Numerical and experimental studies of pressure-controlled cavity expansion in completely decomposed granite soils of Hong Kong

Compaction grouting is the injection of a viscous grout into a soil under high pressure, which then densifies the surrounding soil by reducing void space. Laboratory and field tests of compaction grouting have been carried out. In this paper, a numerical model is used to simulate the compaction grouting process with the primary purpose of investigating relationships among various control parameters, such as injection pressure, void ratio and excess pore water pressure at various radial distances from the injection point. The compaction process is treated as a cavity expansion process in the numerical simulation. The soil is modelled with an elasto-plastic Mohr–Coulomb model using the commercial finite element program ABAQUS. In addition to numerical simulations, pressure-controlled cavity expansion laboratory tests were carried out on completely decomposed granite (CDG) soil specimens. Data collected from laboratory tests are compared with the finite element simulation to validate the finite element analyses. Factors that control the compaction process, such as the coefficient of earth pressure (K), initial void ratio, number of loading cycles and effective confining pressure, are explored in the numerical simulations.     

Analytical problems in determining peptide nitrogen in the humic fractions of three Italian soils

Peptides were released from organic matter fractions of three Italian soils (humin, humic and fulvic acids), when the samples were hydrolyzed in Ba(ON)₂-saturated solution at 105°C for 2 hr. The peptides obtained were separated using electrophoresis and paper chromatography. The presence of polypeptides in the soil organic matter was indicated by: (1) their hydrolysis by pronase; (2) the amino acids released by 6 N HCl hydrolysis; (3) The comparison of i.r. spectra of humic fractions before and after hydrolysis with 6 N HCl.Attempts at isolating the native proteinaceous compounds using electrophoresis in polyacrylamide gel failed; additionally, our attempts to hydrolyze proteinaceous components enzymatically in unfractionated soil organic matter, as well as in its fractions, before and after methylation, with pepsin, papain and pronase, were unsuccessful. Pronase demonstrated a weak proteolytic activity only at very low substrate-enzyme ratios (20 : 1) in humic and fulvic fractions and in whole phyrophosphate extract. Deproteinated substrates treated with pronase also released free amino acids, suggesting autodigestion.In humin, humic and fulvic fractions we found a total amino acid content of 40–45%, 12–24% or 1–85, respectively. Amino acid recovery from single fractions was about 70–80% of the total content in the unfractionated soil.     

Crustal structure from an OBS survey of the Nootka fault zone off western Canada

Summary. The Nootka fault zone is the boundary between the small Explorer and Juan de Fuca plates which are situated between the America and Pacific plates off western Canada. To investigate the crustal structure in the region, three explosive/large airgun refraction lines were shot into three ocean bottom seismometers (OBSs) with three-component geophone assemblies. In this phase of the study, P -wave velocity—depth models are interpreted by comparison of the travel time and amplitude characteristics of the observed data with theoretical seismograms computed using a WKBJ algorithm. The interpretation gives relatively consistent results for the upper crust. However, the structure of the lower crust is significantly different among the various profiles. Upper mantle velocities range from 7.5 to 8.3 kms⁻¹ and the sub-bottom crustal thickness vanes from 6.4 to 11 km. Nevertheless, these seismic models are consistent in general terms with oceanic crustal models represented by ophiolite complexes. Some aspects of the differences among profiles can be explained by consideration of a recent tectonic model for the development of the fault zone. This requires, within a 1 Myr time interval, variations in the process of crustal formation at the ridge, crustal 'maturing', or both. The abnormally thick crust near a spreading centre may result in part from the complex interaction of the Juan de Fuca and Explorer plates with the larger and older America and Pacific plates. Upper mantle velocity variations are consistent with the concept of velocity anisotropy. The different record sections show that seismic energy is attenuated for ray paths traversing the Nootka fault zone.     

Use of ultrasonic treatment for extraction of humic acid with inorganic reagents from soil

The use of ultrasonic vibrations (1 hr) on the extraction of humic acids (HA) from a brown soil has been compared with the extraction by mechanical stirring (24 hr) with two extractants: 0.5 N and 0.1 M Na₄P₂O₇, followed by extraction with 0.5 N NaOH. In the pyrophosphate extraction, ultrasonic and mechanical treatments produced the same yield of HA. Further extraction with NaOH and mechanical stirring gave higher yields.The elemental composition of HA changed remarkably with both ultrasonic and mechanical systems. The HA extracted with ultrasonic treatment showed a higher ash content and a lower content of COOH and phenolic OH groups. These HA's showed higher optical density at 260 and 450 nm when pyrophosphate-extracted, and lower optical density when NaOH-extracted. Moreover the ultrasonic-treated HA in both extractants showed a lower E₄₀₀/E₆₀₀ ratio.Infrared examination confirmed the difference in chemical characteristics of extracted HA. The HA distribution in the different classes of nominal molecular weights by Sephadex gel filtration was influenced by both ultrasonic and mechanical systems, specially for molecular weights between 5000 and 150,000. It has been noted that the differences due to both systems are less marked than those caused by ssing different extractants.