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1.
This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies. 相似文献
2.
A formulation for the aerodynamic roughness length of air flow over wind waves $$z_0 = \gamma {\text{ }}u_* /\sigma p$$ which was proposed by Toba (1979) and Toba and Koga (1986) from dimensional considerations with some data analysis, is shown to correspond with a formulation for irregular solid surfaces $$(z_0 /h) = a(h/l)^{1 + \beta } $$ which resulted from work by Woodinget al. (1973) and Kustas and Brutsaert (1986);u * is the friction velocity,σ p the spectral peak frequency of wind waves,h the mean height of the solid obstacles,l the mean distance between their crests, andα,Β, andγ are constants. This correspondence is reached by the existence of a statistical 3/2-power law and an effective dispersion relationship for wind waves. Because both approaches of parameterizingz 0 were arrived at independently, they provide each other mutual reinforcement. 相似文献
3.
Iodate (IO3−) is the predominant dissolved species of iodine in the oxygenated waters of the Mediterranean Sea. Iodide (I−) is present in significant quantities (up to 65 nM) in oxygenated waters in the photic zone and near the interface above the anoxic and saline Bannock Basin. Lesser quantities of I− (< 10 nM) are found throughout the rest of the oxic water column. An additional unidentified dissolved iodine species is present immediately above the anoxic interface.Total dissolved iodine (ΣI) increases dramatically across the seawater/brine interface. Part of this increase is undoubtedly the result of the dissolution of iodine-rich evaporites during formation of the brine bodies at the Tyro and Bannock Basins. The vertical distribution of ΣI and other dissolved chemical species (particularly PO43−) in the Bannock Basin brine, however, suggests an additional, present-day, diagenetic source of dissolved iodine to the brine. Based on the increase in the concentration of the most soluble major ions across the seawater/brine interface, 5–7 μM of the 11.5-μM increase in ΣI concentration must be attributed to diagenesis. 相似文献
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5.
De Lange N 《Erdkunde》1993,47(1):61-74
The reduction of the rate of growth of the Brazilian population from 3% in the 1960s to 2% by 1993 resulted from a significant reduction of fertility. According to the 1986 national maternal-child health and family planning survey (PNSMIPF) results, 43.3% of women were using some type of contraception: 65.6% of married or cohabiting women. Women relied most on sterilization (17.2%), followed by oral contraceptives (OCs) (17%), the rhythm method (2.8%), the condom (1.1%), and others (5.2%). Only in the south was OC use more prevalent (28.5%) than sterilization (12.2%). The proportion of sterilization reached 27.8% in the north/center-east urban regions. In urban areas sterilization averaged 18.7% vs. 12.7% in rural areas. 26.9% of currently married women in the age range of 15-44 years had been sterilized. A 1990 international estimation indicated that the proportion of sterilization amounted to 36.9% in China, 30.95 in India, 29.7% in Brazil, 47.6% in South Korea, 30.4% in Thailand, and 36.5% in the Dominican Republic. The 1986 PNSMIPF survey also indicated that sterilized women were better informed than other women about contraception. 75% of the former had used OCs, 5% had used the diaphragm, 3% the IUD, 30% the condom, and 35% coitus interruptus at one time or other. The sterilized women had an average of 1.7 more children than those who were using other methods of contraception. 48.6% of women were sterilized before the age of 30, when they had had an average of 3.6 children. 66.6% of the sterilized women who had given birth before the age of 20 had 4 or more live births as compared to 5.9% of sterilized women aged 30 with the same number of children. 47% of women without any schooling were using some kind of contraception vs. 77% of those who had completed secondary school. A multivariate analysis also showed that the age of the mother, the number of live births, the educational status of the mother, and family income were positively correlated with sterilization. 相似文献
6.
Ulrich Lange Michael Bröcker Klaus Mezger Jerzy Don 《International Journal of Earth Sciences》2002,91(6):1005-1016
Amphibolite-facies orthogneisses of the Orlica-vnienik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. 87Rb-86Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnienik dome. 相似文献
7.
8.
Quaternary minettes and associated volcanic rocks of Mascota,western Mexico: a consequence of plate extension above a subduction modified mantle wedge 总被引:12,自引:0,他引:12
I. S. E. Carmichael R. A. Lange James F. Luhr 《Contributions to Mineralogy and Petrology》1996,124(3-4):302-333
Pleistocene-Holocene volcanism in the Jalisco block of western Mexico is confined to two conspicuous grabens, where potassic
eruptives range from absarokites (48–52% SiO2) and minettes (49–54% SiO2) through basaltic andesites (53–57% SiO2), the most voluminous type, to andesites and their lamprophyric equivalent spessartite (58–62% SiO2); there are no contemporary rhyolitic rocks. This suite has high concentrations of Mg, Cr (<550 ppm) and Ni (<450 ppm) accompanied
by large concentrations of K, P, Ba (<4000 ppm) and Sr (<5000 ppm) and elements such as LREE and Zr (<600 ppm). No combination
of crystal fractionation and/or crustal contamination can reproduce the compositional range of these magmas, which nevertheless
are believed to be genetically related because of their proximity in time and space. Hydrous minerals in the lamprophyres
and the typical absence of plagioclase phenocrysts in both basaltic andesites and andesites reflect the relatively high concentrations
of water in the magmas, which suppressed the crystallisation of feldspar. Experimental verification of the minimal amounts
of water required to reproduce the phenocryst assemblages in selected rocks range from 3.5 to 6%. During ascent in a volcanic
conduit, andesitic magma may lose water and consequently precipitate plagioclase, or it may ascend more rapidly, retaining
more of its initial water, which stabilises phenocrysts of hornblende at the expense of plagioclase. Our estimates of water
concentrations, which are consistent with the various low pressure phenocryst assemblages, will be minimal for the magmas
in their source regions, and the process of magmatic dewatering on ascent may be typical in well established volcanic conduits.
In accord with the compositions of phenocrystic olivine in the basaltic andesites and the minettes, the values of FeO and
Fe2O3 of the bulk lavas and scoriae are demonstrably pristine. As a consequence, there are two characteristic features of the Mascota
suite: the high range of relative oxygen fugacities (ΔNNO=1–5) and the high Mg# (MgO/MgO+FeO) that ranges from 0.70 to 0.91
(with only one andesite as low as 0.66). From the evidence of phlogopite phenocrysts, a partial melt involving phlogopite
would have a higher Mg# than one from olivine (Fo90) and pyroxene alone. As the Mascota series shows a correlation between K2O and Mg#, we conclude that it was generated by partial fusion of the mantle wedge, with a variable contribution of phlogopite
and apatite from veins throughout the lherzolitic assemblage. In conformity with an origin by varying increments of partial
fusion of a phlogopite-bearing mantle, all incompatible elements vary linearly with Ti (or K) as if phlogopite (+apatite)
in the source dominated their contribution to the partial melts. Fluids from dehydration of the subducting slab presumably
deposit hydrous and other minerals in veins in the mantle wedge and also increase its redox state. As the Mascota volcanism
occurs in grabens closer to the trench than the main andesite arc, it is concluded that the eruption of these small volumes
of hydrous magmas require the tectonically favored ascent paths offered by the extensional grabens to reach the surface from
their mantle sources.
Received: 24 January 1995 / Accepted: 21 February 1996 相似文献
9.
Understanding the formation of laminated, organic-rich sediments is an essential topic for researchers interested in fossil fuels, biogeochemical cycles, Earth's environmental history and global change. Biologists have very recently demonstrated that some marine phytoplankton blooms actively govern their own sedimentation by the formation of sticky transparent gels that facilitate rapid aggregation, accelerated sinking and efficient export flux. Here we present fossil evidence of unfragmented, low-diversity phytoplankton assemblages preserved as sedimentary laminae and irregular flocs that are attributable to a similar phytoplankton-driven sedimentary mechanism we term ‘self-sedimentation’. The geological evidence suggests that self-sedimentation precludes significant heterotrophic grazing, propels the formation of some conspicuous hemipelagic sedimentary laminae and results in efficient carbon and opal flux to the sediments. We suggest that the self-sedimentation phenomenon may have broad implications for the geological history of biogeochemical cycling, oceanic ecological dynamics, and abrupt atmospheric/environmental change. Broader recognition of the self-sedimentation phenomenon as explicitly defined here is a prerequisite to testing these unconventional hypotheses. 相似文献
10.