Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

The Record of an Extreme Flood in the Sediments of Montane Lillooet Lake, British Columbia: Implications for Paleoenvironmental Assessment

Severe rainfall in mid October, 2003 produced the largest floods in almost a century of record on rivers in the Cordillera of southwestern British Columbia. Sediment deposited in Lillooet Lake as a result of this event is clearly distinguished by stratigraphy, colour, texture, magnetic properties, and organic content. Each of these physical properties is related to the lacustrine processes, especially turbid underflow, that distributed the sediment through the lake. The flood, which lasted less than a week, delivered 8–12 times the amount of sediment that accumulates in most entire years in the deepest, central parts of the lake. Recognition of events of this type in the stratigraphic record offers a means of assessing the changing nature of extreme hydroclimatic events, and their relation to more ubiquitous, lower-energy processes.     

Glaciolacustrine varved sediment as an alpine hydroclimatic proxy

The physical significance of a negative correlation between a varve record from Mud Lake, British Columbia, and temperature is discussed in the context of a process-network. The process-network is defined as the system of temporally and spatially connected processes involved in the transfer of a signal from climate to varved glaciolacustrine sediment. The six systems defining the network include climate, glacier, fluvial, geomorphic, terrestrial biologic and lacustrine systems to which each process belongs. A literature review outlines significant variation in the strength and character of correlations between components of the process-network and highlights that more comprehensive interpretations of varves as a hydroclimatic proxy require an improved understanding of the process-network. Documenting each process in the network is integral to informing a more complete model of this system, identifying processes that constitute signal transfer and assessing hydroclimatic proxies based on linear correlation. Such documentation is of growing importance as varved lacustrine sediments are increasingly used as a hydroclimatic proxy. The complex nature of the process-network requires greater emphasis on interdisciplinary cooperation and alternative methods to the linear statistical model.     

Geomagnetic secular variation since 1901

Summary. All available annual means, from the world-wide network of magnetic observatories, of north intensity ( X ), east intensity ( Y ) and vertical intensity (Z) from 1901 to 1977 are subjected to spherical harmonic analysis to obtain 38 models of the Earth's geomagnetic field at two-year intervals. These models are differenced to give 37 models of secular variation at two-year intervals from 1903.5 to 1975.5. The results show the decreasing trend of the dipole moment and are analysed for possible information on the westward drift of the magnetic field.     

Bacteria‐sediment associations in an alpine,freshwater environment and their effects on particle size,density and settling velocity

This study measures the presence of bacteria‐sediment associations (BSAs) in an alpine, glacier‐fed watershed in the Southern Coast Mountains of British Columbia, Canada. The impact of BSAs on the creation of flocculated particles and their settling velocity are quantified using a laser transmissometer. Results from the study indicate that BSAs are present in the watershed and vary over both space and time. The percentage of bacteria associated with sediment particles was found to range from < 1% to 40%. Major sources of planktonic bacteria such as agricultural land and wastewater treatment outflow co‐occur with large decreases in the BSA ratio. Laboratory analysis demonstrates that an increase in the concentration of bacteria was associated with a decrease in the volume concentration of small particles, and a decrease in both estimated density and measured settling velocity for particles in larger size classes; consistent with flocculated particles of increasing complexity arising from combinations of primary particles and/or BSAs. Paleoenvironmental reconstructions using laminated lake sediments in alpine, glacier‐fed systems benefit from a fuller understanding of the geomorphologic processes by which they formed. While bacteria are noted to enhance formation of flocculated particles in laboratory systems, their impact upon geomorphic processes in natural systems have yet to be fully explored. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Chloritoid stability in very iron-rich altered pillow lavas

Conclusions Our major conclusions are that the strong correlation of P₂O₅ and light REE abundances in basalts does not (a) require residual apatite or whitlockite during partial melting, or (b) imply that P₂O₅ and REE-rich magmas are derived from more refractory sources than the source of magmas with lower P₂O₅ and REE contents.     

Lithostratigraphy of the Mérida (Wisconsinan) glaciation and Pedregal interstade, Mérida Andes, northwestern Venezuela

At Pedregal, more than 40 m of sediments are exposed within a ‘fan complex’ formed between lateral moraines of the adjacent Mucuchache and El Caballo valleys. Early and late Mérida (Wisconsinan) glaciations are represented by till and till plus proglacial sediments, respectively. A middle Wisconsinan interstadial event, here termed the Pedregal interstade, began at the end of the Early Mérida glaciation at approximately 60 ka BP. Following the retreat of ice from the small Pedregal Basin, a lake formed when the local drainage was blocked due to movement of the Mesa de Caballo along the Boconó Fault. Shallow lake or no-lake phases lasted approximately a few hundred to, at most, 2000 years, and each lake phase was marked by peat accumulation. Four of seven peats identified formed during sufficiently long intervals for soil profiles (incipient to mature Spodosols) also to develop. The Spodosol with the strongest development (Eb/Bsb/Coxb/Cub horizons) is found adjacent to the lowest peat and reflects ongoing early Mérida stadial (MIS 3) conditions; the youngest peats, associated with weak podzolic soils (Eb/Bsb horizons), formed under slightly warmer interstadial conditions, presumably with less soil water. Cyclic lacustrine deposition is related to lake level and relative depth fluctuations, due in part to variable shoreline/delta progradation and shallowing as the lake deepened in general. Whereas final drainage of the lake is related to movement of the Boconó Fault and breach of the moraines that form the Mesa de Caballo, earlier lake level fluctuations appear related to climate change. Radiocarbon dating of the peats suggests they are related to warmer periods and may tentatively correlate with small ‘interstadials’ or ‘D-O events’ detected in the oxygen-isotope record of Greenland ice cores and North Atlantic marine sediments.     

Thermodynamic constraints on phase changes as earthquake source mechanisms in subduction zones

Application of thermodynamic equations for phase transitions with a shock wave output from metastable to stable phases that are believed to occur in subduction zones indicates that while many show a volume reduction, and thus may contribute to slab pull mechanisms of plate tectonics, they do not satisfy criteria for the generation of shock waves. Of the reactions considered only one (antigorite + clinoenstatite → forsterite + talc) satisfies the criteria, and for this case the shock wave pressure is, in fact, less than the pressure calculated for the leading edge of the subduction zone. This would imply that if the transition does occur under shock conditions in the subduction zone, dilatational rather than compressional first motions for the associated earthquake are expected.     

Monopoly

Summary. A model for the geomagnetic secular variation field is given, consisting of a series of magnetic monopoles at the surface of the Earth's core. These are distributed according to the density of the data to allow more detailed representation in areas where the density of observations is high, without introducing spurious detail where data are sparse. A monopole model is calculated from observatory secular change data for the epoch 1957.5–1962.5 and its usefulness assessed.     

Inferred heat transfer mechanisms and tectonic development of planets and satellites

A schematic diagram showing the relative importance of conduction, convection and hotspots as heat transfer mechanisms on planets has been previously described by Solomon and Head (1982). In their construction they assumed that the majority of heat transfer on Earth involved mantle convection (and hence, plate recycling), with Io and Mercury dominated by hotspot and conduction, respectively. This diagram is here quantified and used to deduce the tectonic regime of Jovian and Saturnian satellites.