Mineralogical and geochemical features of authigenic carbonates on seepings and hydrothermal fields (By the examples of the Black Sea reefs and the mounds of the lost city field)

Two genetically different types of authigenic carbonate mounds are studied: those within an active hydrothermal field related to serpentinite protrusions in the zone of intersection of a transform fracture zone and the Mid-Atlantic Ridge, and those in an active field of methane seepings in the Dnieper canyon of the Black sea. The general geochemical conditions under which authigenic carbonate formation occurs in the two fields considered were found. They include the presence of reduced H₂S, H₂, and CH₄ gases at the absence of free oxygen; the high alkalinity of the waters participating in the carbonate formation; the similarity of the textural and structural features of authigenic aragonite, which represents the initial mineral of the carbonate matter of the mounds; the paragenesis of aragonite with sulfide minerals; and the close relation of carbonate mounds with communities of sulfate-reducing and methane-oxidizing microorganisms. A new mechanism of formation of hydrothermal authigenic carbonates is suggested; it implies their microbial sulfate reduction over the hydrogen of the fluid in the subsurface zone (biosphere) of mixing between the hydrothermal solution and the adjacent seawater.     

The 1.80–1.74-Ga gabbro–anorthosite–rapakivi Korosten Pluton in the Ukrainian Shield: a 3-D geophysical reconstruction of deep structure

The deep structure of the gabbro–anorthosite–rapakivi granite (“AMCG-type”) Korosten Pluton (KP) in the northwestern Ukrainian Shield was studied by 3-D modelling of the gravity and magnetic fields together with previous seismic data. The KP occupies an area of ca. 12,500 km² and comprises several layered gabbro-anorthositic intrusions enveloped by large volumes of rapakivi-type granitoids. Between 1.80 and 1.74 Ga, the emplacement of mafic and associated granitoid melts took place in several pulses. The 3-D geophysical reconstruction included: (a) modelling of the density distribution in the crust using the observed Bouguer anomaly field constrained by seismic data on Moho depth, and (b) modelling of the magnetic anomaly field in order to outline rock domains of various magnetisation, size and shape in the upper and lower crust. The density modelling was referred to three depth levels of 0 to 5, 5 to 18, and 18 km to Moho, respectively. The 3-D reconstruction demonstrates close links between the subsurface geology of the KP and the structure of the lower crust. The existence of a non-magnetic body with anomalously high seismic velocity and density is documented. Most plausibly, it represents a gabbroic stock (a parent magma chamber) with a vertical extent of ca. 20 km, penetrating the entire lower crust. This stock has a half-cylindrical shape and a diameter of ca. 90 km. It appears to be connected with a crust–mantle transitional lens previously discovered by EUROBRIDGE seismic profiling. The position of the stock relative to the subsurface outlines of the KP is somewhat asymmetric. This may be due to a connection between the magmatism and sets of opposite-dipping faults initially developed during late Palaeoproterozoic collisional deformation in the Sarmatian crustal segment. Continuing movements and disturbances of the upper mantle and the lower crust during post-collisional tectonic events between 1.80 and 1.74 Ga may account for the long-lived, recurrent AMCG magmatism.     

A new key pole for the East European Craton at 1452 Ma: Palaeomagnetic and geochronological constraints from mafic rocks in the Lake Ladoga region (Russian Karelia)

Palaeomagnetic and geochronological studies on mafic rocks in the Lake Ladoga region in South Russian Karelia provide a new, reliably dated Mesoproterozoic key paleopole for the East European Craton (Baltica). U–Pb dating on baddeleyite gives a crystallisation age of 1452 ± 12 Ma for one of the studied dolerite dykes. A mean palaeomagnetic pole for the Mesoproterozoic dolerite dykes, Valaam sill and Salmi basalts yields a paleopole at 15.2°N, 177.1°E, A₉₅ = 5.5°. Positive baked contact test for the dolerite dykes and positive reversal test for the Salmi basalts and for the dykes confirm the primary nature of the magnetisation. Comparison of this Baltica palaeopole with coeval paleomagnetic data for Laurentia and Siberia provides a revised palaeoposition of these cratons. The results verify that the East European Craton, Laurentia and Siberia were part of the supercontinent Columbia from the Late Palaeoproterozoic to the Middle Neoproterozoic.     

Nature of Co-bearing ferromanganese crusts of the Magellan Seamounts (Pacific Ocean): Communication 2. Ion exchange properties of ore minerals

The results of experimental studies of ion exchange properties of Co-bearing ferromanganese crusts in the Magellan Seamounts (Pacific Ocean) are discussed. Maximum reactivity in reactions with the participation of manganese minerals (Fe-vernadite, vernadite) is typical of Na⁺, K⁺, and Ca²⁺ cations, whereas minimum activity is recorded for cations Pb²⁺ and Co²⁺. The exchange complex of ore minerals in crusts is composed of Na⁺, K⁺, Ca²⁺, Mg²⁺, and Mn²⁺ cations. The exchange capacity of manganese minerals increases from the alkali metal cations to rare and heavy metal cations. Peculiarities of the affiliation of Co²⁺, Mn²⁺, and Mg²⁺ cations in manganese minerals of crusts are discussed. In manganese minerals, Co occurs as Co²⁺ and Co³⁺ cations. Metal cations in manganese minerals occur in different chemical forms: sorbed (Na⁺, K⁺, Ca²⁺, Mn²⁺, Co²⁺, Cu²⁺, Zn²⁺, Cd²⁺, and Pb²⁺); sorbed and chemically bound (Mg²⁺, Ni²⁺, Y³⁺, La³⁺, and Mo⁶⁺); and only chemically bound (Co³⁺). It is shown that the age of crust, its preservation time in the air-dry state, and type of host substrate do not affect the ion exchange indicators of manganese minerals. It has been established that alkali metal cations are characterized by completely reversible equivalent sorption, whereas heavy metal cations are sorbed by a complex mechanism: equivalent ion exchange for all metal cations; superequivalent, partly reversible sorption for Ba²⁺, Pb²⁺, Co²⁺, and Cu²⁺ cations, relative to exchange cations of manganese minerals. The obtained results refine the role of ion exchange processes during the hydrogenic formation of Co-bearing ferromanganese crusts.     

Palaeomagnetic study of Palaeoproterozoic granitoids from the Voronezh Massif, Russia

A palaeomagnetic investigation has been carried out of rocks from the eastern part of the Voronezh Massif, which constitutes, together with the Ukrainian Shield, the Sarmatian segment in the southern part of the East European Craton. The samples were collected in a quarry close to the town of Pavlovsk (50.4°N, 40.1°E), where a syenitic-granitic body intrudes Archaean units. U–Pb (zircon) dating has yielded an age of 2080  Ma for the intrusion.
  Two characteristic magnetic components, A and B, were isolated by thermal and alternating-field demagnetization. Component A was obtained from granites and quartz syenites (11 samples) and has a mean direction of D = 229°, I = 28°, and a pole position at 12°N, 172°E. This pole is close to a contemporary mean pole (9°N, 187°E) for the Ukrainian Shield, which implies that the Voronezh Massif and the Shield constituted a single entity at 2.06  Ga. These poles differ from contemporaneous poles of the Fennoscandian Shield, indicating that the relative positions of the two shields were different from their present configuration about 2100  Myr ago.
  A component B, isolated only in quartz monzonites (five samples), has a mean direction D = 144°, I = 49°, and a pole position at 4°N, 251°E, which is close to late Sveconorwegian (approximately 900  Ma) poles for Baltica. This suggests that the East European Craton was consolidated some time between 2080 and 900  Ma. Comparison with other palaeomagnetic data permit us to narrow this time span to 1770–1340  Ma.     

Adsorption of Heavy Metal Cations by Base Metal Sulfides in the Broken Spur and TAG Hydrothermal Fields,Atlantic Ocean

Data on the mineral and chemical composition of samples of sulfide deposits from the Broken Spur and TAG (Mid-Atlantic Ridge) are presented. The main minerals in the Broken Spur field are marcasite, pyrrhotite, pyrite, chalcopyrite, and sphalerite; in sample from TAG: chalcopyrite, pyrite, and marcasite. It has been established that these sulfide minerals of Fe, Cu, and Zn are natural ion exchangers and belong to the class of adsorbents. Exchange capacity of sulfide minerals in terms of heavy metal cations (Ni2+, Co2+, Cd2+, and Pb2+) is 0.022–0.32 mg-equiv/g. In the exchange reaction products, the mineral composition of sulfide deposits is retained, and new phases do not appear. It is suggested that the adsorbed heavy metal cations populate either vacant cationic or interstitial defect sites in the structures of sulfide minerals. Bond strength of the adsorbed heavy metal cations with the main structural elements of minerals is low, which is confirmed by their high extraction in an acid medium. The results of adsorption-desorption experiments indicate two forms of heavy metal cations in sulfide minerals: adsorbed (basic) and chemically bound.     

High kinetic energy density jets in the Earth’s magnetosheath: A case study

We study several high kinetic energy density jets observed during a traversal of the dayside magnetosheath by the Cluster spacecraft on March 17, 2001, at various distances from the magnetopause, generally characterised by anomalously high values of the local magnetosonic Mach number. We concentrate on two jets observed just outside the magnetopause, the first almost parallel to the GSM x axis and the second directed northward-tailward along the nominal magnetopause surface. We present evidence that none of them can be ascribed to magnetic reconnection at the magnetopause and show that the magnetopause is severely deformed by the jets, so that its local normal forms an angle of 97° with the quiet time magnetopause normal. On these grounds, we suggest that the indentation of the magnetopause is caused by an anti-sunward jet ramming into the magnetopause slightly equatorward of the northern cusp and that the northward-tailward jet is the result of its reflection at the deformed magnetopause. Finally, we briefly discuss our results by comparing them with past studies of events which in some way recall the one analysed herein.     

Authigenic carbonates in methane seeps from the Norwegian sea: Mineralogy, geochemistry, and genesis

Authigenic carbonates in the caldera of an Arctic (72°N) submarine mud volcano with active CH₄bearing fluid discharge are formed at the bottom surface during anaerobic microbial methane oxidation. The microbial community consists of specific methane-producing bacteria, which act as methanetrophic ones in conditions of excess methane, and sulfate reducers developing on hydrogen, which is an intermediate product of microbial CH₄ oxidation. Isotopically light carbon (δ¹³C_av =−28.9%0) of carbon dioxide produced during CH₄ oxidation is the main carbonate carbon source. Heavy oxygen isotope ratio (δ¹⁸O_av = 5%0) in carbonates is inherited from seawater sulfate. A rapid sulfate reduction (up to 12 mg S dm⁻³ day⁻¹) results in total exhausting of sulfate ion in the upper sediment layer (10 cm). Because of this, carbonates can only be formed in surface sediments near the water-bottom interface. Authigenic carbonates occurring within sediments occur do notin situ. Salinity, as well as CO ₃ ²⁻ /Ca and Mg/Ca ratios, correspond to the field of nonmagnesian calcium carbonate precipitation. Calcite is the dominant carbonate mineral in the methane seep caldera, where it occurs in the paragenetic association with barite. The radiocarbon age of carbonates is about 10000 yr.     

Iron and Manganese Minerals in Suspended Matter from the Barents Sea

The mineralogy of suspended matter from surface and bottom waters is studied at two sites in the Barents Sea. Along with terrigenous minerals, the suspended matter samples contain authigenic mineral phases of iron and manganese oxyhydroxides. Mn-feroxyhite, Fe-vernadite, goethite, and proto-ferrihydrite were identified in samples from surface waters, whereas birnessite and nonferruginous vernadite were registered in samples from bottom waters. The formation of suspended manganese minerals in bottom waters is explained by an additional Mn supply from underlying reduced sediments during their early diagenesis and oxygen depletion in the near-bottom nepheloid layer. Bacteria are supposed to take part in the authigenic mineral formation.     

Mineralogy of morphogenetic types of ferromanganese deposits in the world ocean

The mineralogy and structural features of the main types of ferromanganese deposits—nodules, micronodules, Co-bearing crusts, crustlike nodules, and low-temperature hydrothermal manganese crusts and ferruginous ochers—are considered. The correlation between their mineral composition and structure is shown. The proposed classification of mineral types is based on characteristic assemblages of Fe and Mn minerals.