The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996     

Balancing deformation in NW Borneo: Quantifying plate-scale vs. gravitational tectonics in a delta and deepwater fold-thrust belt system

Recent GPS measurements demonstrate that NW Borneo undergoes 4–6 mm of plate-scale shortening a year, which is not accommodated by plate-scale structures. The only geological structure in NW Borneo described to accommodate on-going shortening is the Baram Delta System located on the outer shelf to basin floor. Delta toe fold-thrust belts are commonly thought to be caused by margin-normal compressional stresses generated by margin-parallel upslope gravitational extension.     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

Contribution of geophysical surveys to groundwater modelling of a porous aquifer in semiarid Niger: An overview

Subsurface geophysical surveys were carried out using a large range of methods in an unconfined sandstone aquifer in semiarid south-western Niger for improving both the conceptual model of water flow through the unsaturated zone and the parameterization of numerical a groundwater model of the aquifer. Methods included: electromagnetic mapping, electrical resistivity tomography (ERT), resistivity logging, time domain electromagnetic sounding (TDEM), and magnetic resonance sounding (MRS). Analyses of electrical conductivities, complemented by geochemical measurements, allowed us to identify preferential pathways for infiltration and drainage beneath gullies and alluvial fans. The mean water content estimated by MRS (13%) was used for computing the regional groundwater recharge from long-term change in the water table. The ranges in permeability and water content obtained with MRS allowed a reduction of the degree of freedom of aquifer parameters used in groundwater modelling.     

Study of a triple emission nebula in Orion

The Hii regions S254, 255 and 257 in the constellation of Orion are close together on the sky and appear like a triple object. Fabry-Pérot radial velocities of the Hii regions as well asUBV photo-electric magnitudes of their exciting stars are obtained. The data show that (1) all three nebulae are at a distance of 2.5 kpc; (2) an excess extinction is observed in S255 and S257 while S254 shows no excess extinction; (3) S255, identified as an IR and a molecular source, is the youngest object of the group. It is concluded that the three Hii regions are at different evolutionary stages.     

A seasonal dipolar eddy near Ras Al Hamra (Sea of Oman)

Trajectories and hydrological data from two Argo floats indicate that warm and salty water at 200–300-m depths was ejected from the coast of Oman, near Ras al Hamra, in spring 2008, 2011, and 2012. This warm and salty water, Persian Gulf Water (PGW), once ejected from the coast, recirculated cyclonically in the western Sea of Oman, but also flowed eastward along the Iranian and Pakistani coasts. There, it was expelled seaward by mesoscale eddies as shown by other float data. Seasonal maps of salinity were computed from all available Argo floats; they showed that, in spring, PGW is present in the middle and north of the Sea of Oman, contrary to fall, when the salinity maxima lie southeast of Ras al Hadd. The ejection of PGW from Ras al Hamra is related here to the influence of a mesoscale dipolar eddy which often appears near this cape in spring. The time-averaged and empirical orthogonal functions of altimetric maps over 11 years for this season confirm the frequent presence and the persistence of this feature. From surface currents and hydrology, deep currents were computed via thermal wind balance, and the associated shear and strain fields were obtained. This deformation field is intense near Ras al Hamra, with an offshore direction. This flow structure associated with the mesoscale dipole explains PGW ejection from the coast. This observation suggests that PGW distribution in the Northern Arabian Sea can be strongly influenced by seasonal mesoscale eddies.     

The concept of travelling bedload and its consequences for bedload computation in mountain streams

In bedload transport modelling, it is usually presumed that transported material is fed by the bed itself. This may not be true in some mountain streams where the bed can be very coarse and immobile for the majority of common floods, whereas a finer material, supplied by bed‐external sources, is efficiently transported during floods, with marginal morphological activities. This transport mode was introduced in an earlier paper as ‘travelling bedload’. It could be considered an extension of the washload concept of suspension, applied to bedload transport in high‐energy, heavily armoured streams. Since this fine material is poorly represented in the bed surface, standard surface‐based approaches are likely to strongly underestimate the true transport in such streams. This paper proposes a simple method to account for travelling bedload in bedload transport estimations. The method is tested on published datasets and on a typical Alpine stream, the Roize (Voreppe, France). The results, particularly on active streams that experience greater transport than expected from the grain sizes of their bed material, reinforce the necessity of accounting for the ‘travelling bedload concept’ in bedload computation. The method relevance is discussed regarding varying flood magnitudes, geomorphic responses and eventual anthropic origin of the ‘travelling bedload’ phenomena. To conclude, this paper considers how to compute bedload transport for a wide range of situations, ranging from sediment‐starved cases to the general mobile bed alluvial case, including the intermediate situation of external source supply on armoured bed. Copyright © 2017 John Wiley & Sons, Ltd.     

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.     

Assessing wave climate trends in the Bay of Biscay through an intercomparison of wave hindcasts and reanalyses

The Bay of Biscay, located in the Northeast Atlantic Ocean, is exposed to energetic waves coming from the open ocean that have crucial effects on the coast. Knowledge of the wave climate and trends in this region are critical to better understand the last decade’s evolution of coastal hazards and morphology and to anticipate their potential future changes. This study aims to characterize the long-term trends of the present wave climate over the second half of the twentieth century in the Bay of Biscay through a robust and homogeneous intercomparison of five-wave datasets (Corrected ERA-40 (C-ERA-40), ECMWF Reanalysis Interim (ERA-Interim), Bay Of Biscay Wave Atlas (BOBWA-10kH), ANEMOC, and Bertin and Dodet 2010)). The comparison of the quality of the datasets against offshore and nearshore measurements reveals that at offshore locations, global reanalyses slightly underestimate wave heights, while regional hindcasts overestimate wave heights, especially for the highest quantiles. At coastal locations, BOBWA-10kH is the dataset that compares the best with observations. Concerning long time-scale features, the comparison highlights that the main significant trends are similarly present in the five datasets, especially during summer for which there is an increase of significant wave heights and mean wave periods (up to +15 cm and +0.6 s over the period 1970–2001) as well as a southerly shift of wave directions (around ?0.4° year^?1). Over the same period, an increase of high quantiles of wave heights during the autumn season (around 3 cm year^?1 for 90th quantile of significant wave heights (SWH₉₀)) is also apparent. During winter, significant trends are much lower than during summer and autumn despite a slight increase of wave heights and periods during 1958–2001. These trends can be related to modifications in the wave-type occurrence. Finally, the trends common to the five datasets are discussed by analyzing the similarities with centennial trends issued from longer time-scale studies and exploring the various factors that could explain them.