辉钼矿Re-Os同位素定年方法的改进与应用

公认的Re-Os同位素定年代表物辉钼矿,目前已在金属硫化物矿床年代学研究领域获得了广泛的应用。本研究采用浓HNO₃分解辉钼矿样品,大大地简化了Re和Os的化学制备过程,并根据辉钼矿中正常Os含量水平相对放射成因¹⁸⁷Os可以忽略的特点,以正常Os标准为稀释剂,实现了仪器测量过程中Os同位素质量分馏的在线校正,改善了分析数据的质量。该方法经辉钼矿国家标准物质进行验证,获得了满意的Re、Os含量及Re-Os年龄数据,并且在南岭地区与连阳复式岩体相关的姓坪夕卡岩型钼矿床成矿年龄研究中获得了成功应用。在实际应用中,为了获得有意义的能反映真实地质事件的年龄数据,辉钼矿样品不仅要有足够的取样量,而且还要保证粒度细、混合均匀。     

河北承德黑山铁矿床热液成矿特征及流体包裹体研究

黑山大型钒钛磁铁矿矿床产于大庙斜长岩杂岩体中,是承德地区最重要的"大庙式"岩浆型铁矿床。笔者在矿区野外地质观察过程中发现,穿插于斜长岩中的铁磷矿脉、磁铁矿硫化物矿脉有热液成矿作用的显示,表明黑山铁矿床成因除传统认为的岩浆期结晶、熔离、矿浆贯入成矿作用外,还有热液期的成矿作用发生。本文对热液成矿期铁磷矿石中磷灰石和矿化蚀变石英中的流体包裹体进行了显微测温和激光拉曼光谱分析。结果表明,磷灰石中原生包裹体可以分为气液两相包裹体、含子矿物包裹体、含液态CO2三相包裹体、单液相、单气相包裹体5类,均一温度主要集中于180～420℃,盐度主要集中于6.2%～38.9%NaCleq,流体包裹体气相成分主要为CO2、N2和CH4,液相成分主要为H2O,固相成分主要为方解石、石盐、白云石及铁氧化物子矿物。石英中流体包裹体类型和成分与磷灰石中的类似,但固相成分未发现石盐和不透明金属子矿物,均一温度变化于149～422℃,盐度变化于5.7%～22.9%NaCleq。成矿流体为CaCl2-NaCl-H2O-CO2体系,均一温度和盐度呈现正相关连续渐变的特征。铁磷矿石的磷灰石中原生包裹体为流体包裹体,盐度高,子矿物种类复杂,组成中富含CO2和CH4等,这些特征显示成矿流体以岩浆热液为主;成矿机理可能与大气降水对岩浆热液的稀释有关。     

Acoustic emissions associated with the formation of fracture sets in sandstone under polyaxial stress conditions‡

A polyaxial (true‐triaxial) stress‐loading system, developed originally for determining all nine components of P‐ and S‐wave velocities and attenuation and fluid permeability for 50.8 mm‐side cubic rock specimens tested to failure, has been modified to permit the measurement of acoustic emission events associated with the failure process. Results are reported for Crosland Hill sandstone tested to failure under loading conditions leading to the formation of sets of aligned microcracks, achieved by maintaining the minor principal stress at a low value while increasing the two other principal stresses until failure of the rock. An ultrasonic survey associated with the test has been employed to map the transversely‐isotropic velocity structure created by through‐going parallel fractures resulting from the sets of aligned microcracks. This velocity structure has then been employed to locate acoustic emission events recorded during the test by four acoustic emission sensors located in each of the six specimen loading platens. A selection of acoustic emission events associated with one of the fractures has been processed for moment tensor analysis information, in order to determine the source type and orientation of microcracking as the fracture grows. The mechanisms indicate tensile behaviour during initial fracture propagation. Shear failure, however, appears to dominate as the fracture finally approaches the opposite face of the cubic specimen. The work presented here has, in part, led to the development of new rock testing systems and geophysical monitoring and processing technologies that will enable laboratory study of rock behaviour under conditions better resembling those experienced in situ.     

High-resolution Mechanics of a Microearthquake Sequence

—?Unique data from microseismic (MS) and acoustic emission (AE) systems monitoring a common rock volume have been analyzed from the Underground Research Laboratory in Canada. The two 16 sensor systems were installed to investigate stress-induced microcracking around clay and concrete bulkheads as part of the Tunnel Sealing Experiment. Single and double MS events are found to be spatially associated with clusters of between 19–86 higher frequency AE events. Each AE cluster is elongated with the longest axis between 15 and 50?cm. The AE events occurring before the associated MS event are termed foreshocks, and for two of the three analyzed AE clusters an acceleration in the AE frequency and cumulative magnitude occurs upto the time of the MS event, however with one AE cluster very few foreshocks are recorded, possibly indicating a more homogeneous failure plane. Time independent moment tensors were determined with the MS events showing significant deviatoric sources. The majority of the AE events have deviatoric mechanisms with a few crack opening and crack closure type events also determined. This study highlights the benefits of using small-scale seismic systems to investigate the temporal fracture mechanics of microcrack formation, and allows comparisons with larger more damaging seismicity.     

Simulation of Unstable Fault Slip in Granite Using a Bonded-particle Model

—?A bonded-particle model is used to simulate shear-type microseismic events induced by tunnel excavation in granite. The model represents a volume of granite by an assembly of 50,000 individual particles bonded together at points of contact. A plane of weakness is included in the model and this plane is subjected to increasing shear load while the normal load across the plane is held constant. As shear stress in the model increases, bonds begin to break and small acoustic emissions (AE) result. After enough bonds have broken, macro-slip occurs across the large portions of the fault in an unstable manner. Since the model is run dynamically, seismic source information can be calculated for the simulated AE and macro-slip events. This information is compared with actual results obtained from seismic monitoring around an underground excavation. Although the modelled events exhibit larger magnitudes than the actual recorded events, there are many similarities between the model and the actual results, namely the presence of foreshocks before the macro-slip events and the patterns of energy release during loading. In particular, the model provides the ability to examine the complexity of the slip events in detail.     

The Assessment of Damage Around Critical Engineering Structures Using Induced Seismicity and Ultrasonic Techniques

—?Two large-diameter boreholes have been excavated vertically from the floor of a tunnel at the Äspö Hard Rock Laboratory, Sweden. The two deposition holes will have simulated high-level radioactive waste canisters installed in them in an experiment undertaken to test the retrievability of waste from a proposed repository. Induced seismicity and other acoustic monitoring techniques have been used to investigate the Excavation Damaged Zone (EDZ) around the two holes. High-frequency acoustic emission (AE) monitoring has been used to delineate regions of stress-induced microfracturing on the millimetre scale. This has been shown to locate in clusters around the perimeter of the deposition hole at azimuths orthogonal to the far-field maximum principal stress. Three-dimensional velocity surveys have been conducted along ray paths that pass through the damaged region and through a stress-disturbed zone around the excavation. Induced microfracturing and stress disturbance have been observed as sharp decreases in velocity as the excavation proceeds through the rock mass. The combination of the high-resolution velocity measurements and the AE source locations has allowed the linking of the velocity measurements to a volume of excavation damaged rock. This has provided a quantitative estimate of the effect of the EDZ on the rock mass.