Absolute isotopic abundances of Ti in meteorites

The absolute isotope abundance of Ti has been determined in Ca-Al-rich inclusions from the Allende and Leoville meteorites and in samples of whole meteorites. The absolute Ti isotope abundances differ by a significant mass dependent isotope fractionation transformation from the previously reported abundances, which were normalized for fractionation using ${}^{46}\text{Ti}{}^{48}\text{Ti}$. Therefore, the absolute compositions define distinct nucleosynthetic components from those previously identified or reflect the existence of significant mass dependent isotope fractionation in nature. We provide a general formalism for determining the possible isotope compositions of the exotic Ti from the measured composition, for different values of isotope fractionation in nature and for different mixing ratios of the exotic and normal components. The absolute Ti and Ca isotopic compositions still support the correlation of ⁵⁰Ti and ⁴⁸Ca effects in the FUN inclusions and imply contributions from neutron-rich equilibrium or quasi-equilibrium nucleosynthesis. The present identification of endemic effects at ⁴⁶Ti, for the absolute composition, implies a shortfall of an explosive-oxygen component or reflects significant isotope fractionation. Additional nucleosynthetic components are required by ⁴⁷Ti and ⁴⁹Ti effects. Components are also defined in which ⁴⁸Ti is enhanced.Bulk samples of carbonaceous meteorites (C2 and C3 types) show distinct excesses at ⁵⁰Ti but no nonlinear effects at the other Ti isotopes. Other chondrites, including Orgueil (Cl), show no nonlinear effects. Relative to terrestrial Ti, a small isotope fractionation is found for only an enstatite chondrite. The Ti absolute compositions in Ca-Al-rich inclusions show significant isotope fractionation effects corresponding to an enhancement in the heavier isotopes relative to the lighter isotopes as compared to Ti in a TiO₂ standard and in chondrites. The absence of a correlation of Ti isotope fractionation effects with those for Ca and Mg is indicative of multiple processes of condensation, volatilization and recondensation; however, the mechanisms causing the isotope fractionation are not well understood.     

Implementing adaptation in developed countries: an analysis of progress and trends

Little attention has been paid thus far to the experiences of developed countries in adapting to climate change. This article addresses this research gap by providing an assessment of broad trends in progress on planning and implementing adaptation in developed countries. Primary inputs are the National Communications (NCs) by these countries to the United Nations Framework Convention on Climate Change (UNFCCC), although the article also discusses illustrative examples of recent adaptation activities that have not been covered in the NCs. NCs reflect ‘whole government’ perspectives and follow a standardized reporting format, which facilitates cross-national comparisons. The analysis shows that impacts and adaptation receive limited attention within NCs. The discussion on impacts and adaptation has typically been dominated by climate scenarios and impacts analysis, while the discussion on adaptation is often limited to the identification of generic options. There are signs of recent progress, however, in the Third and especially the Fourth NCs, in which a growing number of developed countries report on establishing frameworks for adaptation and on efforts to implement adaptation measures that take future climate into account. Although an encouraging sign, it is still too early to assess the eventual impact of such measures.     

QUARTZ WEATHERING IN FREEZE–THAW CYCLES: EXPERIMENT AND APPLICATION TO THE EL'GYGYTGYN CRATER LAKE RECORD FOR TRACING SIBERIAN PERMAFROST HISTORY

The object of this study is to test the assumption that cryogenic weathering (here understood as in‐situ disintegration of rock under cold‐climate conditions including ice as a weathering agent) preferentially breaks up quartz grains. We apply the results of laboratory tests to a Quaternary sediment record. The combination of silt production, relative quartz enrichment in the silt fraction, and quartz grain micromorphology is traced in a multi‐100‐kyr lake sediment archive as indicator data for cryogenic weathering. Constant cryogenic weathering conditions are inferred for at least the last 220 000 years from a lake sediment core of El'gygytgyn Crater, northeast Russia. This is the longest continuous terrestrial archive currently known for the continental Arctic. Quartz enrichment in the fines evolves from seasonal freeze–thaw weathering as demonstrated in laboratory testing where over 100 freeze and thaw cycles crack quartz grains preferentially over feldspar. Microscopic grain features demonstrate that freeze–thaw cycling probably disrupts quartz grains along mineral impurities such as bubble trails, gas–liquid inclusions, or mineralogical sub‐grain boundaries. Single‐grain micromorphology (e.g. angular outlines, sharp edges, microcracks, brittle surfaces) illustrates how quartz becomes fragmented due to cryogenic cracking of the grains. The single‐grain features stemming from the weathering dynamics are preserved even after a grain is transported off site (i.e. in mobile slope material, in seasonal river run‐off, into a lake basin) and may serve as first‐order proxy data for permafrost conditions in Quaternary records.     

Tracing glacier wastage in the Northern Tien Shan (Kyrgyzstan/Central Asia) over the last 40 years

The status and dynamics of glaciers are crucial for agriculture in semiarid parts of Central Asia, since river flow is characterized by major runoff in spring and summer, supplied by glacier- and snowmelt. Ideally, this coincides with the critical period of water demand for irrigation. The present study shows a clear trend in glacier retreat between 1963 and 2000 in the Sokoluk watershed, a catchment of the Northern Tien Shan mountain range in Kyrgyzstan. The overall area loss of 28% observed for the period 1963–2000, and a clear acceleration of wastage since the 1980s, correlate with the results of previous studies in other regions of the Tien Shan as well as the Alps. In particular, glaciers smaller than 0.5 km² have exhibited this phenomenon most starkly. While they registered a medium decrease of only 9.1% for 1963–1986, they lost 41.5% of their surface area between 1986 and 2000. Furthermore, a general increase in the minimum glacier elevation of 78 m has been observed over the last three decades. This corresponds to about one-third of the entire retreat of the minimum glacier elevation in the Northern Tien Shan since the Little Ice Age maximum.     

Ca isotopes in refractory inclusions

We report measurements of the absolute isotope abundance of Ca in Ca-Al-rich inclusions from the Allende and Leoville meteorites. Improved high precision measurements are reported also for ⁴⁶Ca. We find that nonlinear isotope effects in Ca are extremely rare in these inclusions. The absence of nonlinear effects in Ca, except for the effects in FUN inclusions, is in sharp contrast to the endemic effects in Ti. One fine-grained inclusion shows an excess of ⁴⁶Ca of (7 ± 1)%., which is consistent with addition of only ⁴⁶Ca or of an exotic (1) component with ⁴⁶Ca¹ ~ ⁴⁸Ca¹. FUN inclusion EK-1-4-1 shows a small ⁴⁶Ca excess of (3.3 ± 1.0)%.; this confirms that the exotic Ca components in EK-1-4-1 were even more deficient in ⁴⁶Ca relative to ⁴⁸Ca than is the case for normal Ca. The Ca in the Ca-Al-rich inclusions shows mass dependent isotope fractionation effects (as deduced from the absolute ${}^{40}\text{Ca}{}^{44}\text{Ca}$) which have a range from ?3.8 to +6.7%. per mass unit difference. This range is a factor of 20 wider than the range previously established for bulk meteorites and for terrestrial and lunar samples. Ca and Mg isotope fractionation effects in the Ca-Al-rich inclusions are common and attributed to kinetic isotope effects which imply the production of the inclusions by complex sequences of condensation, vaporization and recondensation. A correlation was found between Ca and Mg isotope fractionation effects and inclusion type. A possible correlation between isotope fractionation and rare earth element abundance patterns is discussed.     

Sedimentology,palaeoenvironments and biostratigraphy of the Pliocene–Pleistocene carbonate platform of Grande‐Terre (Guadeloupe,Lesser Antilles forearc)

Pliocene and Pleistocene deposits from Grande‐Terre (Guadeloupe archipelago, French Lesser Antilles) provide a remarkable example of an isolated carbonate system built in an active margin setting, with sedimentation controlled by both rapid sea‐level changes and tectonic movements. Based on new field, sedimentological and palaeontological analyses, these deposits have been organized into four sedimentary sequences (S1 to S4) separated by three subaerial erosion surfaces (SB0, SB1 and SB2). Sequences S1 and S2 (‘Calcaires inférieurs à rhodolithes’) deposited during the Late Zanclean to Early Gelasian (planktonic foraminiferal Zones PL2 to PL5) in low subsidence conditions, on a distally steepened ramp dipping eastward. Red algal‐rich deposits, which dominate the western part of Grande‐Terre, change to planktonic foraminifer‐rich deposits eastward. Vertical movements of tens of metres were responsible for the formation of SB0 and SB1. Sequence S3 (‘Formation volcano‐sédimentaire’, ‘Calcaires supérieurs à rhodolithes’ and ‘Calcaires à Agaricia’) was deposited during the Late Piacenzian to Early Calabrian (Zones PL5 to PT1a) on a distally steepened, red algal‐dominated ramp that changes upward into a homoclinal, coral‐dominated ramp. Deposition of Sequence S3 occurred during a eustatic cycle in quiet tectonic conditions. Its uppermost boundary, the major erosion surface SB2, is related to the Cala1 eustatic sea‐level fall. Finally, Sequence S4 (‘Calcaires à Acropora’) probably formed during the Calabrian, developing as a coral‐dominated platform during a eustatic cycle in quiet tectonic conditions. The final emergence of the island could then have occurred in Late Calabrian times.     

The Morávka meteorite fall: 3. Meteoroid initial size,history, structure,and composition

Abstract— The properties and history of the parent meteoroid of the Morávka H5–6 ordinary chondrites have been studied by a combination of various methods. The pre‐atmospheric mass of the meteoroid was computed from fireball radiation, infrasound, seismic signal, and the content of noble gases in the meteorites. All methods gave consistent results. The best estimate of the pre‐atmospheric mass is 1500 ± 500 kg. The fireball integral bolometric luminous efficiency was 9%, and the acoustic efficiency was 0.14%. The meteoroid cosmic ray exposure age was determined to be (6.7 ± 1.0) × 10⁶ yr. The meteorite shows a clear deficit of helium, both ³He and ⁴He. This deficit can be explained by solar heating. Numerical backward integration of the meteoroid orbit (determined in a previous paper from video records of the fireball) shows that the perihelion distance was probably lower than 0.5 AU and possibly as low as 0.1 AU 5 Ma ago. The collision which excavated Morávka probably occurred while the parent body was on a near‐Earth orbit, as opposed to being confined entirely to the main asteroid belt. An overview of meteorite macroscopic properties, petrology, mineralogy, and chemical composition is given. The meteorites show all mineralogical features of H chondrites. The shock level is S2. Minor deviations from other H chondrites in abundances of trace elements La, Ce, Cs, and Rb were found. The ablation crust is enriched with siderophile elements.     

The isotopic composition of titanium in the Allende and Leoville meteorites

We describe the analytical techniques developed for the precise measurement of the titanium isotope abundances using a TiO⁺ ion beam. Terrestrial, lunar, and bulk meteorite samples yield identical results. Using a normalization to ${}^{46}\text{Ti}{}^{48}\text{Ti}$ for mass dependent isotope fractionation, we obtain the normal Ti composition: ${}^{46}\text{Ti}{}^{48}\text{Ti}\text{= 0.108548}$; ${}^{47}\text{Ti}{}^{48}\text{Ti}\text{= 0.099315 ± 0.000005}$; ${}^{49}\text{Ti}{}^{48}\text{Ti}\text{= 0.074463 ± 0.000004}$; ${}^{50}\text{Ti}{}^{48}\text{Ti}\text{= 0.072418 ± 0.000004}$ (2σ grand mean), taking ${}^{18}\text{O}{}^{16}\text{O}\text{= 0.002045}$ and ${}^{17}\text{O}{}^{16}\text{O}\text{= 0.00037}$. Measurements on thirteen coarse-grained and fine-grained Ca-Al-Ti-rich inclusions from the Allende and Leoville meteorites show the presence of widespread, significant, nonlinear isotope anomalies in the Ti isotopes which were not used for normalization. The data require the addition of at least three exotic components. The distinct correlation of non-linear effects for the most neutron-rich isotopes of Ca and Ti and the absence of substantial effects at ⁴⁶Ca in the FUN samples EK-1-4-1 and C-1 indicate that the effects reflect neutron-rich equilibrium or quasi-equilibrium nucleosynthetic processes in the outer layers of a supernova core. The results on Ca and Ti in conjunction with the isotopic effects on other elements (Mg, Sr, Ba, Nd, Sm) show that the samples represent mixtures of different nucleosynthetic components from distinctive processes (‘e’, ‘r’, ‘p’) which do not appear to be related to processes in the same stellar sites.