U-Pb Zircon Calendar for Namaquan (Grenville) Crustal Events in the Granulite-facies Terrane of the O'okiep Copper District of South Africa

The O'okiep Copper District is underlain by voluminous 1035–1210Ma granite gneiss and granite with remnants of metamorphosedsupracrustal rocks. This assemblage was intruded by the 1030Ma copper-bearing Koperberg Suite that includes jotunite, anorthosite,biotite diorite and hypersthene-bearing rocks ranging from leuconoriteto hypersthenite. New sensitive high-resolution ion microprobeage data demonstrate the presence of 1700–2000 Ma zirconas xenocrysts in all of the intrusive rocks, and as detritalzircon in the metasediments of the Khurisberg Subgroup. Thesedata are consistent with published Sm–Nd model ages ofc. 1700 Ma (T_CHUR) and c. 2000 Ma (T_DM) of many of the intrusivesthat support a major crust-forming event in Eburnian (Hudsonian)times. In addition, U–Th–Pb analyses of zirconsfrom all major rock units define two tectono-magmatic episodesof the Namaquan Orogeny: (1) the O'okiepian Episode (1180–1210Ma), represented by regional granite plutonism, notably theNababeep and Modderfontein Granite Gneisses and the Concordiaand Kweekfontein Granites that accompanied and outlasted (e.g.Kweekfontein Granite) regional tectonism [F₂(D₂)] and granulite-faciesmetamorphism (M₂); (2) the Klondikean Episode (1020–1040Ma), which includes the intrusion of the porphyritic RietbergGranite and of the Koperberg Suite that are devoid of regionalplanar or linear fabrics. Klondikean tectonism (D₃) is reflectedby major east–west-trending open folds [F₃(D_3a)], andby localized east–west-trending near-vertical ductilefolds [‘steep structures’; F₄(D_3b)] whose formationwas broadly coeval with the intrusion of the Koperberg Suite.A regional, largely thermal, amphibolite- to granulite-faciesmetamorphism (M₃) accompanied D₃. This study demonstrates, interalia, that the complete spectrum of rock-types of the KoperbergSuite, together with the Rietberg Granite, was intruded in ashort time-interval (<10 Myr) at c. 1030 Ma, and that therewere lengthy periods of about 150 Myr of tectonic quiescencewithin the Namaquan Orogeny: (1) between the O'okiepian andKlondikean Episodes; (2) from the end of the latter to the formalend of Namaquan Orogenesis 800–850 Ma ago. KEY WORDS: U–Pb, zircon; O'okiep, Namaqualand; granite plutonism; granulite facies; Koperberg Suite; Namaquan (Grenville) Orogeny     

Biomineralization of Uranium: A Simulated Experiment and Its Significance

A simulated experimental reduction of U^v1 and the synthesis of uraninite by a sulfate-reducing bacteria,Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were:35℃, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week‘s incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments,might have participated in the biomineralization of this uranium deposit. There is an important difference in the orderdisorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.     

铀的微生物Desulfovibrio desulfuricans DSM 642成矿作用:模拟实验及其意义

在我国首次报道用硫酸盐还原菌 Desulf ovibriodesulfuricans DSM 6 4 2 ,模拟我国层间氧化带砂岩型铀矿形成的主要物理化学条件 (35℃ ,p H=7.0～ 7.4 ) ,实验还原U( )和合成沥青铀矿。结果表明 ,实验经一周后 ,微生物成因沥青铀矿即生成于该菌胞表面。由此推断 ,在侏罗系砂岩中广泛繁衍的这种硫酸盐还原菌 ,可能参与了该类铀矿床的成矿作用。同时发现 ,由该实验菌实验还原生成的沥青铀矿 ,与在天然地质条件下生成的该铀矿物 ,其晶体结构的有序—无序性质存在重大差异 :在天然条件下藉长期和缓慢地沉淀、生长形成的沥青铀矿 ,其中纳米级…     

Polybaric Evolution of Calc-alkaline Magmas from Nisyros, Southeastern Hellenic Arc, Greece

The lavas of Nisyros were erupted between about 0?2 m.y B.P.and 1422 A.D., and range in composition from basaltic andesiteto rhyodacite. Most were erupted prior to caldera collapse (exactdate unknown), and the post-caldera lavas are petrographically(presence of strongly resorbed phenocrysts) and chemically (lowerTiO₂ K₂O, P₂O₅, and LIL elements) distinct from the pre-calderalavas. The pre-caldera lavas do not form a continuous seriessince lavas with SiO₂ contents between 60 and 66 wt.% are absent.Nevertheless, major element variations demonstrate that fractionalcrystalliz ation (involving removal of olivine, dinopyroxene,plagioclase, and Fe-Ti oxide from the basaltic andesites andandesites and plagioclase, clinopyroxene, hypersthene, Ti-magnetite,ilmenite, apatite, and zircon from the dacites and rhyodacites)played a major role in the evolution of the pre-caldera lavas.Several lines of evidence indicate that other processes werealso important in magma evolution: (1) Quantitative modelingof major element data shows that phenocryst phases of unlikelycomposi tion or unrealistic assemblages of phenocryst phasesare required to relate the dacites and rhyodacites to the basalticandesites and andesites; (2) The proportions of olivine andclinopyroxene required in quantitative models for the initialstages of evolution differ from those observed petrographicallyand this is not likely to reflect either differential ratesof crystal settling or the curvature of cotectics along whichliquids of basaltic andesite to andesite composition lie; (3)The concentrations of Rb, Cs, Ba, La, Sm, Eu, and Th in therhyod.acites are too high for these lavas to be related to thedacites by fractional crystallization alone; and (4) ⁸⁷Sr/⁸⁶Srratios for the andesites and rhyodacites are higher than thosefor the basaltic andesites and dacites, respectively. It isshown that fractional crystallization was accompanied by assimilation,and that magma mixing played a minor role (if any) in the evolutionof the pre-caldera lavas. Trace element and isotopic data indicatethat the andesites evolved from the basaltic andesites by AFCinvolving average crust or upper crust, whereas the rhyodacitesevolved from the dacites by AFC involving lower crust. Additionalevidence for polybaric evolution is provided by the occurrenceof distinct Ab-rich cores of plagioclase phenocrysts in thedacites and rhyodacites, which record a period of high pressurecrystallization, and by the occurrence of both normal and reverse-zonedphenocrysts in the basaltic andesites and andesites. Furthermore,calculated pressures of crystallization are {small tilde}8 kbfor the dacites and rhyodacites and 3?5–4 kb for the basalticandesites and andesites. It is concluded that the dacites andrhyodacites evolved via AFC from basaltic andesites and andesiteslargely in chambers sited near the base of the crust whereasthe basaltic andesites and andesites mostly evolved in chamberssited at mid-crustal levels. Eruption from different chambersexplains the compositional gap in the chemistry of the pre-calderalavas since eruptive products represent a more or less randomsampling of residual liquids which separate (via filter pressing)from bodies of crystallizing magma at various depths. Magmamixing was important in the evolution of the post-caldera lavas,but geochemical data require that these magmas evolved fromparental magmas which were derived from a more refractory sourcethan the parental magmas to the pre-caldera lavas. ^*Present address: Netherlands Energy Research Foundation (ECN), P.O. Box 1, 1755 ZG Petten, The Netherlands     

Long-Term Evolution of Fluid-Rock Interactions in Magmatic Arcs: Evidence from the Ritter Range Pendant, Sierra Nevada, California, and Numerical Modeling

A record of > 100 million years of fluid flow, alteration,and metamorphism in the evolving Sierra Nevada magmatic areis preserved in metavolcanic rocks of the Ritter Range pendantand surrounding granitoids. The metavolcanic rocks consist of:(1) a lower section of mostly marine volcaniclastic rocks, lavas,and intercalated carbonate rocks that is Triassic to Jurassicin age, and (2) an upper section comprising a subaerial caldera-fillcomplex of mid-Cretaceous age. Late Cretaceous high-temperaturecontact metamorphism (2 kbar, >450–500C) occurredafter renewed normal faulting along the caldera-bounding faultsystem juxtaposed the two sections. The style and degree of alteration and ¹⁸O values differ amongthe rocks of the upper and lower sections and the granitoids.Rocks of the lower section show pervasive lithologically controlledalkali alteration, local Mn and Mg enrichment, and oxidation.Some ash flow tuffs now contain up to 10% K²O by weight. Therocks of the upper section show lesser extents of alkali alteration.Granitoids that cut both sections are generally unaltered. Mostmetavolcanic rocks of the lower section have high ¹⁸O values(+ 11 to + 16%; whole rock and quartz phenocrysts); however,lower-section rocks within the caldera-bounding fault systemhave low ¹⁸O values of + 4 to +7. The metavolcanic rocks ofthe upper section also have low ¹⁸O values of + 2 to + 7. Granitoidshave ¹⁸O values of + 7 to + 10, typical of unaltered Sierrangranitoids. The lower section contains discontinuous veins ofhigh-temperature (450–500C) calc-silicate minerals. Theseveins are typically <5 m long, do not cross intrusive contacts,and postdate the pervasive alkali alteration. Late veins aretypically > 10 m long, formed at temperatures of less than450–500C, and cross intrusive contacts. Veins have similar¹⁸O values to those of the local host rocks. The nature of the alteration and the high oxygen isotopic valuesof the rocks of the lower section indicate that these rocksinteracted extensively with seawater at temperatures <300C,probably in superposed marine hydrothermal systems associatedwith coeval volcanic centers. Metavolcanic rocks of the uppersection evidently interacted with meteorie waters, probablyin a hydrothermal system associated with the Cretaceous caldera;rocks of the lower section that were adjacent to the calderawere also affected by this alteration. The preservation of thesignatures of these earlier events, the nature of the earlyveins, and results from numerical models of hydrothermal flowthat include fluid production indicate that during progradecontact metamorphism, the rocks of the pendant primarily interactedwith locally derived fluids. Fluid flow was predominantly upwardand away from intrusive contacts and down-temperature. Permeabilitiesare estimated to have been between 0•1 and 1µD, whichis that necessary for maintenance of lithostatic fluid pressures.In hydrothermal models with such permeabilities, large-scalecirculation of meteoric fluids develops after prograde metamorphismceases. The nature of the late veins in the Ritter Range pendantsuggests that such a flow pattern evolved only after the pendantand granitoids had cooled below 450–500C. The long-termhistory of alteration documented in the Ritter Range pendantis probably typical of wall rocks in most batholiths *Present address: Department of Geosciences, University of Arizona, Tucson, Arizona 85721     

Equatorial Wave Expansion of Instantaneous Flows for Diagnosis of Equatorial Waves from Data: Formulation and Illustration

This paper presents a method for expanding horizontal flow variables in data using the free solutions to the shallow-water system as a basis set. This method for equatorial wave expansion of instantaneous flows(EWEIF) uses dynamic constraints in conjunction with projections of data onto parabolic cylinder functions to determine the amplitude of all equatorial waves.EWEIF allows us to decompose an instantaneous wave flow into individual equatorial waves with a presumed equivalent depth without using temporal or spatial filtering a priori.Three sets of EWEIF analyses are presented. The first set is to confirm that EWEIF is capable of recovering the individual waves constructed from theoretical equatorial wave solutions under various scenarios. The other two sets demonstrate the ability of the EWEIF method to derive time series of individual equatorial waves from instantaneous wave fields without knowing a priori exactly which waves exist in the data as well as their spatial and temporal scales using outputs of an equatorial β-channel shallow-water model and ERA-Interim data. The third set of demonstrations shows, for the first time, the continuous evolutions of individual equatorial waves in the stratosphere whose amplitude is synchronized with the background zonal wind as predicted by quasi-biennial oscillation theory.     

A Crustal Progenitor for the Intrusive Anorthosite--Charnockite Kindred of the Cupriferous Koperberg Suite, O'okiep District, Namaqualand, South Africa; New Isotope Data for the Country Rocks and the Intrusives

The Koperberg Suite comprises some 1700 small bodies of intrusiverocks largely composed of andesine anorthosite, biotite diorite,and leuconorite, norite and melanorite-hypersthenite; 30 mineshave been established in the O'okiep District in the cupriferousrocks of this anorthosite-charnockite kindred. The suite isintrusive into a sequence of granite gneiss and metavolcanicand metasedimentary rocks, and intrusive granite, that wereelevated to the granulite fades of regional metamorphism.TheSm-Nd model ages for the country rocks and the Koperberg Suiteare all 1700 Ma (T_CHUR) and 2000 Ma (T_DM) supporting a majorcrustforming event in this portion of Namaqualand at the endof Lower Proterozoic times. The granulite fades metamorphismin the O'okiep District is recorded by a Rb-Sr isochron ageof 1223 48 Ma on the Nababeep Granite Gneiss, and by (1197 15)-Ma-old inherited cores of zircons in the Koperberg Suite.The time of intrusion of the Concordia and Rietberg Granitesis believed to be reflected by their Rb-Sr whole-rock age of1105 24 Ma. The mean U-Pb age of 1029 10 Ma on individualzircon grains and zircon rims from the Koperberg Suite recordsthe time of its intrusion, and this is supported by the Sm-Ndwhole-rock age of 1022 42 Ma for the suite. Subsequent coolingand reheating events are recorded by the Ar-Ar ages of 800–850Ma for the Koperberg Suite, and of 500–550 Ma for thesuite and certain country rocks, respectively.An Nd value of-7,and its volume and composition, suggest a crustal-melt sourcefor the intrusive Concordia Granite. Moreover, the age-correctedhigh l_Sr (07061-07272) and low Nd (-9), and the high µ₂(101), that characterize the Koperberg Suite also imply a crustalsource, and a model is presented for the generation of the majorpart of the suite by partial melting of granulites of overallintermediate (diorite) composition in the lower crust. Corresponding author     

Petrological and Geochemical Evidence for Granitoid Formation: The Waldoboro Pluton Complex, Maine

The Acadian-age Waldoboro Pluton Complex (WPC), mid-coastalMaine, consists of seven granitoid units surrounded by migmatitic,peraluminous gneisses and schists (predominantly Bucksport orSebascodegan Formation). The complex (area >340 km²) cross-cutsthe westward-vergent St. George thrust fault, which may markthe boundary between the Avalon and Gander composite terranes.Field and petrologic data indicate in situ formation of theperaluminous, syntectonic granitoids: contacts with Bucksportparagneisses are transitional and concordant; abundant country-rockenclaves show evidence for melting; restitic garnet, biotite,and plagioclase in the granitoids are identical in compositionto garnet, biotite, and plagioclase in the country rock. Chemicalvariations among the main granitoid phases (gneissic granite,granite, and leucogranite) reflect varying degrees of melt-restiteunmixing. Major and trace elements define mixing trends betweenrefractory Bucksport lithologies and leucogranites which approximatemelt compositions. Petrographic and whole-rock chemical dataare consistent with restitic plagioclase, garnet, biotite, tourmaline,zircon, apatite, sphene, and an accessory phase such as monazite.Quantitative major-oxide mass-balance models indicate that gneissicgranite represents a mixture of 55% melt–45% restite whereasgranite represents a mixture of 76% melt–24% restite.Melt-restite proportions calculated from trace element dataagree with those calculated from major oxide data for the gneissicgranite, but are different (85% melt–15% restite) fromthose calculated from major oxide data for the granite. Thisis attributed to inhomogeneous distribution of minor phasesand the effects of metasomatism. High K₂O, Rb, Ba, Cs, Li, B,K/Rb, K/Ba, Rb/Sr, and Th/U along the eastern mylonitic marginand elsewhere within the WPC reflect post-solidification metasomaticprocesses. Intrusion of mafic magmas during uplift after crustal thickeningappears to have caused high-temperature metamorphism and anatexisof Bucksport country rocks at relatively low pressure (0.4 GPa).Dehydration melting of muscovite to produce magmas saturatedor nearly saturated with H₂O explains the formation of migmatitesin the vicinity of the WPC. Formation of granites by 50–60%fluid-absent melting of Bucksport source rocks containing 20%biotite requires that fusion occurred at T860C and consumedall of the biotite in the source rock. Phase equilibrium dataand estimated temperatures of formation provide evidence thatthe granitoids formed at T<860C, whereas petrographic dataindicate that not all biotite in the source rock was consumedduring anatexis. Therefore, the WPC granitoids could have formedby fluid-absent melting if the source rocks contained >20%biotite (the maximum amount observed). However, it is also possiblethat influx of aqueous fluid before or during anatexis allowedproduction of relatively large volumes of melt at T<860C.Available data do not allow these possibilities to be rigorouslytested. The WPC granitoids have many characteristics of S-type granitesand preserve a chemical and mineralogical record of their sourcerocks, indicating that granites can image their sources evenin tectonically complex regions.     

Metamorphism, geochemistry and origin of magnesian volcanic rocks, Klamath Mountains, California

Metabasaltic rocks in the Klamath Mountains of California with ‘komatiitic’ major element concentrations were investigated in order to elucidate the origin of the magnesian signature. Trace-element concentrations preserve relict igneous trends and suggest that the rocks are not komatitic basalts, but immature arc rocks and within-plate alkalic lavas. Correlation of ‘excess’ MgO with the volume per cent hornblende (±clinopyroxene) suggests that the presence of cumulus phases contributes to the MgO-rich compositions. Early submarine alteration produced regional δ¹⁸O values of +10±1.5%_° and shifts in Al₂O₃, Na₂O, and K₂O concentrations. Regional metamorphic grade in the study area varies from biotite-zone greenschist facies (350–550°C, c. 3 kbar) southward to prehnite–actinolite facies (200–400°C, ≤3 kbar), but little isotopic or elemental change occurred during the regional recrystallization. The greenschist facies assemblage is actinolitic hornblende + phengite + epidote + sodic plagioclase + microcline + chlorite + titanite + hematite + quartz in Ti-poor metabasaltic rocks; in addition to these phases biotite is present in Ti-rich analogues. Lower grade greenstones contain prehnite and more nearly stoichiometric actinolite. The moderate to low pressures of regional metamorphism are compatible with P–T conditions in a magmatic arc. Later contact metamorphism at 2–2.9±0.5 kbar and at peak temperatures approaching 600° C around the English Peak and Russian Peak granodiorites produced 3–4–km-wide aureoles typified by gradual, systematic increases in the pargasite content of amphibole, muscovite content of potassic white mica, and anorthite content of plagioclase compositions. Metasomatism during contact metamorphism produced further increases in bulk-rock δ¹⁸O_SMOW of as much as +6%_°. Thus, the unusually MgO-rich nature of the Sawyers Bar rocks may be attributed at least partly to metasomatism and the presence of magnesian cumulus phases.     

Competition and co-operation in the semi-periphery: closer economic partnership and sectoral transformations in Chile and New Zealand

The signing of a strategic economic partnership (the Trans-Pacific SEP or P4) between Chile, New Zealand, Singapore and Brunei Darussalam in 2005 reveals the emergence of a new generation of trade agreements that seek to promote longer-term synergies and cooperation. This is in marked contrast with a purely competitive, market-based model of agreements whereby economies are opened up to oligopsonistic capital. The orientation is clearly more neostructural and strategic in construction, emphasizing the opportunities within the global economy of improved relations with similarly positioned economies within the semi-periphery. This article analyses both the basis for and implications of the P4 for Chile and New Zealand by looking at three sectors in which both countries are competitive in export markets: dairy, wine and fisheries. By assessing similarities and differences, and the ways in which competition or co-operation might be established, the potential impacts of the agreement can be posited. Within a global context of bilateral and multilateral commercial agreements, it is this type of agreement that perhaps best fits the needs of smaller economies in the periphery that seek to establish greater competitive space for their exports in core economies without engaging in a mutually destructive war of competition in similar sectors and products.