Ductile-brittle transition in pre-Alpine amphibolite facies mylonites during evolution from water-present to water-deficient conditions (Mont Mary nappe, Italian Western Alps)

In the Austroalpine Mont Mary nappe (Italian Western Alps) discrete zones of mylonites–ultramylonites developed from coarse-grained, upper amphibolite facies metapelites of pre-Alpine age. The syn–mylonitic mineral assemblage is quartz–biotite–muscovite–plagioclase–garnet–sillimanite–ilmenite–graphite, and formed via the model hydration reaction: Grt₁+Kfs+H₂O=Bt₂+Ilm₂+Qtz+Ms± Sil .Grain-size reduction of about three orders of magnitude was accompanied by extensive recrystallization of all minerals except sillimanite, and by compositional changes of garnet and biotite. Deformation took place at temperatures of 510–580  °C under low-pressure conditions (0.25–0.45 GPa) and corresponds to the latest stages of pre-Alpine metamorphic evolution. The pre-Alpine mylonitization conditions were close to the brittle-ductile transition, as indicated by syn–mylonitic generation of pseudotachylytes and high differential stress inferred from quartz grain-size piezometry. The brittle-ductile behaviour at a relatively high temperature, and the absence of annealing textures in quartz aggregates, are suggestive of water-deficient conditions during mylonitization. These were accomplished through progressive consumption of water by syn–kinematic hydration reaction and by adsorption onto the greatly increased grain boundary area resulting from dynamic recrystallization.     

Integration of natural data within a numerical model of ablative subduction: a possible interpretation for the Alpine dynamics of the Austroalpine crust

A numerical modelling approach is used to validate the physical and geological reliability of the ablative subduction mechanism during Alpine convergence in order to interpret the tectonic and metamorphic evolution of an inner portion of the Alpine belt: the Austroalpine Domain. The model predictions and the natural data for the Austroalpine of the Western Alps agree very well in terms of P–T peak conditions, relative chronology of peak and exhumation events, P–T–t paths, thermal gradients and the tectonic evolution of the continental rocks. These findings suggest that a pre‐collisional evolution of this domain, with the burial of the continental rocks (induced by ablative subduction of the overriding Adria plate) and their exhumation (driven by an upwelling flow generated in a hydrated mantle wedge) could be a valid mechanism that reproduces the actual tectono‐metamorphic configuration of this part of the Alps. There is less agreement between the model predictions and the natural data for the Austroalpine of the Central‐Eastern Alps. Based on the natural data available in the literature, a critical discussion of the other proposed mechanisms is presented, and additional geological factors that should be considered within the numerical model are suggested to improve the fitting to the numerical results; these factors include variations in the continental and/or oceanic thickness, variation of the subduction rate and/or slab dip, the initial thermal state of the passive margin, the occurrence of continental collision and an oblique convergence.     

C-O-H-S fluid composition and oxygen fugacity in graphitic metapelites

Abstract C-O-H fluid produced by the equilibration of H₂O and excess graphite must maintain the atomic H/O ratio of water, 2:1. This constraint implies that all thermodynamic properties of the fluid are uniquely determined at isobaric-isothermal conditions. The O₂, H₂O and CO₂ fugacities (fo₂, f_H2O and f_CO2) of such fluids have been estimated from equations of state and fit as a function of pressure and temperature. These fugacities can be taken as characteristic for graphitic metamorphic systems in which the dominant fluid source is dehydration, e.g. pelitic lithologies. Because there are no compositional degrees of freedom for graphite-saturated fluids produced entirely by dehydration, the variance of the dehydration process is not increased in comparison with that in non-graphitic systems. Thus, compositional ‘buffering’of C-O-H fluids by dehydration equilibria, a common petrological model, requires that redox reactions, decarbonation reactions or external, H/O ± 2, fluid sources perturb the evolution of the metamorphic system. Such perturbations are not likely to be significant in metapelitic environments, but their tendency will be to increase the f_O2 of the fluid phase. At high metamorphic grades, pyrite desulphidation reactions may cause a substantial reduction of f_H2O and slight increases in f_O2 and f_CO2 relative to sulphur-free fluid. At low metamorphic grade, sulphur solubility in H/O ± 2 fluids is so low that pyrite decomposition must occur by sulphur-conserving reactions that cause iron depletion in silicates, a common feature of sulphidic pelites. With increasing temperature and sulphur solubility, pyrite desulphidation may be driven by dehydration reactions or infiltration of H₂O-rich fluids. The absence of magnetite and the assemblages carbonate + aluminosilicate or pyrite + pyrrhotite + ilmenite from most graphitic metapelites is consistent with an H/O = 2 model for GCOH(S) fluid. For graphitic rocks in which such a model is inapplicable, a phase diagram variable that defines the H/O ratio of GCOH(S) fluid is more useful than the conventional f_O2 variable.     

Andalusite-bearing veins at Vedrette di Ries (eastern Alps, Italy): fluid phase composition based on fluid inclusions

Abstract Andalusite-bearing veins formed during contact metamorphism in the aureole of the Vedrette di Ries tonalite. In the veins, quartz crystals that are completely armoured by andalusite or that occur in strain shadow areas contain three generations of fluid inclusions: low-salinity H₂O-CO₂-CH₄ mixtures with CH₄/(CO₂+ CH₄) ± 0.35 (type A); low-salinity aqueous fluids (type B); H₂O-free, CO₂-CH₄ fluids with the same carbonic speciation as A (type C). Carbonic types A and C typically have a dark appearance, which is attributed to graphite coatings on inclusion walls. Microstructural analysis of the host quartz and calculated densities indicate that type A inclusions were likely trapped during vein formation. These inclusions underwent strain-assisted re-equilibration during cooling that resulted in density increases without change of composition. After the rocks had cooled below about 350 ° C, type C inclusions appear to have formed from one of the immiscible fractions after unmixing of the H₂O-CO₂-CH₄ fluid mixtures. Aqueous type B inclusions, apparently trapped between 225 and 350 ° C, could represent an independent fluid, or could be the H₂O-rich fraction of unmixed type A fluids. Taking account of the uncertainties, the composition and density of the complex type A inclusion fluids are in good agreement with the properties of primary fluids calculated from the petrological data. The fluid inclusion data support the model of vein formation by hydrofracturing as a result of dehydration of graphitic metapelites. These new results also demonstrate the importance of considering strain in the interpretation of metamorphic fluid inclusions.     

Mesophotic coral buildups in a prodelta setting (Late Eocene,southern Pyrenees,Spain): a mixed carbonate–siliciclastic system

Lower Priabonian coral bioherms and biostromes, encased in prodelta marls/clays, occur in the Aínsa‐Jaca piggyback basin, in the South Central Pyrenean zone. Detailed mapping of lithofacies and bounding surfaces onto photomosaics reveals the architecture of coral buildups. Coral lithosomes occur either isolated or amalgamated in larger buildups. Isolated lithosomes are 1 to 8 m thick and a few hundred metres wide; clay content within coral colonies is significant. Stacked bioherms form low‐relief buildups, commonly 20 to 30 m thick, locally up to 50 m. These bioherms are progressively younger to the west, following progradation of the deltaic complex. The lowermost skeletal‐rich beds consist of bryozoan floatstone with wackestone to packstone matrix, in which planktonic foraminifera are abundant and light‐related organisms absent. Basal coral biostromes, and the base of many bioherms, consist of platy‐coral colonies ‘floating’ in a fine‐grained matrix rich in branches of red algae. Corals with domal or massive shape, locally mixed with branching corals and phaceloid coral colonies, dominate buildup cores. These corals are surrounded by matrix and lack organic framework. The matrix consists of wackestone to packstone, locally floatstone, with conspicuous red algal and coral fragments, along with bryozoans, planktonic and benthonic foraminifera and locally sponges. Coral rudstone and skeletal packstone, with wackestone to packstone matrix, also occur as wedges abutting the buildup margins. Integrative analysis of rock textures, skeletal components, buildup anatomy and facies architecture clearly reveal that these coral buildups developed in a prodelta setting where shifting of delta lobes or rainfall cycles episodically resulted in water transparency that allowed zooxanthellate coral growth. The bathymetric position of the buildups has been constrained from the light‐dependent communities and lithofacies distribution within the buildups. The process‐product analysis used here reinforces the hypothesis that zooxanthellate corals thrived in mesophotic conditions at least during the Late Eocene and until the Late Miocene. Comparative analysis with some selected Upper Eocene coral buildups of the north Mediterranean area show similarities in facies, components and textures, and suggest that they also grew in relatively low light (mesophotic) and low hydrodynamic conditions.     

Sequence stratigraphy in the context of rapid regional uplift and high‐amplitude glacio‐eustatic changes: the Pleistocene Cutro Terrace (Calabria,southern Italy)

The Cutro Terrace is a mixed marine to continental terrace, where deposits up to 15 m thick discontinuously crop out in an area extending for ca 360 km² near Crotone (southern Italy). The terrace represents the oldest and highest terrace of the Crotone area, and it has been ascribed to marine isotope stage 7 (ca 200 kyr bp ). Detailed facies and sequence‐stratigraphic analyses of the terrace deposits allow the recognition of a suite of depositional environments ranging from middle shelf to fluvial, and of two stacked transgressive–regressive cycles (Cutro 1 and Cutro 2) bounded by ravinement surfaces and by surfaces of sub‐aerial exposure. In particular, carbonate sedimentation, consisting of algal build‐ups and biocalcarenites, characterizes the Cutro 1 cycle in the southern sector of the terrace, and passes into shoreface and foreshore sandstones and calcarenites towards the north‐west. The Cutro 2 cycle is mostly siliciclastic and consists of shoreface, lagoon‐estuarine, fluvial channel fill, floodplain and lacustrine deposits. The Cutro 1 cycle is characterized by very thin transgressive marine strata, represented by lags and shell beds upon a ravinement surface, and thicker regressive deposits. Moreover, the cycle appears foreshortened basinwards, which suggests that the accumulation of its distal and upper part occurred during forced regressive conditions. The Cutro 2 cycle displays a marked aggradational component of transgressive to highstand paralic and continental deposits, in places strongly influenced by local physiography, whereas forced regressive sediments are absent and probably accumulated further basinwards. The maximum flooding shoreline of the second cycle is translated ca 15 km basinward with respect to that of the first cycle, and this reflects a long‐term regressive trend mostly driven by regional uplift. The stratigraphic architecture of the Cutro Terrace deposits is the result of the interplay between regional uplift and high amplitude, Late Quaternary glacio‐eustatic changes. In particular, rapid transgressions, linked to glacio‐eustatic rises that outpaced regional uplift, favoured the accumulation of thin transgressive marine strata at the base of the two cycles. In contrast, the combined effect of glacio‐eustatic falls and regional uplift led to high‐magnitude forced regressions. The superposition of the two cycles was favoured by a relatively flat topography, which allowed relatively complete preservation of stratal geometries that record large shoreline displacements during transgression and regression. The absence of a palaeo‐coastal cliff at the inner margin of the terrace supports this interpretation. The Cutro Terrace provides a case study of sequence architecture developed in uplifting settings and controlled by high‐amplitude glacio‐eustatic changes. This case study also demonstrates how the interplay of relative sea‐level change, sediment supply and physiography may determine either the superposition of cycles forming a single terrace or the formation of a staircase of terraces each recording an individual eustatic pulse.     

A thermodynamic model for titanium and ferric iron solution in biotite

Recent crystallographic data indicate that in biotite Ti orders preferentially onto the M2 octahedral site rather than onto the M1 site as assumed in previous solution models for K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (KFMASHTO) biotite. In view of these data, we reformulate and reparameterize former biotite solution models. Our reparameterization takes into account Fe–Mg order–disorder and ferric iron contents of natural biotite as well as both natural and experimental observations on biotite Ti-content over a wide range of physicochemical conditions. In comparison with previous biotite models, the new model reproduces the Ti-content and stability field of biotite as constrained by experiments with significantly better accuracy. The predictive power of the model is tested by comparison with petrologically well-characterized natural samples of SiO₂-saturated and SiO₂-undersaturated rocks that were not used in the parameterization. In all these tests, the reformulated model performs well.     

Microstructures of melt inclusions in anatectic metasedimentary rocks

The occurrence of crystallized and glassy melt inclusions (MI) in high‐grade, partially melted metapelites and metagraywackes has opened up new possibilities to investigate anatectic processes. The present study focuses on three case studies: khondalites from the Kerala Khondalite Belt (India), the Ronda migmatites (Spain), and the Barun Gneiss (Nepal Himalaya). The results of a detailed microstructural investigation are reported, along with some new microchemical data on the bulk composition of MI. These inclusions were trapped within peritectic garnet and ilmenite during crystal growth and are therefore primary inclusions. They are generally isometric and very small in size, mostly ≤15 μm, and only rarely reaching 30 μm; they occur in clusters. In most cases inclusions are crystallized (‘nanogranites’) and contain a granitic phase assemblage with quartz, feldspar and one or two mica depending on the particular case study, commonly with accessory phases (mainly zircon, apatite, rutile). In many cases the polycrystalline aggregates that make up the nanogranites show igneous microstructures, e.g. granophyric intergrowths, micrographic quartz in K‐feldspar and cuneiform rods of quartz in plagioclase. Further evidence for the former presence of melt within the investigated inclusions consists of melt pseudomorphs, similar to those recognized at larger scale in the host migmatites. Moreover, partially crystallized inclusions are locally abundant and together with very small (≤8 μm) glassy inclusions may occur in the same clusters. Both crystallized and partially crystallized inclusions often display a diffuse nanoporosity, which may contain fluids, depending on the case study. After entrapment, inclusions underwent limited microstructural modifications, such as shape maturation, local necking down processes, and decrepitation (mainly in the Barun Gneiss), which did not influence their bulk composition. Re‐homogenized nanogranites and glassy inclusions show a leucogranitic and peraluminous composition, consistent with the results of partial melting experiments on metapelites and metagraywackes. Anatectic MI should therefore be considered as a new and important opportunity to understand the partial melting processes.     

Automicrite in a ‘nummulite bank’ from the Monte Saraceno (Southern Italy): evidence for synsedimentary cementation

Following introduction of the term ‘nummulite bank’, there has been debate regarding interpretation of these types of deposits as autochthonous (automicrite) or allochthonous (detrital micrite). These banks are made up of large foraminifera and ill‐defined fine‐grained components. The fine‐grained components consist mainly of micrites. The recognition of automicrite has deep implications for the synsedimentary cementation and stabilization of the bank. In order to distinguish between automicrite and detrital micrite, the nanomorphology, geochemistry and organic matter remains in the microfacies of a nummulite bank in the Middle Eocene of Monte Saraceno (Gargano, Southern Italy) were analysed. Optical and scanning electron microscope investigations showed that the micrites have been recrystallized to aggrading microsparite. Epifluorescence observations on selected micrite/microsparite areas with peloidal texture revealed the presence of organic matter. Scanning electron microscope analyses on epifluorescent micrites showed that the microbial peloids have smaller crystal sizes than those in organic matter‐depleted areas. The geochemical characterization of extracted organic matter, performed through the functional group analyses by Fourier transform‐infrared spectroscopy, shows strong prevalence of the aromatic fraction over the aliphatic and carboxylic ones. These characteristics of organic compounds indicate both their thermal maturation and their likely derivation from degradation of bacterial communities. The local presence of peloidal anti‐gravity textures, bright epifluorescence and organic molecules in clotted peloidal areas suggest that the metabolic activity of microbial communities could have induced precipitation of these micrites and, consequently, the syndepositional cementation of the nummulite bank. This type of cementation can rapidly stabilize sediments and promote the depositional bank geometry.     

Relationships between high‐magnitude relative sea‐level changes and filling of a coarse‐grained submarine canyon (Pleistocene,Ionian Calabria,Southern Italy)

A middle Pleistocene coarse‐grained canyon fill succession (the Serra Mulara Formation) crops out in the northern sector of the Crotone Basin, a forearc basin located on the Ionian side of the Calabrian Arc and active from the Serravallian to middle Pleistocene. This succession is an example of coarse‐grained submarine canyon fill, which consists of a north‐west to south‐east elongated body (4·25 km long and up to 1·5 km wide) laterally confined by a deep‐water clayey and silty succession and located behind the modern Neto delta (north of Crotone). The thickness of the unit reaches 178 m. The lower part of the canyon fill is dominated by gravelly to sandy density‐flow deposits containing abundant bivalve and gastropod fragments, passing upward into a succession composed of metre‐scale to decimetre‐scale density‐flow deposits forming sandstone–mudstone couplets. Sandstone deposits are mostly structureless and planar‐laminated, whereas the clayey layers record hemipelagic deposition during quieter phases. This succession is overlain by another composed of thicker structureless sandstones alternating with layers of interlaminated mudstones and sandstones, which contain leaf remnants and fresh water ostracods, and are linked directly to river floods. The canyon fill is overlain by gravelly to sandy continental deposits recording a later stage of emergence. Facies analysis, together with micropalaeontological data from the hemipelagic units, suggests that the studied canyon fill records, firstly, a progressive gravel material cut‐off during deposition due to an overall relative sea‐level rise, leading to a progressive increase in the entrapment of sediment in fluvial to shallow‐marine systems, and secondly, a generalized relative sea‐level lowering. This trend probably reflects high‐magnitude glacio‐eustatic changes combined with the regional uplift of the region, ultimately leading to emergence.