeping control development since the 1980's, an analysis of various existing backpropagation-based neural controllers is provided. We then propose a single-input multioutput (SIMO) neural control strategy for situations where the exact mathematical dynamics of the ship are not available. The aim of this study is to build an autonomous neural controller which uses rudder to regulate both the tracking error and heading error. During the whole control process, the proposed SIMO neural controller adapts itself on-line from a direct evaluation of the control accuracy, and hence the need for a “teacher” or an off-line training process can be removed. With a relatively modest amount of quantitative knowledge of the ship behavior, the design philosophy enables real time control of a nonlinear ship model under random wind disturbances and measurement noise. Three different track-keeping tasks have been simulated to demonstrate the effectiveness of the training method and the robust performance of the proposed neural control strategy 相似文献
4.
The actual penetration depth of the Shoemaker-Levy 9 fragments into the Jovian atmosphere is still an open question. From fundamental equations of meteoric physics with variable cross-section, a new analytic model of energy release of the fragments is presented. In use of reasonable parameters, a series of results are calculated for different initial mass of the fragments. The results show that the largest fragment explodes above pressure levels of 3 bars and does not penetrate into the H2O cloud layer of the Jovian atmosphere, and that airburst of smaller fragments occur even above the upper cloud layer. 相似文献
5.
为建立社会主义市场经济的地矿工作新秩序,本文对国有地矿企业的经营者(厂长、经理)这一特殊群体进行了分析。着重研究了新形势下企业经营者实行年薪制的问题。指出年薪制就是以企业一个生产经营周期为单位确定经营者的报酬,这一周期通常为一年。进而阐述了为什么要实行企业经营者年薪制;企业经营者的收入应与职工工资完全脱钩;采用基础报酬加效益报酬的方法确定收入等等。并构想了实行经营者年薪制所需要的外部环境:建立经营者人才市场、经营者要能进能出、实行任职资格制度、建立风险机制、按劳动力市场经济规律办事。 相似文献
6.
Based on the CN and C2 comae isophotes for two comets (1961 IX and 1970 16) given by Rahe et al. and the relevant theory of physical chemistry, we have deduced the distributions of the CN and C2 modecules in the coma, their scale heights and mean lifetimes. The results favour the viewpoint that HCN is the parent of CN, and that C2H2 is the parent of C2. 相似文献
7.
THE SIMULATED STORAGE CAPACITY OF FLOOD AND WATERLOGGING IN THE TYPICAL AGRICULTURAL REGION IN JIANGHAN PLAIN 总被引:2,自引:0,他引:2
1INTRODUCTIONJianghanPlainisoneoftheimportantbasesofChina′sagriculturalproductivitylocatedinthemiddleChangjiangRivervalleyofcentralChina.TheJianghanplainapproximately6.6×104km2inareaandover30millioninpopulationistherenowned“countryoffishandrice"in… 相似文献
8.
In many astrophysical problems, the study of the stability of an atmosphere in the presence of a magnetic field is of importance. In most cases the MHD instabilities of atmospheres are studied by energy principle of Bernsteinet al. (1958). In this paper, a general method for studying the stability of a system subject to MHD equations of conditions has been proposed. This is based on the local potential concept put forward by Glansdorff and Prigogine (1964). The scheme for securing stability criteria has been demonstrated in two particular cases. 相似文献
9.
Zhang Qing Wang Li-fan Hu Jing-yao P. A. Mazzali Wang Zhen-ru 《Chinese Astronomy and Astrophysics》1995,19(4):426-431
We present the modeling of the ultraviolet and optical spectra obtained simultaneously on 1993 April 15 with the HST and at Lick Observatory. A Monte Carlo code is employed in the modeling and a comparison is made between models reported by different groups. With an atmosphere similar to the Sun in chemical composition, the observed spectral lines are well reproduced by a power law density structure of index around 20 except the strong H and HeI λ5876 lines which have peculiar absorption profiles. The photospheric velocity is found to be 9500 km/s and the blackbody temperature of the spectrum is 7990 K. For H and HeI λ5876, we suggest a two-component density structure which has a smoother layer located immediately outside the steeply decreasing inner envelope. The power law indices are most probably 20 and 3, respectively, with the transition point at about 13 000 km/s. In addition, this outer smooth layer serves to flatten the far UV spectrum as observed. 相似文献
10.
A THREE-DIMENSIONAL ELASTIC NESTED-GRID MESO-(β-γ)SCALE ATMOSPHERIC MODEL——PARTI:MODEL DESCRIPTION
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A three-dimensional elastic nonhydrostatic mesoscale(β-γ)model with nested-grid is presented.It uses a set of fullequations in terrain-following coordinates as its basic dynamic frame,which is solved with a time-splitting algorithmfor acoustic and gravity waves.The model physical parameterization includes a K-theory subgrid eddy mixing for cloudand free atmosphere,a bulk planetary boundary layer parameterization,and three types of sofisticated cloudmicrophysics schemes with double-parameters for hail-bearing clouds,warm clouds and snowing clouds respectively.The model is designed to be used flexibly for simulations of a variety of meso-and small-scale atmospheric processes,and can be improved as a regional and local operational NWP system in future. 相似文献