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排序方式: 共有157条查询结果,搜索用时 15 毫秒
1.
Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH3)63+ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation. 相似文献
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Delphine PaillerEdouard Bard Frauke RostekYan Zheng Richard MortlockAlexander van Geen 《Geochimica et cosmochimica acta》2002,66(5):849-865
Authigenic metals (uranium, cadmium, and molybdenum), organic carbon (OC) and total C37 alkenone (totC37) concentrations were measured for the last 350 kyr in core MD900963, located in the eastern equatorial Arabian Sea. Authigenic metal concentrations on a carbonate-free basis range between 1 and 17 ppm, 0.5 and 6 ppm, and 0.5 and 4 ppm for U, Cd, and Mo, respectively. The profiles are characterized by well-defined 23 kyr cycles between oxic and mildly suboxic conditions. The redox-sensitive metal profiles also follow variations in the concentrations of OC (0.2-0.9%) and alkenones (0.2-6.7 ppm). The coupled variations in inorganic and organic constituents are attributed to a 23-kyr cycle in primary production above site MD900963, as suggested by clear correlations with independent micropaleontologic proxies (primary productivity indices based on foraminifera and coccoliths and fragmentation of foraminiferal shells). The 23-kyr cycles do appear to be primarily driven by productivity rather than changes in bottom water oxygen. Comparison with other records indicates that if this interpretation is correct, productivity variations across much of the Indian Ocean have been dominated by precessional forcing, with high productivity in phase with low summer insolation in the Northern Hemisphere. This interpretation contrasts with the traditional attribution of enhanced productivity in the Indian Ocean with periods of high summer insolation. 相似文献
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Bruno Dhuime Delphine Bosch Olivier Bruguier Renaud Caby Carlos Archanjo 《Comptes Rendus Geoscience》2003,335(15):1081-1089
The Borborema Province (BP) of northeastern Brazil is a complex crustal assemblage, which has undergone a polycyclic evolution during the Proterozoic. In the Piancó-Alto Br??gida belt, a metamorphosed leucosome vein inserted in amphibolites has a trace element pattern suggesting a T-MORB protolith. Apatites yield a REE pattern indicating growth in equilibrium with garnet, thus pointing to its metamorphic origin. UPb analyses yield an age of 540±5 Ma interpreted as a cooling age following amphibolite facies regional metamorphism associated with granitic emplacement at ca. 580 Ma. The resulting slow cooling rates (ranging from ca. 2.5 to 5 °C Ma?1) are consistent with underplating of mafic magmas, or crustal thickening caused by nappe stacking, as possible processes governing the metamorphic evolution of the BP. To cite this article: B. Dhuime et al., C. R. Geoscience 335 (2003). 相似文献
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Corinne Sonzogni Edouard Bard Frauke Rostek Denis Dollfus Antoni Rosell-Melé Geoffrey Eglinton 《Quaternary Research》1997,47(3):344-355
We compare alkenone unsaturation ratios measured on recent sediments from the Indian Ocean (20°N–45°S) with modern sea oceanographic parameters. For each of the core sites we estimated average seasonal cycles of sea surface temperature (SST) and salinity, which we then weighted with the seasonal productivity cycle derived from chlorophyll satellite imagery. The unsaturation index (U37K′) ranges from 0.2 to 1 and correlates with water temperature but not with salinity. TheU37K′versus SST relationship for Indian Ocean sediments (U37K′= 0.033 SST + 0.05) is similar to what has been observed for core tops from the Pacific and Atlantic oceans and the Black Sea. A global compilation for core tops givesU37K′= 0.031 T + 0.084 (R= 0.98), which is close to a previously reported calibration based on particulate organic matter from the water column. For temperatures between 24° and 29°C, however, the slope seems to decrease to about 0.02U37K′unit/°C. For Indian Ocean core tops, the ratios of total C37alkenones/total C38alkenones and the slope of theU37K′-SST relationship are similar to those previously observed for cultures ofEmiliania huxleyibut different from those previously published forGephyrocapsa oceanica.EitherE. huxleyiis a major producer of alkenones in the Indian Ocean or strains ofG. oceanicaliving in the northern Indian Ocean behave differently from the one cultured. In contrast with coccolithophorid assemblages, the ratios of C37alkenones to total C38alkenones lack clear geographic pattern in the Indian Ocean. 相似文献
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Edouard Bard Grant M. Raisbeck Franoise Yiou Jean Jouzel 《Earth and Planetary Science Letters》1997,150(3-4):453-462
For about the last 30 years it has been recognized that the high frequency component of the tree rings 14C/12C record is dominated by the modulation of the cosmic ray flux by the solar wind. In particular, it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric 14C/12C. During the last millennium other periods of high 14C/12C values were observed but their solar origin is still debatable. In the present work we compare these fluctuations with an independent record of cosmogenic 10Be measured in ice from the South Pole to check the solar origin of the observed 14C/12C variations. In order to compare quantitatively the results obtained on 10Be and 14C, it is necessary to take into account the different behaviour of these two cosmogenic isotopes, and especially the damping effect of the carbon cycle in the case of 14C. As an input to a 12-box numerical model we used the relative fluctuations of the 10Be concentrations record measured in South Pole ice and converted it into a synthetic 14C record. We took into account the fact that 10Be modulation is enhanced in polar regions due to the orientation of the geomagnetic field. As expected, the fluctuations of the modelled 14C record are much smaller (a factor of 20) than those observed for the raw 10Be record. In addition, the variations are smoother and shifted in time by a few decades. The 10Be-based 14C variations closely resemble the 14C measurements obtained on tree rings (R = 0.81). In particular, it is easy to identify periods of maximal 14C/12C which correspond to solar activity minima centred at about 1060, 1320 (Wolf), 1500 (Spörer), 1690 (Maunder) and 1820 (Dalton) yr A.D. Cross-correlation calculations suggest that there is no significant lag between the 10Be-based 14C and the tree-ring 14C records. Our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium. 相似文献
8.
Quality Assessment of Cartographic Generalisation 总被引:2,自引:1,他引:2
Sylvain Bard 《Transactions in GIS》2004,8(1):63-81
This paper proposes a methodology to assess the quality of cartographic generalisa‐tion, which consists of representing geographic space in a simplified way according to the scale and the objectives of the intended map. The automation of this process makes the derivation of data easier, but the quality of the results is often not evaluated. This paper proposes an assessment model based on: (1) characterisation of the data in their initial and final states at different levels of analysis; (2) a data quality assessment by comparison of the two characterisations; and (3) aggregation of the various assessment results to summarise data quality. The assessment algorithm has been implemented and the method has been tested to assess the generalisation of a small urban area. A visualisation tool for assessment of the results has been developed to validate the generalisation evaluation. The results of the research are presented and discussed at the end of the paper. 相似文献
9.
An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry 下载免费PDF全文
Bouchaïb Tibari Arnaud Vacherat Martin Stab Raphaël Pik Delphine Yeghicheyan Pascal Hild 《Geostandards and Geoanalytical Research》2016,40(3):365-375
Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure. 相似文献
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