Study on electric variations of media in epicentral area by geomagnetic transfer functions

ＳｔｕｄｙｏｎｅｌｅｃｔｒｉｃｖａｒｉａｔｉｏｎｓｏｆｍｅｄｉａｉｎｅｐｉｃｅｎｔｒａｌａｒｅａｂｙｇｅｏｍａｇｎｅｔｉｃｒａｎｓｆｅｒｆｕｎｃｔｉｏｎｓＸｉａｏ－ＰｉｎｇＺＥＮＧ；（曾小苹）Ｙｕｎ－ＦａｎｇＬＩＮＩ；（林云芳）Ｚｈｏｎｇ－ＪｉｅＺＨ...     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

冀北滦平地区中生代火山岩地层锆石U-Pb测年及启示

在冀北—辽西地区, 冀北的滦平地区是中生代地层最为齐全, 也是唯一的晚中生代沉积作用基本连续的地区.许多研究者认为该地区的土城子组与张家口之间存在着J₃—K₁界线和中生代的构造转换界面.该地区分布的主要中生代地层自下而上依次为髫髻山组、土城子组、张家口组、大北沟组、大店子组和西瓜园组.通过LAICPMS方法的锆石UPb测年, 获得了该地区中生代火山岩地层的年代格架, 即髫髻山组的顶界年龄为(162.8±3.2)Ma, 土城子组形成的主体年代范围是(142.6±1.3)~(136.4±1.9)Ma, 张家口组形成的年代范围是(135.7±1.8)~(135.2±2.3)Ma, 大店子组顶部安山岩的年龄是(131.4±3.7)~(130.2±3.0)Ma.锆石的稀土元素分析表明: 土城子组中锆石的稀土元素特征与张家口组中锆石的特征一致, 而与髫髻山组中的锆石有较大的区别.综合以上分析数据及野外地质特征可以得出以下结论: (1)该地区的土城子组与髫髻山组之间不仅时间间隔较长, 而且二者中火山岩的源区也有较大的区别; 土城子组与张家口组之间不仅时间上基本连续, 而且二者中火山岩的源区也有明显的一致性.这就表明了滦平地区的土城子组与张家口组是同一地质背景下的产物, 即该地区二者之间应不存在J₃—K₁界面和构造转换界面.(2)滦平地区大店子组顶部火山岩在年代上与辽西北票—义县地区的义县组底部、辽西凌源地区的张家口组顶部基本相当.      

Simultaneous determinations of U–Pb age,Hf isotopes and trace element compositions of zircon by excimer laser-ablation quadrupole and multiple-collector ICP-MS

We describe an in situ method for simultaneous measurement of U–Pb–Hf isotopes and trace element compositions of zircons using a quadrupole and multiple-collector inductively-coupled-plasma mass spectrometer (Q-ICP-MS and MC-ICP-MS, respectively) connected to a single excimer laser-ablation system. A laser-generated zircon aerosol was split behind the ablation cell into two transport tubes via a Y-shaped connector and simultaneously introduced into the two mass spectrometers. Hafnium isotopes were measured on the MC-ICP-MS instrument, while U–Pb ages and trace element compositions were determined using the Q-ICP-MS. The precision and accuracy of this method was evaluated using six well-known and widely used zircon standards (91500, Temora-2, GJ-1, Mud Tank, BR266 and Monastery). Analyses were carried out using spot sizes of 32, 44 and 60 μm. For the 44 and 60 μm spot, the resulting U–Pb ages, Hf isotopic and rare earth element (REE) compositions of these six zircons agree with recommended/reported values within 2σ error. The difference in relative standard deviations (RSD) of ²⁰⁶Pb/²³⁸U ages between split-flow measurements and those obtained separately on the Q-ICP-MS is within ～ 20% for 91500, Temora-2 and GJ-1, and ～ 60% for Mud Tank (due to its lower U and Pb concentrations). Our method provides a precise approach for determining the U–Pb age and the Hf isotopic and trace element compositions of zircon within a single ablation event. This is in particular important for analysis of zircons that are small or contain complicated zoning patterns. Finally, the REE composition of zircon BR266 is more homogeneous than other zircons and could be a suitable standard by which to benchmark new standards for microprobe analyses of zircons.     

川东南焦石坝页岩气区现今地温场特征

四川盆地是我国重要的含油气区,关于盆地现今地温场的工作,前人已经做过一些研究.而对于近年来页岩气勘探取得突破性进展的川东南焦石坝地区,现今地温场的研究工作甚少.本文基于川东南高陡褶皱带焦石坝页岩气区新增的3口钻井的稳态测温数据和118块岩石样品热导率数据,计算了研究区的地温梯度和大地热流值.结合前人的研究成果,编制了研究区大地热流等值线图.结果表明,焦石坝页岩气区地温梯度介于24~34℃/km,大地热流值介于60~70mW·m~(-2)之间,与川中古隆起相似,属于地温高异常区.地温高异常缘于隆起区相对高的岩石热导率引起的浅部热流的重新分配.其次,与位于研究区东侧边界的齐岳山大断裂在燕山和喜山期的构造引起的热液活动有关.焦石坝页岩气区地温高异常对页岩气的解吸附速率具有促进作用,对提高采收率具有一定意义.     

云南天文台丽江高美古和昆明的大气视宁度研究

研究云南天文台昆明凤凰山和丽江高美古两地点的大气视宁度。利用云南天文台于1994年建立的3孔较差视宁度监视仪（3孔DIMM），对这两个地点的视宁度对比观测。还利用云南天文台的1米望远镜所得到的视宁度与3孔DIMM所测的视宁度进行对比。1米望远镜和3孔DIMM同时观测了7个晚上，各取得308组数据，它们的视宁度平均分别为0．90〃和0．84〃。还讨论了3孔DIMM采用不同曝光时间对视宁度测量值的影响，从实验得出3孔DIMM采用20ms曝光比采用8ms曝光所测视宁度的值要好15％左右。从1995年5月－1996年12月，对丽江高美古和昆明凤凰山二地进行了视宁度的对比观测。在高美古和昆明分别观测了234夜和256夜，观测结果是两个点的视宁度平均；丽江为0．70〃，昆明为0．95〃，同时也统计了两个点的月平均视宁度和最好夜的视宁度，并讨论了两地视宁度随时间的变化规律。     

盐城国家级自然保护区人工湿地丹顶鹤的分布动态

通过盐城国家级自然保护区内生态工程及水产养殖区、水稻田、芦苇茬、盐田扬水滩等人工湿地丹顶鹤(Grusjaponensis)的分布动态调查结果,分析出丹顶鹤的最佳生境,进而提出对该种群与栖息地的管理举措。该项工作主要借助望远镜、照相机监测,采用直接计数法统计数量,历史数据则引用参考文献。结果表明:各类人工湿地中丹顶鹤的分布数量为528只,已超过越冬总数(967只)的一半,达到54.1%。其中生态工程及水产养殖区为丹顶鹤最佳生境,其次分别为水稻田、芦苇茬和盐田扬水滩。根据分布动态调查结果,对未来丹顶鹤的分布趋势进行了预测,并提出了管理措施。     

北秦岭西段冥古宙锆石(4.1～3.9Ga)年代学新进展

2007年王洪亮等报道在北秦岭西段火山岩中获得一粒年龄为4079±5Ma的冥古宙捕虏锆石。之后,对这一发现开展了深入的调查研究,我们除利用SHIMP技术方法对原4079Ma的锆石进行验证外,新获得了两粒~(207)Pb/~(206)Pb年龄为4007±29Ma和3908±45Ma捕获的变质成因锆石,表明早在4.0Ga已经有变质作用的发生,这或许说明在冥古宙时期地球已经具有相当规模和厚度的地壳。同时开展的岩石学研究表明,蕴含古老锆石的母岩属于火山碎屑熔岩类而不是火山熔岩。     

Zircon LA-ICP MS U-Pb Dating of the Longkang Andesitic Ignimbrites from Jiuzhaigou： Evidence of the Mianlue Suture Westward Extension

Genesis of metasedimentary-volcanics outcroped in Kangxian-Pipasi-Nanping (康县-琵琶寺-南坪) tectonic zone is closely related with tectonic evolution of the Mianlue (勉略) Ocean. In the west end of Kangxian-Pipasi-Nanping tectonic zone, there are hundred meters of andesitic ignimbrites and tuffites. Zircon U-Ph dating on these volcanies has great significance to the tectonic implication of zircons from Longkang andesitic ignimbrites are magmatic genesis with oscillatory zoning and high U ((35-750) ppm), Th ((311-717) ppm) contents with high Th/U (0.44-1.30) ratios. The measured 206pb/238U ratios are in good analytical precision, yielding a weighted mean age of (246±3) Ma (MSWD=2.6, n=12, 2σ). Some detrital zircons have also been observed, they have maximal concordia area. Combined with regional geology and the volcanic rocks in the studied area, the (246±3) Ma zircon U-Pb age suggests a Late Permian orogenic volcanism and provides important geochronology evidence for the Mianlue suture westward extension.     

http://www.sciencedirect.com/science/article/pii/S1674987114000607

The Qinling Complex of central China is thought to be the oldest rock unit and the inner core of the North Qinling Orogenic Belt （NQOB）. Therefore, the Qinling Complex is the key to understanding the pre- Paleozoic evolution of the NQOB. The complex, which consists of metagraywackes and marbles, un- derwent regional amphibolite-facies metamorphism. In this study, we constrained the formation age of the Qinling Complex to the period between the late Mesoproterozoic and the early Neoproterozoic （ca. 1062-962 Ma）, rather than the Paleoproterozoic as previously thought. The LA-ICP-MS data show two major metamorphic ages （ca. 499 and ca. 420-400 Ma） for the Qinling Complex. The former age is consistent with the peak metamorphic age of the high- and ultra-high pressure （HP-UHP） rocks in the Qinling Complex, indicating that both the HP-UHP rocks and their country rocks experienced intensive regional metamorphism during the Ordovician. The latter age may constrain the time of partial melting in the NQOB between the late Silurian and early Devonian. The Qinling Complex is mostly affiliated with subduction-accretion processes along an active continental margin, and should contain detritus deposited in a forearc basin.