Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

COMPARISON OF MEASUREMENT METHODS BASED ON A MODEL FOR THE ERROR STRUCTURE

Comparison of methods is a technique often used for investigation of systematic errors of measurementmethods.As concerns the design and analysis of such comparisons,much variety of opinion and practiceexists.In one approach a few specimens are measured several times by different operators in differentlaboratories(reproducibility conditions)and in another approach several specimens are measured on oneor a few occasions by one operator in the same laboratory(repeatability conditions).In this paper amodel for the error structure of measurements is formulated and it is emphasized that one has todistinguish between two types of systematic errors:the first type depends only on the level of themeasured quantity and the second type is specific for the separate specimens.On the basis of this modelthe information which can be obtained from the different designs of method comparisons is discussed.A new approach for the analysis of method comparisons with many specimens is also proposed.     

Appraisal of soft computing techniques in prediction of total bed material load in tropical rivers

This paper evaluates the performance of three soft computing techniques, namely Gene-Expression Programming (GEP) (Zakaria et al 2010), Feed Forward Neural Networks (FFNN) (Ab Ghani et al 2011), and Adaptive Neuro-Fuzzy Inference System (ANFIS) in the prediction of total bed material load for three Malaysian rivers namely Kurau, Langat and Muda. The results of present study are very promising: FFNN (R ² = 0.958, RMSE = 0.0698), ANFIS (R ² = 0.648, RMSE = 6.654), and GEP (R ² = 0.97, RMSE = 0.057), which support the use of these intelligent techniques in the prediction of sediment loads in tropical rivers.     

Sedimentary response of Pagham Harbour, southern England to barrier breaching in AD 1910

This paper examines the evolution of Pagham Harbour, southern England following storm-induced breaching of a protective barrier in AD 1910. Stratigraphic studies of sediments collected from intertidal areas show the presence of a distinct stratigraphic horizon in the northeast of Pagham Harbour at ca. 0 to +1.0 m ordnance datum (OD). Radiometric data indicate that this horizon is a ‘reclamation surface’ formed after land claim in AD 1846. Following marine flooding in AD 1910, sediment has accreted relatively rapidly (at a broadly constant rate of between 4 and 8 mm a⁻¹), wave and/or tidal energy have decreased and extensive marshes have developed. An asymptotic reduction in sediment accretion rate through time, as predicted in various theoretical models of salt marsh accretion, is not observed. Over the entire Pagham Harbour area, the period between AD 1948 and AD 1986 has seen an average marsh loss of 0.0087 km² a⁻¹, which is relatively small in comparison with other more exposed sites in the local area. Historically breached sites such as Pagham Harbour are common around European coasts, and these provide important natural laboratories within which the medium-term (decadal to centennial) coastal response to barrier breaching, and to managed-realignment coastal protection schemes, can be assessed.     

Sources and timing of trace metal contamination to sediments in remote sealochs,N.W. Scotland

Sediment cores from a transect of sealochs, Etive, Sunart, Nevis, Duich, Broom and Torridon in N.W. Scotland were analysed for the trace metals lead, copper, and zinc. In addition, sediment cores from the Clyde Sea Basin (Loch Fyne, the Gareloch, Clyde dumpsite) and from the Irish and Celtic Seas were analysed as possible source areas for contaminated particles. The sediment cores were dated using excess ²¹⁰Pb and ¹³⁷Cs, and Al normalisation was used to correct for sediment compositional effects. All cores showed increased concentrations of all trace metals (and M/Al) towards the surface, with a maximum of 280–500% above background being observed in Loch Etive. Only cores from Duich and Torridon (Zn/Al and Pb/Al) and Etive (Zn/Al) did not continue to show an increase in trace metals to the uppermost samples. The burden of atmospherically derived trace metals accumulated over the past 100 years was compared with similar published burdens from a series of freshwater lochs adjacent to the sealochs. Plots of excess ²¹⁰Pb (used to correct for sediment focusing) against atmospherically derived Pb showed a series of linear relationships of systematically decreasing gradient towards the north-west, away from potential urban sources of lead. It was calculated that 49% (15–77%) of the Pb but only 3% (1–4%) of the Zn and 2% (0–3%) of the Cu reached the sealochs from atmospheric sources. The remaining trace metals deposited in the sealochs came from marine particles. Using trace metal ratios as an indicator of pollutant provenance, it was shown that the trace metals came predominantly from the Irish Sea. There was no evidence of trace metals derived from the Firth of Clyde basin. It was concluded that trace metal contamination from the Clyde and the surrounding industrialised urban area was mainly deposited in the estuary and the Clyde Sea basin with its adjoining sealochs, such as the Gareloch and Loch Fyne.     

Bedload transport of small rivers in Malaysia

Numerous time-consuming equations, based on the relationship between the reliability and representativeness of the data utilized in defining variables and constants, require complex parameters to estimate bedload transport. In this study the easily accessible data including flow discharge, water depth, water surface slope, and surface grain diameter （ds0） from small rivers in Malaysia were used to estimate bedload transport. Genetic programming （GP） and artificial neural network （ANN） models are applied as complementary tools to estimate bed load transport based on a balance between simplicity and accuracy in small rivers. The developed models demonstrate higher performance with an overall accuracy of 97% and 93% for ANN and GP, respectively compared with other traditional methods and empirical equations.     

A MULTIBLOCK PARTIAL LEAST SQUARES ALGORITHM FOR INVESTIGATING COMPLEX CHEMICAL SYSTEMS

The details of a general multiblock partial least squares(PLS)algorithm based on one originallypresented by Wold et al.have been developed and are completely presented.The algorithm can handlemost types of relationships between the blocks and constitutes a significant advancement in the modelingof complex chemical systems.The algorithm has been programmed in FORTRAN and has been testedon two simulated multiblock problems,a three-block and a five-block problem.The algorithm combinesthe score vectors for all blocks predicting a particular block into a new block.This new block is used topredict the predicted block in a manner analogous to the two-block PLS.In a similar manner if one blockpredicts more than one other block,the score vectors of all predicted blocks are combined to form a newblock,which is then predicted by the predictor block as in the two-block PLS.Blocks that both predictand are predicted are treated in such a way that both of these roles can be taken into account whencalculating interblock relationships.The results of numerical simulations indicate that the computerprogram is operating properly and that the multiblock PLS produces meaningful and consistent results.     

Geochemical and stratigraphic indicators of late Holocene coastal evolution in the Gythio area, southern Peloponnese, Greece

The study of past changes in sea level, and of historical and pre-historical coastal evolution, using coastal sediment stratigraphies is well-established over a range of geographic areas, in both seismic and aseismic settings. In the eastern Mediterranean, however, such studies are less common, and, notably, the use of sediment geochemistry, and its combination with lithostratigraphic studies to analyze palaeoenvironmental and palaeo-sea-level change, has not been explored to any significant extent, despite the fact that geochemical data have been successfully used elsewhere to aid in the identification of sea-level changes. Here, we use a combined geochemical, stratigraphic and microfossil approach to reconstruct late Holocene coastal evolution and sea-level change at two sites near Gythio in the southern Peloponnese, Greece. The sites show stratigraphic and geochemical evidence of the presence in Late Helladic times (ca. 1500 BC) of barrier-protected coastal lagoonal/wetland environments, which have gradually infilled over the last ca. 3500 yr. Archaeological remains and ceramic and charcoal-bearing horizons within the sediment sequences indicate Late Roman occupation of the area, although there is no sedimentary evidence of significant pre-Roman activity at the study sites. An apparent brackish wetland peat deposit at − 3.4 m (overlain by anoxic lagoonal clays) at Kamares (Kato Vathi) Bay shows a calibrated radiocarbon age of 1640–1440 BC, suggesting a relative sea-level rise of 0.8–1 mm/yr in this area over the past 3500 yr, in good agreement with previous archaeological and sea-level modelling studies. There is no evidence, based on the stratigraphic, microfossil or geochemical record, of sudden marine flooding events related to local or regional seismic activity, despite the presence of the area in a seismically active zone known to be subject to periodic earthquakes and tsunami. The data highlight the utility of combining geochemical and stratigraphic studies in the reconstruction of coastal evolution and the study of palaeo-sea-level changes, particularly in sequences (such as those described here) where microfossils are poorly preserved.     

Recent estuarine sedimentation rates from shallow inter-tidal environments in western Scotland: implications for future sea-level trends and coastal wetland development

During the mid-late Holocene large sections of the Scottish coastline have been characterized by falling relative sea-levels resulting from differential glacio-isostatic uplift of this region of northern Britain. The complex interplay between crustal and sea-level movements continues to influence the morphological development of the Scottish coast. A number of geophysical models predict ongoing uplift of the Scottish landmass. However, a number of recent studies based upon the analysis of satellite altimetry data indicate a late 20th Century acceleration in the rate of eustatic sea-level rise.Detailed geochemistry, radiometric dating, and diatom analysis on selected sediment cores from four mature coastal marsh environments in Argyll, western Scotland, provides an opportunity to investigate the linkages between Twentieth century crustal movements, eustatic sea-level rise and recent rates of sedimentation recorded within marsh sediments across the proposed Scottish glacio-isostatic uplift dome.Solid-phase major and trace element geochemistry has been used to examine the extent to which post-depositional physical disturbance and/or chemical reactions may have influenced the reliability of the radiometric dating methods. Geochemical data indicate that the evolution of these marsh environments has not been significantly influenced by physical disturbance and overall the supply of minerogenic material to the marshes has been quite uniform.Vertical distributions of ²¹⁰Pb_excess and ¹³⁷Cs activity have been measured and used to develop models of recent marsh vertical accretion. Dating of the cores reveals subtle variations in the rates of sediment accumulation over the last c. 70 years between sites. For much of the last hundred years or so, sedimentation rates have been in good overall agreement with various estimations for sea-level rise, although at the more easterly sites these estimates are generally exceeded. However, quasi-equilibrium between marsh sedimentation and sea-level rise for much of the Twentieth Century is indicated from the Diatom analysis.Over the most recent period of marsh development (<10 years), a significant increase in the rate of surface sedimentation is recorded at all sites across the study area. Diatom analysis of these surface layers reveals an increase in the relative abundance of marine (polyhalobous) taxa in the near-surface sediments. This signifies a very recent increase in the rate of regional relative sea-level rise indicating that a regional threshold in coastal forcing has now been exceeded.These findings provide clear evidence that recent relative sea-level rise is now outpacing estimated rates of glacio-isostatic adjustment (GIA) across the proposed Scottish uplift dome.