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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff
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We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
在早期的文章中,基于耀变体(Blazar)的知识,我们预言了在射电噪活动星系核(AGN)中心10
kpc范围内X射线喷流的存在.钱得拉(Chandra)卫星最近对低功率射电星系的X射线观测与我们的预言相一致.在本文中我们研究了kpc尺度喷流中的电子加速,并建议通过对强的FR
Ⅱ射电星系中所预言的X射线喷流的钱得拉卫星的X射线的观测,来研究红的耀变体中的康普顿冷却以及在内部致密喷流和大尺度延伸喷流间环境的不同.以上的研究可以进一步检验我们的关于射电噪活动星系核中kpc尺度X射线喷流的模型. 相似文献
3.
采用PCR技术对2种亚洲龙鱼的mtDNAD_Loop全序列进行扩增和测序,序列结构分析和序列同源性比对结果表明,2种亚洲龙鱼的mtDNAD_Loop在靠近5’端有3个终止相关序列TAS(Ⅰ、Ⅱ、Ⅲ),靠近D_Loop的3’端有4个保守区域CSB1、CSB2、CSB3、CSB-D。在终止相关序列和保守区域之间是连续重复区域。经DNASP4.0软件分析,全序列中检测出多态位点数(S)为26,其中有17个转换,核苷酸多样性(Pi)为0.013,平均核苷酸差异数(K)为17.333。 相似文献
4.
5个新发现的X选BL Lac天体 总被引:1,自引:0,他引:1
利用ROSATVLA方法筛选,从ROSATX射线源中选出了一批新的BLLac天体和类星体的候选体.1996年12月8日至17日,利用北京天文台2.16m望远镜和新从美国引进的OMR摄谱仪,对这批新候选体进行了光谱认证.经SUN工作站处理,又发现了5个新的X选BLLac天体.此外,还对去年作者在OMR引进之前发现的BLLac天体进行了检验,结果发现,去年发现的7个BLLac天体中,2322+343的CaIIH&K“Breakstrength”为26.9%,稍大于判据25%,因此,2322+343到底是BLLac天体还是射电星系还有待于进一步测光及偏振观测的验证. 相似文献
5.
Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro. 相似文献
6.
本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实 相似文献
7.
鱼卡煤田大煤沟组高分辨率层序地层特征及聚煤规律 总被引:1,自引:0,他引:1
利用高分辨率层序地层学理论和技术方法,综合地震、测井、岩芯和煤质资料对柴达木盆地北缘鱼卡煤田中下侏罗统大煤沟组地层河湖三角洲沉积体系进行高分辨率层序地层学分析,从中识别出短期、中期、长期3个级别的基准面旋回层序,划分出向上"变深"非对称型、向上"变浅"非对称型及对称型3种短期基准面旋回基本结构类型。依据等时地层对比法则进行不同级次基准面旋回层序的联井对比,建立了大煤沟组的等时地层格架,在等时地层格架内进行了煤层对比,并在等时地层格架内分析了聚煤规律。 相似文献
8.
9.
Tetraploid induced by physical and chemical methods in Jinjiang oyster(Crassostrea rivularis) 总被引:1,自引:0,他引:1
Rong Shoubai Shi Shumei Mo Qirong Liu Shaeqiong Liang Ze Zhao Xiuzhu Tong Wangdong Li Shouwu Li Yimin 《海洋学报(英文版)》1994,13(2):275-283
TetraploidinducedbyphysicalandchemicalmethodsinJinjiangoyster(Crassostrearivularis)¥RongShoubai,ShiShumei,McQirong,LiuShaeqio... 相似文献
10.
1 .IntroductionNondestructiveinspection (NDI)isveryimportantforensuringthereliabilityofoffshorestructuresintheirservicelives (Lauraetal.,1 996 ) .Itiswellknownthatdetectionofflawsinvolvesconsider ablestatisticaluncertainties.Asaresult,theprobabilityofdetection (POD)forallflawsofagivensizehasbeenusedintheliteraturetodefinethecapabilityofaparticularNDItechniqueinagivenen vironment.SincethedataofPODusuallyscatterlargely ,itisdifficulttodeterminewhichmodelfitstheavailabledatabest.Thismodelun… 相似文献