High to ultrahigh temperature contact metamorphism and dry partial melting of the Tasiuyak paragneiss,Northern Labrador

Contact aureoles of the anorthositic to granitic plutons of the Mesoproterozoic Nain Plutonic Suite (NPS), Labrador, are particularly well developed in the Palaeoproterozoic granulite facies, metasedimentary, Tasiuyak gneiss. Granulite facies regional metamorphism (M_R), c. 1860 Ma, led to biotite dehydration melting of the paragneiss and melt migration, leaving behind biotite‐poor, garnet–sillimanite‐bearing quartzofeldspathic rocks. Subsequently, Tasiuyak gneiss within a c. 1320 Ma contact aureole of the NPS was statically subjected to lower pressure, but higher temperature conditions (M_C), leading to a second partial melting event, and the generation of complex mineral assemblages and microstructures, which were controlled to a large extent by the textures of the M_R assemblage. This control is clearly seen in scanning electron microscopic images of thin sections and is further supported by phase equilibria modelling. Samples collected within the contact aureole near Anaktalik Brook, west of Nain, Labrador, mainly consist of spinel–cordierite and orthopyroxene–cordierite (or plagioclase) pseudomorphs after M_R sillimanite and garnet, respectively, within a quartzofeldspathic matrix. In addition, some samples contain fine‐grained intergrowths of K‐feldspar–quartz–cordierite–orthopyroxene inferred to be pseudomorphs after osumulite. Microstructural evidence of the former melt includes (i) coarse‐grained K‐feldspar–quartz–cordierite–orthopyroxene domains that locally cut the rock fabric and are inferred to represent neosome; (ii) very fine‐ to medium‐grained cordierite–quartz intergrowths interpreted to have formed by a reaction involving dissolution of biotite and feldspar in melt; and (iii) fine‐scale interstitial pools or micro‐cracks filled by feldspar interpreted to have crystallized from melt. Ultrahigh temperature (UHT) conditions during contact metamorphism are supported by (i) solidus temperatures >900 °C estimated for all samples, coupled with extensive textural evidence for contact‐related partial melting; (ii) the inferred (former) presence of osumilite; and (iii) titanium‐in‐quartz thermometry indicating temperatures within error of 900 °C. The UHT environment in which these unusual textures and minerals were developed was likely a consequence of the superposition of more than one contact metamorphic event upon the already relatively anhydrous Tasiuyak gneiss.     

The reaction history of kyanite in high‐P aluminous granulites

Cathodoluminescence (CL) mapping of kyanite in high pressure, aluminous granulites from the central Grenville Province reveals internal structures that are linked to their metamorphic reaction history. In two samples, individual kyanite crystals are shown to be composite porphyroblasts comprising three distinct generations, defined by their CL intensity and Cr (±V, Ti, Fe and Ga) content, and each separated by resorbed interfaces. In contrast, a sub‐aluminous sample contains two types of kyanite, one as resorbed inclusions in garnet and another in the groundmass or replacing garnet. These textural variants of kyanite are interpreted within the framework of phase equilibria modelling. In P–T pseudosections, a first generation of kyanite, which is only present in the most aluminous samples, is potentially linked to staurolite breakdown, and its resorption is consistent with a subsequent increase in pressure. This kyanite represents the earliest remnant of prograde metamorphism identifiable in these rocks. The second generation, present in the porphyroblasts in the same samples and as inclusions in garnet in the sub‐aluminous sample, is interpreted to be the peritectic product of muscovite dehydration melting. Resorption of this kyanite is consistent with subsequent continuous dehydration melting of biotite, which is also inferred based on microstructural considerations. The final generation of kyanite, present as rims on the prograde kyanite porphyroblasts in aluminous samples and as part of the groundmass or replacing garnet in the sub‐aluminous rock, is interpreted to have grown during melt crystallization upon retrogression. The presence of retrograde kyanite implies that the melt crystallized over a wide range of temperatures, and provides an important constraint on the P–T conditions of the metamorphic peak and on the retrograde P–T path. CL mapping is crucial for identifying retrograde kyanite in aluminous samples, as it preferentially overgrows existing kyanite rather than replacing other prograde phases. The scarcity of kyanite in sub‐aluminous rocks allows retrograde kyanite to grow as discrete crystals that can be identified by optical microscopy. This work attests to the potential of unconventional tools such as CL imaging for deciphering the metamorphic history of rocks.     

An electron‐optical study of melt‐related microstructures in granulite facies rocks from the Torngat Orogen

Cordierite–quartz and plagioclase–quartz intergrowths in a paragneiss from northern Labrador (the Tasiuyak Gneiss) were studied using SEM, STEM and TEM. The gneiss experienced granulite facies conditions and partial melting during both regional and, subsequently, during contact metamorphism. The microstructures examined all results from the contact metamorphism. Cordierite–quartz intergrowths occur on coarse and fine scales. The former sometimes exist as a ‘geometric’ intergrowth in which the interface between cordierite and quartz appears planar at the resolution of the optical microscope and SEM. The latter exists in several microstructural variants. Plagioclase is present as a minor component of the intergrowth in some examples of both the coarse and fine intergrowth. Grain boundaries in cordierite–quartz intergrowths are occupied by amorphous material or a mixture of amorphous material and chlorite. Cordierite and quartz are terminated by crystal faces in contact with amorphous material. Chlorite is sometimes found on cordierite surfaces and penetrating into cordierite grains along defects. Quartz contains (former) fluid inclusions 10–20 nm in maximum dimension. The presence of planar interfaces between cordierite and the amorphous phase is reminiscent of those between crystals and glass in volcanic rocks, but in the absence of compelling evidence that the amorphous material represents former melt, it is interpreted as a reaction product of cordierite. Plagioclase–quartz intergrowths occur in a number of microstructural variants and are commonly associated with cordierite–quartz intergrowths. The plagioclase–quartz intergrowths display simple, non‐planar interfaces between plagioclase and quartz. Quartz contains (former) fluid inclusions of dimensions similar to those observed in cordierite–quartz intergrowths. The boundary between quartz and enclosing K‐feldspar is cuspate, with quartz cusps penetrating a few tens of nanometres into K‐feldspar, commonly along defects in K‐feldspar and sometimes with very low dihedral angles at their tips. This cuspate microstructure is interpreted as melt pseudomorphs. The plagioclase–quartz intergrowths share some features with myrmekite, but differ in some respects: the composition of the plagioclase (An₃₇Ab₆₂Or₁–An₃₈Ab₆₁Or₁); the association with cordierite–quartz intergrowths; and microstructures that are atypical of myrmekite (e.g. quartz vermicules shared with cordierite–quartz intergrowths). It is inferred that the plagioclase–quartz intergrowths may have formed from, or in the presence of, melt. Inferred melt‐related microstructures preserved on the nanometre scale suggest that melt on grain boundaries was more pervasive than is evident from light optical and SEM observations.     

Crustal architecture above the high-pressure belt of the Grenville Province in the Manicouagan area: new structural, petrologic and U–Pb age constraints

Recent U–Pb age determinations and P–T estimates allow us to characterize the different levels of a formerly thickened crust, and provide further constraints on the make up and tectono-thermal evolution of the Grenville Province in the Manicouagan area. An important tectonic element, the Manicouagan Imbricate zone (MIZ), consists of mainly 1.65, 1.48 and 1.17 Ga igneous rocks metamorphosed under 1400–1800 MPa and 800–900 °C at 1.05–1.03 Ga, during the Ottawan episode of the Grenvillian orogenic cycle, coevally with intrusion of gabbro dykes in shear zones. The MIZ has been interpreted as representing thermally weakened deep levels of thickened crust extruded towards the NW over a parautochthonous crustal-scale ramp. Mantle-derived melts are considered as in part responsible for the high metamorphic temperatures that were registered.New data show that mid-crustal levels structurally above the MIZ are represented by the Gabriel Complex of the Berthé terrane, that consists of migmatite with boudins of 1136±15 Ma gabbro and rafts of anatectic metapelite with an inherited monazite age at 1478±30 Ma. These rocks were metamorphosed at about the same time as the MIZ (metamorphic zircon in gabbro: 1046±2 Ma; single grains of monazite in anatectic metapelite: 1053±2 Ma) and under the same T range (800–900 °C) but at lower P conditions (1000–1100 MPa). They are mainly exposed in an antiformal culmination above a high-strain zone, which has tectonic lenses of high P–T rocks from the MIZ and is intruded by synmetamorphic gabbroic rocks. This zone is interpreted as part of the hangingwall of the MIZ during extrusion. A gap of 400 MPa in metamorphic pressures between the tectonic lenses and the country rocks, together with the broad similarity in metamorphic ages, are consistent with rapid tectonic transport of the high P–T rocks over a ramp prior to the incorporation of the mafic lenses in the hangingwall.Between the antiformal culmination of the Gabriel Complex and the MIZ 1.48 Ga old granulites of the Hart Jaune terrane are exposed. They are intruded by unmetamorphosed 1228±3 Ma gabbro sills and 1166±1 Ma anorthosite. Hart Jaune Terrane represents relatively high crustal levels that truncate the MIZ-Gabriel Complex contact and are preserved in a synformal structure.Farther south, the Gabriel Complex is overlain by the Banded Complex, a composite unit including 1403+32/−25 Ma granodiorite and 1238+16/−13−1202+40/−25 Ma granite. This unit has been metamorphosed under relatively low-P (800 MPa) granulite-facies conditions. Metamorphic U–Pb data, limited to zircon lower intercept ages (971±38 Ma and 996±27 Ma) and a titanite (990±5 Ma) age, are interpreted to postdate the metamorphic peak.The general configuration of units along the section is consistent with extrusion of the MIZ during shortening and, finally, normal displacement along discrete shear zones.     

Anatectic record and contrasting P–T paths of aluminous gneisses from the central Grenville Province

Anatectic aluminous gneisses, some derived from sedimentary rocks of broadly pelitic composition and others from hydrothermally altered felsic volcanic rocks, are exposed in the mid‐P and high‐P segments of the hinterland in the central Grenville Province. These gneisses consist dominantly of garnet, biotite, K‐feldspar, plagioclase and quartz, with sillimanite or kyanite, and display microstructural evidence of anatexis by fluid‐absent reactions consuming muscovite and/or biotite. Melt‐related microstructures, such as inter‐granular films and/or interstitial quartz or feldspar enclosing relict phases, are most abundant in the metasedimentary samples. Despite anatexis at granulite facies conditions, the hydrothermally altered rocks preserve earlier features attributed to the circulation of hydrothermal fluids, such as sillimanite seams, dismembered quartz veins and garnet‐rich aluminous nodules in a K‐feldspar‐dominated matrix. Microstructural and mineral chemical data, integrated with P–T pseudosections calculated with thermocalc for the metasedimentary rocks, permit qualitative constraints on the P–T paths. Data from a high‐P kyanite‐bearing sample are consistent with a steep prograde P–T path up to ~14.5 kbar and 860–900 °C, followed by decompression with minor cooling to the solidus at ~11 kbar and 870 °C. This pressure‐dominated P–T path is similar to those inferred in other parts of the high‐P segment in the central Grenville Province. In contrast, the P–T path predicted from a mid‐P sillimanite‐bearing paragneiss has a strong temperature gradient with P–T of ~9.5 kbar and 850 °C at the thermal peak, and a retrograde portion down to ~8 kbar and 820 °C. In a broad sense, these two contrasting P–T patterns are consistent with predictions of thermo‐mechanical modelling of large hot orogens in which P–T paths with strong pressure gradients exhume deeper rocks in the orogenic flanks, whereas P–T paths with strong temperature gradients in the orogenic core reflect protracted lateral transport of ductile crust beneath a plateau.     

Metamorphic textures and P–T evolution of high-P granulites from the Lelukuau terrane, NE Grenville Province

High‐pressure (HP) granulites and eclogitized metagabbro are exposed along an orogen‐parallel high‐P belt that was developed at c. 1050–1020 Ma in the NE Grenville Province. Among these rocks, mafic granulites derived from a Labradorian anorthosite suite of the Lelukuau terrane contain garnet, Al‐Na diopside, and, depending on bulk composition, plagioclase and kyanite. Moreover, the distribution of phases is influenced by the original igneous texture. For instance, in high X_MgO leucocratic varieties, garnet porphyroblasts nucleated together with kyanite in An‐rich cores of plagioclase domains whereas in low X_MgO rocks garnet occurs together with clinopyroxene within formerly igneous ferromagnesian domains and kyanite is missing. In contrast, garnet pseudomorphs after igneous plagioclase in melanocratic varieties display evidence of earlier corona development. Metamorphic textures are consistent with a two stage evolution: (a) development of garnet and Al‐Na‐diopside (Cpx₁) under high‐P metamorphic conditions, concomitant with elimination of plagioclase in the mesocratic to melanocratic varieties; and (b) partial loss of Al‐Na from Cpx₁ resulting in production of new andesitic plagioclase, and growth of new clinopyroxene (Cpx₂) after garnet and quartz in leucocratic to mesocratic rocks consistent with decompression. Widespread equilibrium textures between garnet‐Pl₂‐Cpx₂ and/or reset Cpx₁ are consistent with development at the thermal peak. Estimated P–T conditions for the presumed thermal peak fall in the range 1500–1800 MPa and 800–900 °C and are comparable to those recorded by eclogitized gabbros from other parts of the high‐P belt of the NE Grenville province. Low jadeite content of clinopyroxene from the HP granulites is attributed to the low bulk Na₂O/(Na₂O + CaO) of these rocks relative to common basaltic compositions. Scarcity of apparent retrograde textural overprint in both the HP granulites and the eclogites suggests fast subsequent cooling, consistent with extrusion of the high‐P belt towards the foreland shortly after the metamorphic peak.     

Transformation of Fe–Ti gabbro to coronite, eclogite and amphibolite in the Baie du Nord segment, Manicouagan Imbricate Zone, eastern Grenville Province

Fe–Ti gabbros from the Baie du Nord Segment of the Manicouagan Imbricate Zone, metamorphosed under high P–T conditions during the Grenvillian orogeny, have been the focus of a detailed micropetrological study. Textures and mineral chemistry suggest that the mineral assemblages represent progressive stages of metamorphic transformation resulting in the formation of coronas, pseudomorphs after igneous phases (transitional) and true, granoblastic eclogites. The transitional and eclogitic samples also have coronas which are developed locally around igneous xenocrysts of plagioclase and olivine. The deformed margins of coronitic Fe–Ti gabbros are transformed to amphibolite and contain clinopyroxene-bearing leucosomes with garnet poikiloblasts that are indicative of high-P–T dehydration melting. Interpretation of garnet zoning and thermobarometry suggest that the highest P–T conditions are recorded by coronas around xenocrysts (c. 720–800 °C at 14–17 kbar) and garnet–clinopyroxene cores in granoblastic assemblages (c. 740–820 °C at 13–17 kbar) in the eclogitic samples. Re-equilibration during the early stages of exhumation at high-T conditions (>700 °C) affected all samples, and is evidenced by the widespread development of pargasite-bearing plagioclase collars in the coronitic and transitional metagabbros and by widespread re-equilibration of the eclogites giving lower P–T estimates at grain boundaries. However, the difference in calculated pressure conditions between coronite and eclogite samples is consistent with increasing pressure (depth) from the coronites (11–13 kbar) to the eclogites (13–17 kbar). The P–T conditions recorded by these rocks define a metamorphic field gradient which suggests high heat flow through the lower crust during the Grenvillian orogeny.