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W.M. Edmunds 《Journal of African Earth Sciences》1996,22(4):385-389
The scope for using hydrogeochemical techniques in water quality studies in Africa is reviewed as a background to a set of thematic papers. Water quality problems are emerging as a key issue in Africa either:
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i) in view of the pressures of man-made pollution on finite resources; or 2.
ii) the existence of regions with naturally induced geological problems, for example fluoride endemic areas.
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Groundwater recharge in an arid grassland as indicated by soil chloride profile and multiple tracers
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Previous studies have shown that shallow groundwater in arid regions is often not in equilibrium with near‐surface boundary conditions due to human activities and climate change. This is especially the case where the unsaturated zone is thick and recharge rate is limited. Under this nonequilibrium condition, the unsaturated zone solute profile plays an important role in estimating recent diffuse recharge in arid environments. This paper combines evaluation of the thick unsaturated zone with the saturated zone to investigate the groundwater recharge of a grassland in the arid western Ordos Basin, NW China, using the soil chloride profiles and multiple tracers (2H, 18O, 13C, 14C, and water chemistry) of groundwater. Whereas conventional water balance and Darcy flux measurements usually involve large errors in recharge estimations for arid areas, chloride mass balance has been widely and generally successfully used. The results show that the present diffuse recharge beneath the grassland is 0.11–0.32 mm/year, based on the chloride mass balance of seven soil profiles. The chloride accumulation age is approximately 2,500 years at a depth of 13 m in the unsaturated zone. The average Cl content in soil moisture in the upper 13 m of the unsaturated zone ranges from 2,842 to 7,856 mg/L, whereas the shallow groundwater Cl content ranges from 95 to 351 mg/L. The corrected 14C age of shallow groundwater ranges from 4,327 to 29,708 years. Stable isotopes show that the shallow groundwater is unrelated to modern precipitation. The shallow groundwater was recharged during the cold and wet phases of the Late Pleistocene and Holocene humid phase based on palaeoclimate, and consequently, the groundwater resources are nonrenewable. Due to the limited recharge rate and thick unsaturated zone, the present shallow groundwater has not been in hydraulic equilibrium with near‐surface boundary conditions in the past 2,500 years. 相似文献
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G. P. Mathlin A. C. Baker D. K. Churches M. G. Edmunds 《Monthly notices of the Royal Astronomical Society》2001,321(4):743-758
We construct a simple, robust model of the chemical evolution of galaxies from high to low redshift, and apply it to published observations of damped Lyman α quasar absorption line systems (DLAs). The elementary model assumes quiescent star formation and isolated galaxies (no interactions, mergers or gas flows). We consider the influence of dust and chemical gradients in the galaxies, and hence explore the selection effects in quasar surveys. We fit individual DLA systems to predict some observable properties of the absorbing galaxies, and also indicate the expected redshift behaviour of chemical element ratios involving nucleosynthetic time delays.
Despite its simplicity, our 'monolithic collapse' model gives a good account of the distribution and evolution of the metallicity and column density of DLAs, and of the evolution of the global star formation rate and gas density below redshifts z ∼3. However, from the comparison of DLA observations with our model, it is clear that star formation rates at higher redshifts ( z >3) are enhanced. Galaxy interactions and mergers, and gas flows very probably play a major role. 相似文献
Despite its simplicity, our 'monolithic collapse' model gives a good account of the distribution and evolution of the metallicity and column density of DLAs, and of the evolution of the global star formation rate and gas density below redshifts z ∼3. However, from the comparison of DLA observations with our model, it is clear that star formation rates at higher redshifts ( z >3) are enhanced. Galaxy interactions and mergers, and gas flows very probably play a major role. 相似文献
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The expulsion of metal-rich grains from collapsing protostars is considered, and it is concluded that stars of mass greater than 21M
could be significantly depleted in heavy metals during their formation. 相似文献
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