Responsible Geographies: Co-oreating Knowledge in Aotearoa

We examine in this paper the potential for (reforming the relations of social scientific research in Aotearoa. Drawing upon our experience of undertaking historical geographical research with and for Ngati-Toa Rangatira, we argue for the need to develop responsible geographies in Aotearoa. We suggest that the metaphors of ‘crossing borders’ and ‘building structures’ might offer one route into the development of such a responsible geography.     

Apparent oxygen isotope equilibrium during progressive foliation development and porphyroblast growth in metapelites: implications for stable isotope and conventional thermometry

The assumption of oxygen isotope and major element equilibrium during prograde metamorphism was tested using staurolite‐grade pelitic schists that have undergone sequential porphyroblast growth and multiple episodes of recrystallization of matrix minerals and foliation development. Textural relationships are used to infer a metamorphic history that involves garnet growth followed by staurolite growth, with each porphyroblast growth event followed by at least one period of recrystallization of matrix minerals. Conventional geothermobarometry using Qtz–Grt–Pl–Ms–Bt ± St equilibria yields peak P–T conditions of c. 625 °C at 9–11 kbar, consistent with KMnFMASH petrogenetic grid predictions for stability of the assemblage Grt + St + Bt. Qtz–Grt oxygen isotope fractionations yield apparent temperatures of c. 590 °C and Qtz–St fractionations yield an apparent temperature of c. 595 °C. Diffusional modelling indicates that quartz isotopic compositions were reset by c. 30 °C via retrograde isotopic diffusional exchange with micas. The isotopic temperatures appear to be in excellent agreement with one another, and suggest oxygen isotope equilibrium was attained between garnet and staurolite at c. 625 °C. However, the agreement of Qtz–Grt and Qtz–Str isotopic temperatures is not consistent with petrographic observations (garnet grew before staurolite) and petrogenetic grid constraints that predict that garnet grows over a temperature interval of c. 525–550 °C. Given that: (i) oxygen diffusion rates in staurolite and garnet are slow enough to render an individual porphyroblast effectively closed to exchange after it forms; and (ii) matrix minerals are able to exchange isotopes via recrystallization during each period of deformation; garnet and staurolite could not have simultaneously achieved oxygen isotope equilibrium with each other or with minerals in the recrystallized matrix. Thus, the Qtz–Grt fractionations, which yield apparent temperatures that are in apparent agreement with peak metamorphic temperature and apparent temperatures for Qtz–St fractionations, cannot be fractionations resulting from equilibrium isotopic exchange. Instead, they are apparent fractionations between porphyroblasts formed at different temperature and times in the prograde P–T–D path, and quartz that recrystallized and exchanged with micas and plagioclase during several phases of deformation.     

SEISMIC INVERSION BY A RMS BORN APPROXIMATION IN THE SPACE-TIME DOMAIN1

A new approximate method to calculate the space-time acoustic wave motion generated by an impulsive point source in a horizontally layered configuration is presented. The configuration consists of a stack of fluid layers between two acoustic half-spaces where the source and the receiver are located in the upper half-space. A distorted-wave Born approximation is introduced; the important feature of the method is the assumption of a background medium with vertical varying root-mean-square acoustic wave speed. A closed-form expression for the scattered field in space and time as a function of the contrast parameters is deduced. The result agrees closely with rigorously calculated synthetic seismograms. In the inverse scheme the wave speed and mass density can be reconstructed within a single trace. Results of the inversion scheme applied to synthetic data are shown.     

Modeling shoreline sand waves on the coasts of Namibia and Angola

The southwestern (SW) coast of Africa (Namibia and Angola) features long sandy beaches and a wave climate dominated by energetic swells from the Southsouthwest (SSW), therefore approaching the coast with a very high obliquity. Satellite images reveal that along that coast there are many shoreline sand waves with wavelengths ranging from 2 to 8 km. A more detailed study, including a Fourier analysis of the shoreline position, yields the wavelengths (among this range) with the highest spectral density concentration. Also, it becomes apparent that at least some of the sand waves are dynamically active rather than being controlled by the geological setting. A morphodynamic model is used to test the hypothesis that these sand waves could emerge as free morphodynamic instabilities of the coastline due to the obliquity in wave incidence. It is found that the period of the incident water waves, T_p, is crucial to establish the tendency to stability or instability, instability increasing for decreasing period, whilst there is some discrepancy in the observed periods. Model results for T_p = 7–8 s clearly show the tendency for the coast to develop free sand waves at about 4 km wavelength within a few years, which migrate to the north at rates of 0.2–0.6 km yr^?1. For larger T_p or steeper profiles, the coast is stable but sand waves originated by other mechanisms can propagate downdrift with little decay.     

DIFFRACTION BY A WEDGE IN AN ACOUSTIC CONSTANT DENSITY MEDIUM1

A new method is presented for solving the 2D problem of diffraction of a plane wave by a wedge of arbitrary angle in a purely acoustic, constant-density medium with different constant compressional wave speeds inside and outside the wedge. The diffraction problem is formulated as integral equations, and a wavenumber–frequency representation of the scattered field is obtained. With the aid of the Cagniard–de Hoop method, exact analytical expressions in the space–time domain are obtained for the different wave constituents, i.e. geometric optical scattered waves and edge diffracted waves including head waves. These expressions can be computed to any degree of accuracy within reasonable computation times on a computer, and the semi-analytical method of solution presented thus constitutes a means of constructing reference solutions for wedge configurations. Such highly accurate reference solutions are of importance for verification of results that include diffraction phenomena modelled by general numerical approximate methods, e.g. finite differences, finite elements and spectral methods. Examples of such applications of the method of solution are given.     

Ponga, Glass and Concrete

In accepting that Aotearoa is no-longer a rural nation there are exciting possibilities for the study of urban socio-cultural geography - the effects of urbanisation on the lives ofNewZealanders. Contemporary social geographical theories have combined with postmodernism, poststructuralism, postcolonialism and feminism toproducea ‘new cultural geography’. We argue that this new cultural geography couldprovide important theoretical avenues for the development of an ‘indigenous’ New Zealand urban socio-cultural geography.     

Structural clues to the origin of refractory metal alloys as condensates of the solar nebula

Abstract– Alloys of the refractory metals Re, Os, W, Ir, Ru, Mo, Pt, and Rh with small amounts of Fe and Ni are predicted to be one of the very first high‐temperature condensates in a cooling gas of solar composition. Recently, such alloy grains were found in acid‐resistant residues of the Murchison CM2 chondrite. We used focused ion beam (FIB) preparation to obtain electron‐transparent sections of 15 submicrometer‐sized refractory metal nuggets (RMNs) from the original Murchison residue. We studied their crystallography, microstructures, and internal compositional variations using transmission electron microscopy (TEM). Our results show that all RMNs studied have hexagonal close‐packed (hcp) crystal structures despite considerable variations of their bulk compositions. Crystallographic superstructures or signs of spinodal decomposition are absent and defect microstructures are scarce. Internally, RMNs are compositionally homogeneous, with no evidence for zoning patterns or heterogeneities due to exsolution. Many RMNs show well‐defined euhedral crystal shapes and all are nearly perfect single crystal. Our findings are consistent with a direct (near‐) equilibrium condensation of refractory metals into a single alloy at high temperature in the solar nebula as predicted by current condensation models. We suggest that this alloy is generally hcp structured due to an extended ε‐phase field in the relevant multicomponent alloy system. The high degree of structural perfection and compositional homogeneity is attributed to high defect energies, high formation temperatures, slow cooling rates, small grain sizes, and rapid internal diffusion.     

Geothermometry in the Kiglapait Aureole: Part II. Evaluation of Exchange Thermometry in a Well-Constrained Thermal Setting

Previous determination of a well-constrained thermal profilerepresenting peak conditions of metamorphism for the contactaureole of the Kiglapait Intrusion, Labrador, provides the basisfor critical comparative geothermometry of cation exchange thermometersapplied to mafic and ultramafic granulites. Knowledge of theshape of the profile and constraints on the temperature of theintruding magma allow calculation of cooling rates which rangefrom 150?C/m.y. at the contact to 30?C/m.y. at 2500 m from thecontact. Substitution of these rates in diffusion equationspermits discrimination between geothermometers which are eitheradequately or poorly calibrated, as well as thermometers whichare probably inappropriate for use in metamorphic terranes.Our results suggest that the two-pyroxene thermometer (Lindsley& Andersen, 1983) is accurate from 950 to 750?C. Below 750?C,both limbs of the miscibility gap require at least minor recalibration,or the projection scheme of Lindsley & Andersen (1983) requiresadjustment. Results from the cpx-ilm thermometer are erraticand imply that the solution models for pyroxene and ilmenite,as presently formulated in this thermometer, are inadequate.Results from the opx-ilm, ol-ilm, and opx-ol thermometers areinconsistent. Theoretical calculations at both high and lowtemperatures show that these three thermometers cannot giveinternally consistent results. Results from Fe-Ti oxide thermometrysuggest that these minerals are easily re-equilibrated due tocation interdiffusion between grains. However some grain pairsappear to retain compositions appropriate to peak thermal conditions.