Watershed morphometric analysis of Wadi Baish Dam catchment area using integrated GIS-based approach

The integration of Remote Sensing (RS) and Geographic Information Systems (GIS) constitutes a powerful tool for the evaluation of watershed morphometric parameters. The benefits of this integration include saving time and effort as well as improving the accuracy of the analysis. Moreover, this technique is appropriate for describing the watershed and its streams. In this study, a detailed morphometric analysis of the Wadi Baish catchment area has been performed using the Shuttle Radar Topography Mission (SRTM). The performed morphometric analysis includes linear, areal, and relief aspects. The results of the morphometric analysis reveal that the catchment can be described as of eighth stream order and consists of an area of 4741.07 km². Additionally, the basin is characterized by a relatively high mean value of bifurcation (4.012), indicative of the scarcity of permeable rocks with high slope in the area. This value of bifurcation ratio is consistent with the high drainage density value of 2.064 km/km² and confirms the impermeability of the subsurface material and mountainous relief. The hypsometric integral of the catchment is 47.4%, and the erosion integral of the catchment is 52.6%, both were indications of a mature catchment area.     

Evaluating the use of 3'-(p-Aminophenyl) fluorescein for determining the formation of highly reactive oxygen species in particle suspensions

Background  

Given the importance of highly reactive oxygen species (hROS) as reactants in a wide range of biological, photochemical, and environmental systems there is an interest in detection and quantification of these species. The extreme reactivity of the hROS, which includes hydroxyl radicals, presents an analytical challenge. 3'-(p-Aminophenyl) fluorescein (APF) is a relatively new probe used for measuring hROS. Here, we further evaluate the use of APF as a method for the detection of hydroxyl radicals in particle suspensions.     

Investigating parabolic and nebkha dune formation using a cellular automaton modelling approach

Vegetation plays an important role in shaping the morphology of aeolian dune landscapes in coastal and semi‐arid environments, where ecogeomorphic interactions are complex and not well quantified. We present a Discrete ECogeomorphic Aeolian Landscape model (DECAL) capable of simulating realistic looking vegetated dune forms, permitting exploration of relationships between ecological and morphological processes at different temporal and spatial scales. The cellular automaton algorithm applies three simple rules that lead to self‐organization of complex dune environments, including nebkhas with distinctive deposition tails that form in association with mesquite‐type shrubs, and hairpin (long‐walled) parabolic dunes with trailing ridges that evolve from blowouts in association with vegetation succession. Changing the conditions of simulations produces differing landscapes that conform qualitatively to observations of real‐world dunes. The model mimics the response of the morphology to changes in sediment supply, vegetation distribution, density and growth characteristics, as well as initial disturbances. The introduction of vegetation into the model links spatial and temporal scales, previously dimensionless in bare‐sand cellular automata. Grid resolutions coarser than the representative size of the modelled vegetation elements yield similar morphologies, but when cell size is reduced to much smaller dimensions, the resultant landscape evolution is dramatically different. The model furthermore demonstrates that the relative response characteristics of the multiple vegetation types and their mutual feedback with geomorphological processes impart a significant influence on landscape equilibria, suggesting that vegetation induces a characteristic length scale in aeolian environments. This simple vegetated dune model illustrates the power and versatility of a cellular automaton approach for exploring the effects of interactions between ecology and geomorphology in complex earth surface systems. Copyright © 2007 John Wiley & Sons, Ltd.     

Abiotic ammonium formation in the presence of Ni-Fe metals and alloys and its implications for the Hadean nitrogen cycle

Experiments with dinitrogen-, nitrite-, nitrate-containing solutions were conducted without headspace in Ti reactors (200°C), borosilicate septum bottles (70°C) and HDPE tubes (22°C) in the presence of Fe and Ni metal, awaruite (Ni₈₀Fe₂₀) and tetrataenite (Ni₅₀Fe₅₀). In general, metals used in this investigation were more reactive than alloys toward all investigated nitrogen species. Nitrite and nitrate were converted to ammonium more rapidly than dinitrogen, and the reduction process had a strong temperature dependence. We concluded from our experimental observations that Hadean submarine hydrothermal systems could have supplied significant quantities of ammonium for reactions that are generally associated with prebiotic synthesis, especially in localized environments. Several natural meteorites (octahedrites) were found to contain up to 22 ppm N_tot. While the oxidation state of N in the octahedrites was not determined, XPS analysis of metals and alloys used in the study shows that N is likely present as nitride (N^3-). This observation may have implications toward the Hadean environment, since, terrestrial (e.g., oceanic) ammonium production may have been supplemented by reduced nitrogen delivered by metal-rich meteorites. This notion is based on the fact that nitrogen dissolves into metallic melts.     

Ecogeomorphic state variables and phase‐space construction for quantifying the evolution of vegetated aeolian landscapes

Cellular automaton modelling for the simulation of dune field formation and evolution has developed progressively in aeolian geomorphology in the last decade or so. A model that incorporates the effects of vegetation and its interactions with geomorphic landscape development – the Discrete Ecogeomorphic Aeolian Landscapes (DECAL) model – can replicate a number of important visual and qualitative aspects of the complex evolution of aeolian dune landscapes under the influence of vegetation dynamics in coastal environments. A key challenge in this research area is the analysis and comparison of both simulated and real‐world vegetated dune landscapes using objective and quantifiable principles. This study presents a methodological framework or protocol for numerically quantifying various ecogeomorphic attributes, using a suite of mathematically defined landscape metrics, to provide a rigorous and statistical evaluation of vegetated dune field evolution. Within this framework the model parameter space can be systematically explored and simulation outcomes can be methodically compared against real‐world landscapes. Based on a simplified scenario of parabolic dunes developing out of blow‐outs the resulting dune field realizations are investigated as a function of variable growth vigour of two simulated vegetation types (pioneer grass and successional woody shrub) by establishing a typological phase‐diagram of different landscape classes. The set of simulation outcomes furthermore defines a higher‐dimensional phase‐space, whose axes or dimensions can be interpreted by analysing how individual ecogeomorphic landscape metrics, or state variables, contribute to the data distribution. Principal component analysis can reduce this to a visual three‐dimensional (3D) phase‐space where landscape evolution can be plotted as time‐trajectories and where we can investigate the effects of changing environmental conditions partway through a simulation scenario. The use of landscape state variables and the construction of a 3D phase‐space presented here may provide a general template for quantifying many other eco‐geomorphic systems on the Earth's surface. Copyright © 2010 John Wiley & Sons, Ltd.     

Adenine oxidation by pyrite-generated hydroxyl radicals

Cellular exposure to particulate matter with concomitant formation of reactive oxygen species (ROS) and oxidization of biomolecules may lead to negative health outcomes. Evaluating the particle-induced formation of ROS and the oxidation products from reaction of ROS with biomolecules is useful for gaining a mechanistic understanding of particle-induced oxidative stress. Aqueous suspensions of pyrite particles have been shown to form hydroxyl radicals and degrade nucleic acids. Reactions between pyrite-induced hydroxyl radicals and nucleic acid bases, however, remain to be determined. Here, we compared the oxidation of adenine by Fenton-generated (i.e., ferrous iron and hydrogen peroxide) hydroxyl radicals to adenine oxidation by hydroxyl radicals generated in pyrite aqueous suspensions. Results show that adenine oxidizes in the presence of pyrite (without the addition of hydrogen peroxide) and that the rate of oxidation is dependent on the pyrite loading. Adenine oxidation was prevented by addition of either catalase or ethanol to the pyrite/adenine suspensions, which implies that hydrogen peroxide and hydroxyl radicals are causing the adenine oxidation. The adenine oxidation products, 8-oxoadenine and 2-hydroxyadenine, were the same whether hydroxyl radicals were generated by Fenton or pyrite-initiated reactions. Although nucleic acid bases are unlikely to be directly exposed to pyrite particles, the formation of ROS in the vicinity of cells may lead to oxidative stress.     

Pyrite oxidation inhibition by a cross-linked lipid coating

The effect of a diacetylene-containing phospholipid on the oxidation of pyrite, FeS₂, was investigated. Earlier work reported by our research group showed that the adsorption of l,2-bis(10,12-tricosadiynoyl)-sn-glycero-3-phosphocholine on pyrite suppressed the extent of its oxidation by about 75% over a specific time period. Results presented here show that the pre-exposure to UV radiation of this lipid after sorption onto pyrite results in a 90% suppression. Attenuated total reflection (ATR) Fourier transform infra-red spectroscopy (FTIR) suggests that the UV irradiation of the lipid does not result in degradation of the adsorbed layer. It is believed that the UV exposure results in the cross-linking and polymerization of the adsorbed phospholipid into a relatively impermeable barrier that separates the pyrite from the aqueous phase. The results of this study might have implications for the protection of pyrite from oxidation in the environment.     

Sulfur geochemistry of hydrothermal waters in Yellowstone National Park,Wyoming, USA. III. An anion-exchange resin technique for sampling and preservation of sulfoxyanions in natural waters

A sampling protocol for the retention, extraction, and analysis of sulfoxyanions in hydrothermal waters has been developed in the laboratory and tested at Yellowstone National Park and Green Lake, NY. Initial laboratory testing of the anion-exchange resin Bio-Rad™ AG1-X8 indicated that the resin was well suited for the sampling, preservation, and extraction of sulfate and thiosulfate. Synthetic solutions containing sulfate and thiosulfate were passed through AG1-X8 resin columns and eluted with 1 and 3 M KCl, respectively. Recovery ranged from 89 to 100%. Comparison of results for water samples collected from five pools in Yellowstone National Park between on-site IC analysis (U.S. Geological Survey mobile lab) and IC analysis of resin-stored sample at SUNY-Stony Brook indicates 96 to 100% agreement for three pools (Cinder, Cistern, and an unnamed pool near Cistern) and 76 and 63% agreement for two pools (Sulfur Dust and Frying Pan). Attempts to extract polythionates from the AG1-X8 resin were made using HCl solutions, but were unsuccessful. Bio-Rad™ AG2-X8, an anion-exchange resin with weaker binding sites than the AG1-X8 resin, is better suited for polythionate extraction. Sulfate and thiosulfate extraction with this resin has been accomplished with KCl solutions of 0.1 and 0.5 M, respectively. Trithionate and tetrathionate can be extracted with 4 M KCl. Higher polythionates can be extracted with 9 M hydrochloric acid. Polythionate concentrations can then be determined directly using ion chromatographic methods, and laboratory results indicate recovery of up to 90% for synthetic polythionate solutions using AG2-X8 resin columns.     

Comment on the effect of anisotropy on the onset of convection in a porous medium

The effect of anisotropy on the onset of convection in a saturated porous medium is discussed. In particular, the case of time-dependent density-driven convection is examined. The applicability of the value of an equivalent Rayleigh number as the criterion for the onset of convection is discussed.