Study of two alteration systems as natural analogues for radionuclide release and migration

U-deposit hosted in hydrothermally altered tuffs in Mexico, together with weathering profiles from Cameroon were studied as natural analogues of radionuclide release and migration. Using petrological and spectroscopic methods (infrared and electron paramagnetic resonance), we have distinguished successive secondary mineral parageneses and the behaviour of radionuclides.

In the U-deposit, the mineral parageneses show that uranium migration is mainly controlled by the redox potential and silica activity of the altering solutions. The high silica content of the solutions is caused by the intense alteration of volcanic rocks. Two types of secondary clay mineral parageneses are evidenced: a kaolinization, intense where uranium is accumulated in the welded tuffs, and a smectitization mainly developed in the underlying weakly welded tuffs.

Several types of kaolinite have been defined according to their genesis (fillings in fissures and feldspar pseudomorphs), their location relative to a breccia pipe where uranium has accumulated (core and rim of the pipe; surrounding rhyolitic tuffs), and particle morphology, structural order and substitutional Fecontent. It is shown that the variations of the concentration of paramagnetic defect centres, always more than ten times as important than those measured in weathering kaolinites, are only correlated to the location of the kaolinites. The highest values correspond to the breccia pipe kaolinites, e.g. kaolinites located in the uranium accumulation zones. Moreover, one or two main defects centres are detected depending on the intimate association of kaolinites with uranium-bearing minerals. Besides, in weathering kaolinites from U-depleted laterites, defect centre concentrations are correlated to the total Fe203 content in bulk samples. This means that the defect centre acts as a memory of the travel of uranium when this element was sorbed onto iron gels in the first stage of weathering.

It is concluded that paramagnetic defect centres in kaolinites might allow an efficient fingerprint of successive irradiations in the natural analogues under study and could be an useful tool to control radionuclides migration through kaolinite-containing clayey materials such as those used for waste repository.

A better understanding of radiation efficiency as well as accurate dose-ratekaolinite-containing clayey materials such as those used for waste reposit estimation are needed for a quantitative tracing of the migration ofA better understanding of radiation efficiency as well as accurate dose-ratekaolin radionuclide elements. With this aim, a simulation has been undertaken withestimation are needed for a quantitative tracing of the migration of various radiations sources. We have determined for each irradiation the parameters of the paramagnetic centres created in order to understand the way they are forming. The knowledge of the parameters governing the formation and the stability of the radiation centres in kaolinites allow to use this mineral as a natural dosimeter.     

Al-O--Al paramagnetic defects in kaolinite

Trapped holes located on Al-O-Al bonds in kaolinite were studied by electron paramagnetic resonance spectroscopy (EPR) at 9.3 and 35 GHz applied to well-crystallized, X-ray irradiated and oriented samples. The Q-band EPR spectrum is characterized by three clearly separated groups of 11 quasi-equidistant superhyperfine lines centered at g_xx=2.040±0.0005, g_yy=2.020±0.0005 and g_zz=2.002±0.001. In each of these groups, the 11 superhyperfine lines exhibit intensities according to the ratios 12345654321. An angular dependence of the Q-band EPR spectrum with respect to the magnetic field is demonstrated by measurements on oriented films of kaolinite. An appropriate numerical treatment of the EPR spectra is described, which allowed extraction of the SuperHyperfine Structures (SHFS). X-and Q-band spectra have also been simulated. It is concluded from these experiments that only one type of center is present. This center, labelled the B-center in the literature, is very probably a hole trapped on oxygen (O^- center) atoms coupled to two octahedral aluminium.     

Fractured space: a geographical reflection on the digital divide

What does it mean to reflect upon space in connection to telecommunications? If we start with a conception of urban space as being fully integrated, including on an equal footing both information and communication technologies (ICT) and mobility techniques, as well as the founding notion of copresence that we find at the heart of all urban organization, we might then be able to examine the notion of the ‘digital divide’ in a new light. This clearly experimental approach is conducted by a research group called ‘Urbatic’, which is composed of geographers who, for the last three years, have been conducting theoretical research whose objective is to take into account two fields of social science: the theory of urbanity and the theory of telecommunication. Surveys conducted in this perspective focus on the analysis of the choices people make between the different means they can use to cope with distances (copresence, mobility and telecommunication) with a view to constructing their own space. The analysis of these choices leads us to propose a new theorized interpretation of the ‘digital divide’.     

Interannual variability of deep convection in the Northwestern Mediterranean simulated with a coupled AORCM

A hindcast experiment of the Mediterranean present-day climate is performed using a fully-coupled Atmosphere–Ocean Regional Climate Model (AORCM) for the Mediterranean basin. The new model, called LMDz-NEMO-Med, is composed of LMDz4-regional as atmospheric component and of NEMOMED8 as oceanic component. This AORCM equilibrates freely, without any flux adjustment, neither in fresh water nor in heat. At its atmospheric lateral boundary conditions, it is driven by ERA-40 data from 1958 to 2001, after a spin-up of 40 years in coupled configuration. The model performance is assessed and compared with available observational datasets. The model skill in reproducing mean state and inter-annual variability of main atmospheric and oceanic surface fields is in line with that of state-of-the-art AORCMs. Considering the ocean behaviour, the inter-annual variations of the basin-scale heat content are in very good agreement with the observations. The model results concerning salt content could not be adequately validated. High inter-annual variability of deep convection in the Gulf of Lion is simulated, with 53 % of convective winters, representative of the present climate state. The role of different factors influencing the deep convection and its inter-annual variability is examined, including dynamic and hydrostatic ocean preconditioning and atmospheric surface forcing. A conceptual framework is outlined and validated in linking the occurrence of deep convection to the efficiency of the integrated surface buoyancy fluxes along the winter season to mix the initially stratified averaged water column down to the convective threshold depth. This simple framework (based only on 2 independent variables) is able to explain 60 % (resp. 69 %) of inter-annual variability of the deep water formation rate (resp. maximum mixed layer depth) for the West Mediterranean Deep Water (WMDW) formation process.     

Tracing of dissolved organic matter from the Sepetiba Bay (Brazil) by PARAFAC analysis of total luminescence matrices

Fluorescent excitation-emission matrices (FEEM) of the fluorescent dissolved organic matter (FDOM) are widely used for DOM characterization and tracing. In this work, a set of FEEM from sampling campaigns in the Sepetiba Bay (Brazil) was decomposed into independent components using the parallel factor analysis (PARAFAC) algorithm. Four independent components were extracted describing the total fluorescence of the FDOM. The well described peaks A, C, M, B and T were found, and a new peak, A', linked to the C peak, was detected. Relative contribution of each of four components to the total fluorescence confirms that the coastal water has DOM of terrestrial origin, except for the 275Ex/400-500Em range (nm), which primarily occurs in marine waters.