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1.
Jun Liu Letitia Topor Jianzhong Zhang Alexandra Navrotsky Robert C. Liebermann 《Physics and Chemistry of Minerals》1996,23(1):11-16
High temperature drop-solution calorimetry in molten 2 PbO · B2O3 at 1044 K for coesite and stishovite polymorphs of silica was carried out to determine the enthalpy of the coesite-stishovite transition. These experiments were performed on high-purity, single-phase samples of coesite and stishovite. Our new value for the enthalpy of the coesitestishovite transition (ΔH 298 0 ) is 29.85 ± 0.78 kJ/mol, which is about 35% lower than previously reported by Akaogi and Navrotsky (1984) and Holm et al. (1967), but which compares well with new measurements by Akaogi et al. (1994b). Using these new data, we have calculated the equilibrium phase boundary between coesite and stishovite and obtained a slope, dP/dT=0.0031 (2) GPa/K. This calculated slope is in good agreement with that determined [0.0026 (2) GPa/K] from the in-situ X-ray diffraction study of Zhang et al. (1996). 相似文献
2.
Anne J. Pedersen Iben V. Kristensen Lisbeth M. Ottosen Alexandra B. Ribeiro Arne Villumsen 《Engineering Geology》2005,77(3-4):331-338
When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m3 wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As. 相似文献
3.
Lisbeth M. Ottosen Anne J. Pedersen Alexandra B. Ribeiro Henrik K. Hansen 《Engineering Geology》2005,77(3-4):317-329
Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination. 相似文献
4.
Susan Ellsworth Alexandra Navrotsky Rodney C. Ewing 《Physics and Chemistry of Minerals》1994,21(3):140-149
Transposed temperature drop calorimetry at 1000 °C was performed on natural zircons (ZrSiO4) from Sri Lanka that were partially to completely metamict due to α-decay event damage (0.06 to 11.7×1015 α-decay events/mg). The enthalpy of annealing at room temperature (ΔHanneal) varies sigmoidally as a function of radiation dose. ΔHanneal reaches a saturation plateau at radiation doses greater than 5×1015 α-decay events/mg. The annealing of several samples to a crystalline structure with broadened diffraction peaks does not significantly affect the enthalpy of annealing. The large magnitude of the enthalpy of annealing plateau, ?59±3 kJ/mol, suggests that the damage to the structure is pervasive on the scale of Angstroms, consistent with the loss of mid-range order characteristic of a glass. The energetics are consistent with, but do not require, chemical heterogeneity caused by micro-domains of amorphous SiO2-rich and ZrO2-rich regions in the metamict state. 相似文献
5.
Charles?R.?SternEmail author Julien?M.?Allaz Markus?B.?Raschke G.?Lang?Farmer M.?Alexandra?Skewes Jeremy?T.?Ross 《Contributions to Mineralogy and Petrology》2018,173(8):65
Aplite dikes intruding the Proterozoic 1.42(±?3) Ga Longs Peak-St. Vrain Silver Plume-type peraluminous granite near Jamestown, Colorado, contain F, P, and rare earth element (REE)-rich globular segregations, with 40–46% REE, 3.7–4.8 wt% P2O5, and 5–8 wt% F. A combination of textural features and geochemical data suggest that the aplite and REE-rich globular segregations co-existed as two co-genetic liquids prior to their crystallization, and we propose that they are formed by silicate–fluoride?+?phosphate (+?S?+?CO2) melt immiscibility following ascent, cooling, and decompression of what was initially a single homogeneous magma that intruded the granite. The REE distribution coefficients between the silica-rich aplites and REE-rich segregations are in good agreement with experimentally determined distribution coefficients for immiscible silicate–fluoride?+?phosphate melts. Although monazite-(Ce) and uraninite U–Th–Pb microprobe ages for the segregations yield 1.420(±?25) and 1.442(±?8) Ga, respectively, thus suggesting a co-genetic relationship with their host granite, εNd1.42Ga values for the granites and related granitic pegmatites range from ??3.3 to ??4.7 (average ??3.9), and differ from the values for both the aplites and REE-rich segregations, which range from ??1.0 to ??2.2 (average ??1.6). Furthermore, the granites and pegmatites have (La/Yb)N <50 with significant negative Eu anomalies, which contrast with higher (La/Yb)N >100 and absence of an Eu anomaly in both the aplites and segregations. These data are consistent with the aplite dikes and the REE-rich segregations they contain being co-genetic, but derived from a source different from that of the granite. The higher εNd1.42Ga values for the aplites and REE-rich segregations suggest that the magma from which they separated had a more mafic and deeper, dryer and hotter source in the lower crust or upper mantle compared to the quartzo-feldspathic upper crustal source proposed for the Longs Peak-St. Vrain granite. 相似文献
6.
Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada 下载免费PDF全文
Rebecca N. Greenberger John F. Mustard Gordon R. Osinski Livio L. Tornabene Alexandra J. Pontefract Cassandra L. Marion Roberta L. Flemming Janette H. Wilson Edward A. Cloutis 《Meteoritics & planetary science》2016,51(12):2274-2292
Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe3+ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars. 相似文献
7.
Hiroko Watanabe Alexandra Tritschler Reizaburo Kitai Kiyoshi Ichimoto 《Solar physics》2010,266(1):5-16
We performed two-dimensional spectroscopic observations of the preceding sunspot of NOAA 10905 located off disk center (S8
E36, μ≈0.81) by using the Interferometric BI-dimensional Spectrometer (IBIS) operated at the Dunn Solar Telescope (DST) of the National
Solar Observatory, New Mexico. The magnetically insensitive Fe I line at 709.04 nm was scanned in wavelength repetitively
at an interval of 37 s to calculate sequences of maps of the line-wing and line-core intensity, and the line-of-sight Doppler
velocity at different line depths (3% to 80%). Visual inspection of movies based on speckle reconstructions computed from
simultaneous broadband data and the local continuum intensity at 709.04 nm revealed an umbral dot (UD) intruding rapidly from
the umbral boundary to the center of the umbra. The apparent motion of this object was particularly fast (1.3 km s−1) when compared to typical UDs. The lifetime and size of the UD was 8.7 min and 240 km, respectively. The rapid UD was visible
even in the line-core intensity map of Fe I 709.04 nm and was accompanied by a persistent blueshift of about 0.06 km s−1. 相似文献
8.
9.
Alexandra Schmäh 《Journal of Paleolimnology》1993,9(2):99-108
In paleolimnology, subfossil head capsules of chironomids play an important role as ecological indicators of lake history. It is important to determine, therefore, whether fossil assemblages are representative of former biocoenoses. There is evidence that headcapsules washed in from other places can make up a significant percentage of the total. As interpretations are usually drawn from the examination of a single core, it is of special interest to know whether a fossil assemblage of a single site properly reflects limnological conditions of the whole lake. This study examined the taxonomic distribution of subfossil chironomids in the surficial sediments of the Bodensee-Untersee, with the aim of assessing the variability in chironomid assemblages. Apparently, most of the head capsules of the profundal fossil assemblages in the Untersee had been washed in from the littoral zone or from the slope. Although the Bodensee-Untersee is a rather large lake, variability is surprisingly low among all samples. Therefore a correct interpretation from a single core may be possible. 相似文献
10.
In climate change impact research it is crucial to carefully select the meteorological input for impact models. We present a method for model selection that enables the user to shrink the ensemble to a few representative members, conserving the model spread and accounting for model similarity. This is done in three steps: First, using principal component analysis for a multitude of meteorological parameters, to find common patterns of climate change within the multi-model ensemble. Second, detecting model similarities with regard to these multivariate patterns using cluster analysis. And third, sampling models from each cluster, to generate a subset of representative simulations. We present an application based on the ENSEMBLES regional multi-model ensemble with the aim to provide input for a variety of climate impact studies. We find that the two most dominant patterns of climate change relate to temperature and humidity patterns. The ensemble can be reduced from 25 to 5 simulations while still maintaining its essential characteristics. Having such a representative subset of simulations reduces computational costs for climate impact modeling and enhances the quality of the ensemble at the same time, as it prevents double-counting of dependent simulations that would lead to biased statistics. 相似文献