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The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ34S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ34S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ34S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ34Spyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe3+ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H2O, not O2. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   
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The coupling of physics and biology was examined along a 160 km long transect running out from the north coast of South Georgia Island and crossing the Southern Antarctic Circumpolar Current Front (SACCF) during late December 2000. Surface and near surface potential TS properties indicated the presence of three water types: a near-shore group of stations characterised by water which became progressively warmer and fresher closer to South Georgia, an offshore grouping in which sea surface temperatures and those at the winter water level were relatively warm (1.8°C and 0.5°C, respectively), and a third in which surface and winter water temperatures were cooler and reflected the presence of the SACCF. The transect bisected the SACCF twice, revealing that it was flowing in opposite directions, north-westward closest to South Georgia and south-eastwards at its furthest point from the island. The innermost limb was a narrow intense feature located just off the shelf break in 2000–3500 m of water and in which rapid surface baroclinic velocities (up to 35 cm s−1) were encountered. Offshore in the outermost limb, shown subsequently to be a mesoscale eddy that had meandered south from the retroflected limb of the SACCF, flow was broader and slower with peak velocities around 20 cm s−1. Chlorophyll a biomass was generally low (<1 mg m−3) over much of the transect but increased dramatically in the region of the innermost limb of the SACCF, where a deepening of the surface mixed layer was coincident with a subsurface chlorophyll maximum (7.4 mg m−3) and elevated concentrations down to 100 m. The bloom was coincident with depleted nutrient concentrations, particularly silicate, nitrate and phosphate, and although ammonium concentrations were locally depleted the bloom lay within an elevated band (up to 1.5 mmol m−3) associated with the frontal jet. Increased zooplankton abundance, higher copepod body carbon mass and egg production rates all showed a strong spatial integrity with the front. The population structure of the copepods Calanoides acutus and Rhincalanus gigas at stations within the front suggested that rather than simply resulting from entrainment and concentration within the jet, increased copepod abundance was the result of development in situ. Estimates of bloom duration, based on silicate and carbon budget calculations, set the likely duration between 82 and 122 d, a figure supported by the development schedule of the two copepod species. Given this timescale, model outputs from FRAM and OCCAM indicated that particles that occurred on the north side of South Georgia in December would have been in the central-southern Scotia Sea 2–3 months earlier, probably in sea ice affected regions.  相似文献   
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The Nanga Parbat Himalaya presents some of the greatest relief on Earth, yet sediment production and denudation rates have only been sporadically addressed. We utilized field measurements and computer models to estimate bank full discharge, sediment transport, and denudation rates for the Raikot and Buldar drainage basins (north slope of Nanga Parbat) and the upper reach of the Rupal drainage basin (south slope).The overall tasks of determining stream flow conditions in such a dynamic geomorphic setting is challenging. No gage data exist for these drainage basins, and the overall character of the drainage basins (high relief, steep flow gradients, and turbulent flow conditions) does not lend itself to either ready access or complete profiling.Cross-sectional profiles were surveyed through selected reaches of these drainage basins. These data were then incorporated into software (WinXSPRO) that aids in the characterization (stage, discharge, velocity, and shear stress) of high altitude, steep mountain stream conditions.Complete field measurements of channel depths were rarely possible (except at several bridges where the middle of the channel could actually be straddled and probed) and, when coupled with velocity measurements, provided discrete points of field-measured discharge calculations. These points were then used to calibrate WinXSPRO results for the same reach and provided a confidence level for computer-generated results.Flow calculations suggest that under near bank full conditions, the upper Raikot drainage basin produces discharges of 61 cm and moves about 11,000 tons day−1 (9980 tons day−1) of sediment through its channel. Bank full conditions on the upper portion of the Rupal drainage basin generate discharges of 84 cm and moves only about 3800 tons day−1 (3450 tons day−1) of sediment. Although the upper Rupal drainage basin moves more water, the lower slope of the drainage basin (0.03) generates a much smaller shear stress (461 Pa) than does the higher slope (0.12) of the upper Raikot drainage basin (1925 Pa).Dissolved and suspended sediment loads were measured from water/sediment samples collected throughout the day and night over a period of 10 days at the height of the summer melt season but proved to be a minor variable in transport flux. Channel bed loads were measured using a pebble count method of bank material and then used to generate ratings curves of bed loads relative to discharge volumes. When coupled with discharge data and basin area, mean annual sediment yield and denudation rates for Nanga Parbat are produced. Denudation rates calculated in this fashion range from 0.2 mm year−1 in the slower, more sluggish Rupal drainage basin to almost 6 mm year−1 in the steeper, faster flowing Raikot and Buldar drainage basins.  相似文献   
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The Hope Slide, which occurred on January 9, 1965, involved an estimated 47-Mm3 of meta-volcanics and intrusive rocks. Previous workers reported the presence of tectonic structures (faults and shear zones) along the failure surface at the Hope Slide. These tectonic features were investigated in detail to assess their effects on rock-mass quality and the related implications for slope stability. This paper integrates basic field and laboratory concepts from structural and engineering geology. Subdividing the failure area into structural domains allowed distinct discontinuity sets to be associated with specific tectonic structures. The Geological Strength Index (GSI) was used to estimate the rock-mass damage related to the tectonic structures. Low GSI values were seen to outline tectonic damage zones. Point-load tests were used to characterise the compressive strength of rocks adjacent to the tectonic structures. Strength anisotropy, tentatively attributed to damage caused by a large shear zone, was observed in greenstone samples. Seepage zones along the failure surface were observed preferentially along shallow discontinuities that dipped downslope and in rock masses of good quality (GSI > 40). An alternative morphology of the slope failure is proposed by distinguishing between the extent of the surficial damage due to the rock-slope failure and the zone of failed material (depletion zone). For the first time, a kinematic mechanism for the Hope Slide is proposed, based on a preliminary 3-dimensional block model. A pre-1965 DEM was produced from estimates of material lost and gained as reported by previous workers. The pre-1965 DEM revealed that the tectonic structures recognised during fieldwork bounded the material that failed in the 1965 event.  相似文献   
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Although the 1963 Vajont Slide in Italy has been extensively studied for over 50 years, its regional geological and geomorphological context has been neglected. In this paper, we use field observations and remote sensing data to elucidate the interaction between endogenic and exogenic processes that brought the north slope of Monte Toc to failure. We present the first detailed pre- and post-failure engineering geomorphology maps of the slide area. The maps delineate two main landslide blocks, several sub-blocks, compressional and extensional zones, and secondary failures in the deposit. The maps provide new insights into the kinematics, dynamics and evolution of the slide. Finally, we discuss the origin of Vajont Gorge and a prehistoric failure that occurred at the same location as the 1963 slide. We propose, as part of a newly developed multi-stage landscape evolution sequence, that the prehistoric failure was a deep-seated gravitational slope deformation (sackung) that initiated during deglaciation and continued to slowly move until the catastrophic failure in 1963. We argue that the gorge was created by these deep-seated slow movements.  相似文献   
9.
Overabundance of white-tailed deer is a pervasive problem across the United States. Deer are blamed for increased risk of auto accidents, tick-borne diseases, and overbrowsing of native species. Lethal management techniques, cited as cost-effective and humane, are commonly employed for herd management. However, the approach frequently sparks outrage among various stakeholders who feel killing of animals is unjustified and prefer nonlethal measures. Wildlife managers then face the challenge of communicating with the public to build policy support for lethal management. The Narrative Policy Framework was used to test the effects of differing narratives on public opinion for lethal deer management. Results indicated narratives were influential in shifting attitudes toward and support for a proposed sharpshooting policy even in some cases where respondents were already familiar with the issue and held a previous opinion. This study also supported the utility of the Narrative Policy Framework for examining human dimensions of wildlife issues.  相似文献   
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Various network model creation algorithms have been introduced to demonstrate a better approximation of the actual walking pattern and to provide a better wayfinding guide. However, it is under‐investigated which algorithm creates the most appropriate indoor navigation network model in the context of wayfinding applications. Due to the lack of discussion, some studies unconsciously extended an algorithm designed for creating an outdoor navigation network model to indoor space applications. This is problematic because indoor space has different spatial contexts from outdoor space, such as non‐linear space and no‐designated walking space. Our solution is to select five well‐known algorithms that have been introduced, to reproduce the algorithm for the automated construction of the indoor navigation network model, and to evaluate the applicability of algorithms for indoor wayfinding applications. This article compares the quality of wayfinding results from the output of the indoor navigation network model against two criteria: route efficiency (i.e., length) and route simplicity (i.e., number of directions). Our statistical analysis illustrates that the visibility graph algorithm is the most appropriate for indoor wayfinding applications.  相似文献   
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