Metal transport, partition and fixation in drainage waters and sediments in carbonate terrain in Southeastern Ontario

Lake sediment composition as an indicator of mineralization within the catchment area has found widespread application in recent years, particularly in Canada. Results have indicated, however, the existence of varying relationships between lake sediment composition and mineralization resulting from local features of the limnological environment. Accordingly it was considered appropriate to examine the nature of metal transport in the lake and stream environment, the partitioning of metal between the stream waters and stream sediments and between lake waters and lake sediments to obtain some understanding of the factors that affect the lake sediment-mineralization relationship. This investigation was carried out over an area containing Pb-Zn occurrences of supposed “Mississippi-Valley type” in Grenville and Paleozoic bedrock in southeastern Ontario.The headwater drainage systems comprise active streams, swamps, beaver ponds and small lake-bog systems giving way downstream to open lakes. The beaver swamps and seasonal swamps act as drainage sinks for metals, restricting the extent of geochemical dispersion in drainage systems adjacent to mineralization. Selective extraction analysis of bog, stream and lake sediments indicates that metals are preferentially concentrated with amorphous iron oxides, which readily adsorb and complex lead and zinc and are stable in the alkaline environment common in swamps adjacent to carbonate-hosted lead-zinc mineralization. The accumulation of lead and zinc with amorphous iron oxides combined with the adsorbing and chelating action of organic matter on lead and zinc makes organic-rich sediments from these small swampy areas an excellent sample medium for reflecting local mineralization. Down drainage anomalies of these elements can be accentuated by selective analysis for the amorphous iron oxide-held metal, involving selective extraction techniques.In contrast, within larger lake systems, the analysis of water samples indicates that geochemical dispersion in surface waters in the high pH environment (pH = 8.0) associated with the carbonate-hosted lead-zinc deposits is extremely restricted. In this environment, anomalous metal contents in lake water were not evident in lakes adjacent to mineralization, while anomalous lake sediment compositions exist only in lakes immediately adjacent to Pb-Zn mineralization and do not extend down the drainage system. The restricted dispersion necessitates basing geochemical reconnaissance surveys on collection and analysis of samples from the headwater organic-rich swamps at a higher sample density and resulting higher cost than in areas where a lower sample density is acceptable due to a wider dispersion.     

Assessment of the LandStar Real-Time DGPS Service under Several Operational Conditions

LandStar is a differential global positioning service (DGPS) that provides 24-h real-time positioning for various applications on land, water, and air in North America, Australia, New Zealand, Europe, and Africa. Its focus is on real-time applications requiring a submeter positioning capability such as agriculture, forestry, Geospatial Information Systems (GIS), survey/mapping, and land/vehicular navigation. LandStar uses a Wide Area Network of reference stations to derive DGPS corrections to model the variation of GPS error sources over a large area. These model parameters are used by the Virtual Reference Station processors to calculate standard corrections that are available for all predefined locations in the network. The corrections are transmitted to the user by L-band satellite communication in the standard RTCM SC104 DGPS correction format. This article investigates the performance of the LandStar Mk III system under various operational conditions and assesses its performance in both static and kinematic modes. Four field tests were conducted during 12 months that tested the sysem in clear static and kinematic conditions as well as suboptimal environments associated with low and heavy foliage conditions. Both the accuracy and availability of the system under these conditions is investigated, with an emphasis on whether the above variables are caused by the LandStar system differential corrections, the GPS measurements, or a combination of both. ? 1999 John Wiley & Sons, Inc.     

Directional sea spectrum determination using HF Doppler radar techniques

Second-order features in HF radar Doppler spectral data are compared with a theoretical model of the radar spectrum. The model is the corner reflector double-scatter model which employs a more realistic directional sea spectrum model than those used in earlier works. It includes a frequency-dependent angular spreading function and assumes the existence of spectral energy over a full360degarising from an apparent second-order wave-wave interaction. Comparison is made with ground wave data collected at the NRL/NOAA/ITS San Clemente Island HF radar.     

Petrologic constraints on rift-zone processes

The Puu Oo eruption in the middle of Kilauea volcano's east rift zone provides an excellent opportunity to utilize petrologic constraints to interpret rift-zone processes. Emplacement of a dike began 24 hours before the start of the eruption on 3 January 1983. Seismic and geodetic evidence indicates that the dike collided with a magma body in the rift zone. Most of the lava produced during the initial episode of the Puu Oo eruption is of hybrid composition, with petrographic and geochemical evidence of mixing magmas of highly evllved and more mafic compositions. Some olivine and plagioclase grains in the hybrid lavas show reverse zoning. Whole-rock compositional variations are linear even for normally compatible elements like Ni and Cr. Leastsquares mixing calculations yield good residuals for major and trace element analyses for magma mixing. Crystal fractionation calculations yield unsatisfactory residuals. The highly evolved magma is similar in composition to the lava from the 1977 eruption and, at one point, vents for these two eruptions are only 200 m apart. Possibly both the 1977 lava and the highly evolved component of the episode 1 Puu Oo lava were derived from a common body of rift-zone-stored magma. The more mafic mixing component may be represented by the most mafic lava from the January 1983 eruption; it shows no evidence of magma mixing. The dike that was intruded just prior to the start of the Puu Oo eruption may have acted as a hydraulic plunger causing mixing of the two rift-zone-stored magmas.