A Cordilleran model for the evolution of Avalonia

Striking similarities between the late Mesoproterozoic–Early Paleozoic record of Avalonia and the Late Paleozoic–Cenozoic history of western North America suggest that the North American Cordillera provides a modern analogue for the evolution of Avalonia and other peri-Gondwanan terranes during the late Precambrian. Thus: (1) The evolution of primitive Avalonian arcs (proto-Avalonia) at 1.2–1.0 Ga coincides with the amalgamation of Rodinia, just as the evolution of primitive Cordilleran arcs in Panthalassa coincided with the Late Paleozoic amalgamation of Pangea. (2) The development of mature oceanic arcs at 750–650 Ma (early Avalonian magmatism), their accretion to Gondwana at ca. 650 Ma, and continental margin arc development at 635–570 Ma (main Avalonian magmatism) followed the breakup of Rodinia at ca. 755 Ma in the same way that the accretion of mature Cordilleran arcs to western North America and the development of the main phase of Cordilleran arc magmatism followed the Early Mesozoic breakup of Pangea. (3) In the absence of evidence for continental collision, the diachronous termination of subduction and its transition to an intracontinental wrench regime at 590–540 Ma is interpreted to record ridge–trench collision in the same way that North America's collision with the East Pacific Rise in the Oligocene led to the diachronous initiation of a transform margin. (4) The separation of Avalonia from Gondwana in the Early Ordovician resembles that brought about in Baja California by the Pliocene propagation of the East Pacific Rise into the continental margin. (5) The Late Ordovician–Early Silurian sinistral accretion of Avalonia to eastern Laurentia emulates the Cenozoic dispersal of Cordilleran terranes and may mimic the paths of future terranes transferred to the Pacific plate.This close similarity in tectonothermal histories suggests that a geodynamic coupling like that linking the evolution of the Cordillera with the assembly and breakup of Pangea, may have existed between Avalonia and the late Precambrian supercontinent Rodinia. Hence, the North American Cordillera is considered to provide an actualistic model for the evolution of Avalonia and other peri-Gondwanan terranes, the histories of which afford a proxy record of supercontinent assembly and breakup in the late Precambrian.     

Composition of the Descartes region,lunar highlands

Analytical data for 40 elements are reported for Apollo 16 soils 60601, 61181, 61501, 64801, 67701, 68501, 65701 and breccias 60015, 60017, 60018, 60315, 61016, 61175, 65015 and 66055. The soils are uniform except for the North Ray Crater rim sample which is richer in Al₂O₃.The breccia components show great diversity in composition. Low-K Fra Mauro basalt, Highland basalt (anorthositic gabbro) and plagioclase are important constituents. Medium-K Fra Mauro basalt is an important constituent of breccias 65015 and 60315.The breccias contain many meteorite fragments and high nickel contents, evidence of the early highland bombardment.Most of the refractory elements (REE, Th, U, Zr, Hf, Nb, Ba) show strong positive correlations, interpreted as resulting from mixing. The REE patterns of the breccias show extreme variation relative to chondrites. There is a good inverse correlation between REE and the europium anomaly ($\text{Eu}\text{Eu}{}^{\mathrm{x}}$). The $\text{La}\text{Yb}$ ratio is constant at 3.1 except in plagioclase. Eu depletion or enrichment is interpreted as due to addition or removal of plagioclase.The Cayley and Descartes formations cannot be distinguished chemically and the differences in surface expression are not due to chemical distinctions. They are interpreted as structural differences, related to early highland cratering and mare basin formation.The complex soil and breccia compositions are related to mixing of four components. These are Low-K Fra Mauro basalt, Highland basalt (anorthositic gabbro) and subordinate plagioclase and Medium-K Fra Mauro basalt. These compositions have been used in a computer program (PETMIX III) to provide fits for the analytical data in terms of the end-members.An average highland composition is proposed, based on the Apollo 15 and 16 orbital data for Si, Al, Mg and Th. Abundances for most other elements are derived from the interelement relationships and correlations, and checked by the mixing program.The resulting composition consists of 69 per cent Highland basalt (anorthositic gabbro) and 31 per cent Low-K Fra Mauro basalt. There is no significant Eu anomaly. The abundances are: SiO₂: 45.2 per cent; TiO₂: 0.68 per cent; Al₂O₃: 24.9 per cent; FeO: 6.3 per cent; MgO: 8.5 per cent; CaO: 13.8 per cent; Na₂O: 0.4 per cent; K₂O: 0.11 per cent; Cr₂O₃: 0.11 per cent; Ba: 144 ppm; Th: 1.8 ppm; U: 0.46 ppm; Pb: 1.6 ppm; Zr: 156 ppm; Hf: 3.2 ppm; Nb: 10.8 ppm; Y: 32 ppm; ΣREE: 85 ppm.     

Rare earth element patterns and crustal evolution—I. Australian post-Archean sedimentary rocks

A suite of Australian shales, greywackes and subgreywackes ranging in age from Proterozoic to Triassic were analyzed for the rare earth elements (REE) in order to detect any secular changes in rare earth distribution. These post-Archean sediments show remarkably similar relative rare earth patterns. They are characterized by negative Eu anomalies of almost constant magnitude (average Eu/Eu* = 0.67 ± 0.05) relative to chondrites and nearly constant ratios of light to heavy rare earths (average ∑LREE/∑HREE = 9.7 ± 1.8).

The REE abundances are generally higher in the younger sediments which may suggest that the absolute abundances of the rare earths in clastic sediments have gradually increased with time. Since no secular change in relative rare earth distribution was detected in the post-Archean sediments, a uniform process of crustal growth and evolution seems to have operated over the past 1500 million years at least.

Australites show rare earth distributions very similar to that of the average clastic sediment. This suggests that the tektite parent material originated in the upper crust.     

Gap flow measurements during the Mesoscale Alpine Programme

Summary The lowest pass through the Alpine crest, the Brenner Pass, was heavily instrumented with ground-based and air-borne in-situ and remote sensors during the Special Observation Period (SOP) of the Mesoscale Alpine Programme (MAP) in the fall of 1999 to study gap flow. The main objectives were to study the combined effects of changes of terrain height and changes of width in altering the flow characteristics, to investigate the coupling of the gap flow to the flow aloft, and to provide high-density measurements in the along- and cross-gap directions.Gap flows occurred during one third of the 70-day SOP, a frequency above the long term average. Gap flows took place with and without accompanying cross-barrier flow and with and without a capping inversion. A case study demonstrates the hydraulic jump-like features that occurred in gap flow on 30 October 1999 and illustrates the types of data available for further analyses.     

Neoproterozoic—Early Paleozoic evolution of peri-Gondwanan terranes: implications for Laurentia-Gondwana connections

Neoproterozoic tectonics is dominated by the amalgamation of the supercontinent Rodinia at ca. 1.0 Ga, its breakup at ca. 0.75 Ga, and the collision between East and West Gondwana between 0.6 and 0.5 Ga. The principal stages in this evolution are recorded by terranes along the northern margin of West Gondwana (Amazonia and West Africa), which continuously faced open oceans during the Neoproterozoic. Two types of these so-called peri-Gondwanan terranes were distributed along this margin in the late Neoproterozoic: (1) Avalonian-type terranes (e.g. West Avalonia, East Avalonia, Carolina, Moravia-Silesia, Oaxaquia, Chortis block that originated from ca. 1.3 to 1.0 Ga juvenile crust within the Panthalassa-type ocean surrounding Rodinia and were accreted to the northern Gondwanan margin by 650 Ma, and (2) Cadomian-type terranes (North Armorica, Saxo-Thuringia, Moldanubia, and fringing terranes South Armorica, Ossa Morena and Tepla-Barrandian) formed along the West African margin by recycling ancient (2–3 Ga) West African crust. Subsequently detached from Gondwana, these terranes are now located within the Appalachian, Caledonide and Variscan orogens of North America and western Europe. Inferred relationships between these peri-Gondwanan terranes and the northern Gondwanan margin can be compared with paleomagnetically constrained movements interpreted for the Amazonian and West African cratons for the interval ca. 800–500 Ma. Since Amazonia is paleomagnetically unconstrained during this interval, in most tectonic syntheses its location is inferred from an interpreted connection with Laurentia. Hence, such an analysis has implications for Laurentia-Gondwana connections and for high latitude versus low latitude models for Laurentia in the interval ca. 615–570 Ma. In the high latitude model, Laurentia-Amazonia would have drifted rapidly south during this interval, and subduction along its leading edge would provide a geodynamic explanation for the voluminous magmatism evident in Neoproterozoic terranes, in a manner analogous to the Mesozoic-Cenozoic westward drift of North America and South America and subduction-related magmatism along the eastern margin of the Pacific ocean. On the other hand, if Laurentia-Amazonia remained at low latitudes during this interval, the most likely explanation for late Neoproterozoic peri-Gondwanan magmatism is the re-establishment of subduction zones following terrane accretion at ca. 650 Ma. Available paleomagnetic data for both West and East Avalonia show systematically lower paleolatitudes than predicted by these analyses, implying that more paleomagnetic data are required to document the movement histories of Laurentia, West Gondwana and the peri-Gondwanan terranes, and test the connections between them.     

Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test,Texas, USA

Sedimentary basins in general, and deep saline aquifers in particular, are being investigated as possible repositories for large volumes of anthropogenic CO₂ that must be sequestered to mitigate global warming and related climate changes. To investigate the potential for the long-term storage of CO₂ in such aquifers, 1600 t of CO₂ were injected at 1500 m depth into a 24-m-thick “C” sandstone unit of the Frio Formation, a regional aquifer in the US Gulf Coast. Fluid samples obtained before CO₂ injection from the injection well and an observation well 30 m updip showed a Na–Ca–Cl type brine with ∼93,000 mg/L TDS at saturation with CH₄ at reservoir conditions; gas analyses showed that CH₄ comprised ∼95% of dissolved gas, but CO₂ was low at 0.3%. Following CO₂ breakthrough, 51 h after injection, samples showed sharp drops in pH (6.5–5.7), pronounced increases in alkalinity (100–3000 mg/L as HCO₃) and in Fe (30–1100 mg/L), a slug of very high DOC values, and significant shifts in the isotopic compositions of H₂O, DIC, and CH₄. These data, coupled with geochemical modeling, indicate corrosion of pipe and well casing as well as rapid dissolution of minerals, especially calcite and iron oxyhydroxides, both caused by lowered pH (initially ∼3.0 at subsurface conditions) of the brine in contact with supercritical CO₂.     

http://www.sciencedirect.com/science/article/pii/S1674987112001570

The supercontinent cycle,by which Earth history is seen as having been punctuated by the episodic assembly and breakup of supercontinents,has influenced the rock record more than any other geologic phenomena,and its recognition is arguably the most important advance in Earth Science since plate tectonics.It documents fundamental aspects of the planet’s interior dynamics and has charted the course of Earth’s tectonic,climatic and biogeochemical evolution for billions of years.But while the widespread realization of the importance of supercontinents in Earth history is a relatively recent development,the supercontinent cycle was first proposed thirty years ago and episodicity in tectonic processes was recognized long before plate tectonics provided a potential explanation for its occurrence.With interest in the supercontinent cycle gaining momentum and the literature expanding rapidly,it is instructive to recall the historical context from which the concept developed.Here we examine the supercontinent cycle from this perspective by tracing its development from the early recognition of long-term episodicity in tectonic processes,through the identification of tectonic cycles following the advent of plate tectonics,to the first realization that these phenomena were the manifestation of episodic supercontinent assembly and breakup.     

Anchoring to determine negotiated catch limits: a case study of an industrial fishery in Oman

Despite refinement in scientific methods of setting total allowable catches (TACs), the choice of values is affected by uncertainty that arises as a result of incomplete information and the behavioural intentions of resource users, among others. In this context, this paper promotes ‘anchoring’ – which is a subject of behavioural economics and is generally practised in decision-making when faced with uncertainty – as an approach to TAC setting. We estimate a set of anchor points for nine demersal species by employing two modelling scenarios, the first using catch-and-effort data and the second only catch data collected from the demersal trawl fishery. A non-parametric test yielded no significant difference between the sets of anchor points generated from the two models. It is hoped that the use of anchoring would constitute a proactive management approach that could serve as a mechanism of promoting knowledge integration and effective communication, developing mutual trust, and improving management outcomes in the future.     

Rare earth element-thorium correlations in sedimentary rocks,and the composition of the continental crust

There is a correlation between thorium and the light rare earth elements, indicated by La/Th ratios in fine grained sedimentary rocks of various ages from Australia and Greenland. The correlation between Th and the heavy rare earth elements (Th/Yb) is much less significant. Archean sedimentary rocks have a higher La/Th (3.6 ± 0.4) than post-Archean sedimentary rocks (La/Th = 2.7 ± 0.2).The cause of this correlation can be attributed to the coherent behaviour of these elements during most sedimentary processes (weathering, transport, diagenesis, etc.). Since the chondrite-normalized rare earth element distribution of clastic fine grained sedimentary rocks is accepted to be parallel to the distribution of REE in the upper continental crust, an estimate of upper crustal Th abundances can be made. Using reasonable assumptions of certain elemental ratios (K/U, Th/U, K/Rb) in the upper crust, minimum estimates of the abundances of K, U and Rb can also be made for the post-Archean and Archean upper crusts.The post-Archean values (K = 2.9%; Rb = 115 ppm; Th = 11.1 ppm; U = 2.9 ppm) compare favourably to some previous estimates made from direct sampling and theoretical considerations and help confirm a granodiorite present day upper continental crust. The Archean data (K = 0.92%; Rb = 30ppm; Th = 3.5 ppm; U = 0.92 ppm) support models which suggest a significantly more mafic exposed crust at that time.     

Rare earth element patterns and crustal evolution—II. Archean sedimentary rocks from Kalgoorlie,Australia

REE data, with major element and other trace element data are reported for a suite of Archean sedimentary rocks (2800 million years old) from Kalgoorlie, Western Australia. The REE patterns fall into two groups with ?LREE/?HREE ratios of 6 and 15, respectively. The first group have either no Eu anomaly relative to chondrites, or a positive Eu anomaly, in contrast to the pronounced Eu depletion (Eu/Eu ~ 0.67) shown by younger (Post-Archean) sedimentary rocks.The problem of positive Eu enrichment relative to chondritic patterns, is examined by analysing a suite of Devonian greywackes, derived from calc-alkaline volcanic rocks. Some of these samples also show positive Eu anomalies, attributable to local accumulation of feldspar. This explanation is preferred to models involving an early anorthositic crust. The group of samples showing heavy REE depletion patterns (complementary to those observed in garnet) appear to be derived from adjacent Na-rich granites which display identical REE patterns. Locally abundant K-rich granites do not appear to have made any contribution to the Archean sedimentary rocks.The majority of the sedimentary rocks have REE patterns indistinguishable from those of recent island arc calc-alkaline rocks, and so could constitute evidence that the Archean crust was principally formed by processes analogous to present day island-arc type volcanism. However, similar REE patterns may be produced by an appropriate mixture of the common bimodal tholeiitic-felsic igneous suite commonly observed in Archean terrains. The REE data presented here do not distinguish between these two models.