A NEW TYPE OF ISOTHERM FOR ZINC LIQUID-SOLID PARTITIONING ON δ-MnO_2,γ-MnOOH AND MANGANIIE IN SEAWATER

This article deals with the interaction of zinc with δ-MnO2,γ-MnOOH and manganite existing in natural water systems. The mechanism of the reaction has been studied in detail. From the fact that the "ratio of ion exchange (%)-pH" graph is an "S shaped" curve, it is possible to deduce that the chemical reaction is of the nature of cation exchange. And since the pH range of ion exchange = 4, it is possible to further deduce that the reaction can be explained by the mechanism of monovalence cation exchange.The main result of this article is the discovery of a new type of isotherm which has not been mentioned in previous literature here and abroad. This isotherm cannot be represented by any presently available adsorption isotherm equations in marine chemistry. The characteristics of this new type of isotherm are as follows: the isotherm has two "knees" and three "plateaus", the heights of these three "plateaus" are in the ratio 1:2:3. In order to explain theoretically our new isotherm, this article suggest     

莫桑比克楠普拉省喀祖祖地区砂金成因及其对岩金指示意义

莫桑比克楠普拉省喀祖祖地区多条河流均有人工砂金开采活动.砂金分布在海拔300～450 m之间的石英砾石层,底部岩石主要为中元古代片麻状杂岩体.研究区为准平原-丘陵地貌,水动力条件受季节影响较大.砂金分布与河流不存在明显的耦合性,暗示了原生金矿化可能较分散.同时,研究区露头受第四纪覆盖严重,物化探效果不显著,砂金与重砂矿...     

废黄河三角洲典型钻孔XJ01全新世地层与微体古生物记录

钻孔XJ01位于废黄河三角洲滨淮镇附近,钻孔中上更新统顶部与全新统有4个14C测年数据控制,该孔全新统岩性特征自下而上为潮间带含贝壳砾质砂层、浅海相淤泥质黏土层、三角洲前缘相深灰色粉砂、三角洲平原相黏土质粉砂及粉砂质黏土。全新统微体古生物分析结果详细地反映了废黄河三角洲典型区域各时期的沉积环境,其中,全新统下部见大量的有孔虫与海相介形虫,中部微体古生物略少,上部地层中海相介形虫增多。整个全新世微体生物组合揭示了一个河口变化的水动力控制沉积环境。     

苏北废黄河三角洲地区浅表沉积物特征和指示意义

苏北废黄河三角洲是中国东部沿海研究海陆交互作用的重要区域,在该区域开展槽型钻和基坑剖面调查,同时采集泥炭层样品进行¹⁴C测年,结果显示废黄河三角洲区域浅表主要分布以淤泥质黏土、黏土或砂黏互层的“千层饼”状沉积物为主的潮坪-潟湖-砂坝相沉积层,以及以细砂、粉砂等砂质为主的废黄河沉积层,其形成时间分别为5—7 ka B.P.(中全新世早—中期)及12—19世纪黄河夺淮期间。因此认为全球性气候变化是废黄河三角洲区域沉积环境演变的主导因素,中全新世早—中期全球性的气温升高和降雨增多造成入海沉积物的增加,形成了全区广泛分布的以潮坪、潟湖、砂坝等微地貌为主的海陆交互相沉积;12—19世纪黄河夺淮期间携带大量泥沙入海,与人类改造活动共同控制了废黄河三角洲现代地貌的形成。