Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.     

Tectonic setting discrimination diagrams for terrigenous rocks: a comparison

An attempt is made to compare discrimination diagrams of the first (mid-1980s) and second (early 2010s) generations compiled using data for sedimentary successions of different ages. Our results suggest that the diagrams of different generations allow more or less correct discrimination only between the platform, rift, passive margin, and island arc settings. The data for collision sediments do not form separate fields in these diagrams.     

Paleoclimate changes in the late precambrian: Evidence from the upper precambrian section of the South Urals

The climatic impact on the formation of fine-grained rocks from the Riphean stratotype and Vendian Asha Group on the western slope of the South Urals during the time interval lasting approximately 1200 Ma is considered. It is shown that these rocks are largely represented by “tectonosilicate-dominated” shales. This feature combined with changes in the average K₂O/Al₂O₃ values disavows the hypothesis in (Kennedy et al., 2006), according to which the growth of free oxygen concentration in the Late Riphean and Vendian atmosphere was determined by gradual intensification of the organic carbon extraction from the biosphere by clays. The average values of the hydrolyzate module, chemical index of alteration (CIA), and several lithogeochemical parameters calculated for the Riphean and Vendian clayey rocks provide grounds for the conclusion that intensity of weathering in paleodrainage areas during the accumulation of the Upper Precambrian sedimentary successions was low. The curve reflecting changes of the average CIA values in the Upper Precambrian fine-grained siliciclastic rocks of the South Urals is similar to some extent with the “standard” CIA_correct. curve (GonzalezAlvarez and Kerrich, 2012). It is assumed that changes in microand macrobiotic communities during the Late Precambrian were controlled to a variable extent by climate fluctuations as well. At the same time, these fluctuations most likely left the chemical composition of water in the ocean virtually unchanged, which is evident from analysis of the redox conditions in the ocean and the distribution of primary producers with the average CIA_correct. and CIA values.     

Fine-Grained Aluminosiliciclastic Rocks of the Middle Riphean Stratotype Section in the Southern Urals: Formation Conditions,Composition and Provenance Evolution

General trends of the formation of Middle Riphean fine-grained aluminosiliciclastic rocks in the Bashkir Meganticlinorium are considered. It is shown that Yurmatinian shales do not contain any significant pyroclastic admixture. Judging from the relatively constant Th/Cr ratio throughout the Yurmatinian section, the tectonic regime in the study territory during the early Middle Riphean is suggested to be rather stable. The main paleoclimatic indices and indicators of the pelitic material maturity (CIA, CIW, IVC, PIA, and Ce/Y) suggest that paleodrainage systems in the early Middle Riphean were dominated by humid climate that gave way to the arid or semiarid type in the middle Yurmatinian. The low Mo/Mn ratio and some other indicators of redox conditions in shales from all Yurmatinian lithostratigraphic units show that no explicit reducing conditions existed in the basin during the early Middle Riphean. The shales were characterized by the increase in K₂O/Al₂O₃ ratio, gradual enrichment in REE, and growth of LREE/HREE and La_N/Yb_N ratios toward the middle Yurmatinian, indicating the gain of an appreciable amount of slightly weathered arkosic aluminosiliciclastic material in the sedimentary basin about 1220–1200 Ma ago. The REE distribution and the UCC- and AUC-normalized shale compositions suggest that the eroded upper crust was compositionally close to the UCC. The occurrence of mafic and ultramafic rocks is also inferred. Data points of Yurmatinian shales plotted in the Cr–Ni, Eu/Eu*–Gd_N/Yb_N, and (La/YB)_N–Yb_N diagrams are localized between the fields of Upper Archean and post-Archean rocks or within the latter field. Hence, post-Archean igneous and metamorphic complexes prevailed in paleodrainage systems of the early Middle Riphean. This is also confirmed by the model Nd ages.     

Sedimentological/Palaeogeographic Data as Fundamental Building Blocks of the DDE Project:Critical Underpinning of Reconstructing Deep-time Earth Systems

正1 Introduction Sedimentary rocks archive important information for understanding how the earth system operates and how life and environments have evolved through earth history.Properly identifying characteristics of sedimentary rocks,along with the subsequent interpretation of depositional processes and sedimentary environments in a basin or locality,are fundamental to inter-basinal correlation of sedimentary successions as well as to understanding and deconvolving regional and global processes     

Variations of the 238U/235U Isotope Ratio in Metasedimentary Rocks and Evidence of Changes in Sedimentation Conditions during the Ediacarian Period of the Neoproterozoic

Doklady Earth Sciences - The isotopic composition of uranium is a new geochemical indicator that facilitates reconstruction of the redox conditions of geological processes. In this paper the...     

The 238U/235U Ratio as an Indicator of Redox Conditions in the Ediacaran Paleobasin (Sequence of the Chaya River,Baikal–Patom Highland,Southern Part of Central Siberia)

Doklady Earth Sciences - Abstract—This article is devoted to a study of variations in the U isotopic composition (238U/235U) in the section of clastic–carbonate Ediacaran sediments...     

Paleozoic Age of Metaterrigenous Sequences of the Maksyutov Metamorphic Complex (Southern Urals): Results of U–Pb Dating of Detrital Zircons

Doklady Earth Sciences - The first U–Pb (LA–ICP–MS) isotope dating of detrital zircons from quartzites of two strata of the Maksyutov metamorphic complex (Southern Urals) was...