The Humphrey Head Borehole: Evidence for Carboniferous vulcanicity and Permian dolomitization in the southern Lake District

In south Cumbria, Permo-Triassic breccias and conglomerates (‘brockram’) are exposed only at Rougholme Point on the Cartmel peninsula. In 1973 the Institute of Geological Sciences Humphrey Head borehole penetrated 257 m of brockram before entering probable Upper Carboniferous sediments. The brockram consists of pebbles of carbonate, chert and basalt in a matrix of haematite-stained quartz sand. Carbonate and chert fragments were derived from the upper part of the Carboniferous Limestone sequence exposed today nearby. Basalt clasts were derived from lavas, which appear to have cooled in a subaqueous environment, at least in part. They were locally derived and are the only certain evidence for Carboniferous volcanic activity in south Cumbria. As volcanic fragments increase in abundance towards the base of the borehole they must have been derived from the top of the succession being eroded and are probably of Brigantian age. Carbonate fragments were dolomitized soon after incorporation in the brockram, probably by saline fluids derived from the evaporative Zechstein Sea. The dolomitization was incomplete, leaving remnant limestone cores to clasts which were subsequently dissolved. The resultant vugs were infilled by dolomite, calcite and gypsum cements, which have been partially weathered from outcropping brockram, leaving hollow pebbles.     

The 1972 Eruption of Kartala volcano,grande comore

A summit eruption of Kartala commenced on September 8th, 1972 and finished on October 5th, 1972. In the course of this eruption, approximately 5×10⁶ m³ of alkali olivine basalt was erupted from a N-S fissure system within and adjacent to the caldera. Aa flows were partly ponded within the caldera, almost filling the 1918 Choungou Chagnoumeni crater pit, and partly spilled NW down the flanks of the volcano. The lavas are of uniform composition, almost identical to those erupted in 1965 and closely resembling the majority of flows erupted during the last 115 years. One-atmosphere melting experiments support petrographic and chemical evidence that the lavas are coctetic, with coprecipitation of olivine, augite and plagioclase. The lavas were crupted at, or close to, their liquidus temperature, determined at approximately 1170°C. Whereas eruptions of Kartala in the nineteenth century were distributed widely along a fissure system approximately 45 km long by 7 km wide, the eruptions since 1918 have been confined to the vicinity of the summit caldera.     

Long-term changes in salt marsh extent affected by channel deepening in a modified estuary

The aim of this study is to quantify the long-term (54 years) rates of marsh extension and retreat at two sites in the Westerschelde Estuary, SW Netherlands. Nine sets of aerial photographs were obtained for each of the two salt marsh sites, Zuidgors and Waarde, taken at various times between 1944 and 1998. The seaward edges of the marshes were digitised from rectified images after the photographs had been scanned and georegistered to the Dutch National Grid. Comparison of the extents of the marshes at these nine time points revealed that the areas of both marshes had fluctuated during these 54 years with periods of both extension and retreat of the seaward marsh edges. These periods of extension and retreat appeared to be approximately synchronised until the 1990s, with mean changes in position of marsh front ranging from −7.92 to 6.04 m a⁻¹.The rate of landward retreat and seaward extension of the marsh front is shown to be related to an increase in the tidal prism brought about by dredging operations to maintain or increase the depth of the main navigable channel of the estuary. The consequent greater frequency with which the high tides reach the edge of the fringing marshes increases the risk of erosion. Strong westerly winds may also be a factor in increasing erosion. No relationship between the volume of shipping traffic using the estuary and marsh erosion was found.     

Compositional variability of ice‐rafted debris in Heinrich layers 1 and 2 on the northwest European continental slope identified by environmental magnetic analyses

The composition of ice‐rafted debris (IRD) within a sediment core from the European continental slope (core OMEX‐2K; 49° 5′ N, 13° 26′ W) has been examined using environmental magnetic analyses. The data demonstrate compositional variability of the IRD within Heinrich layers 2 (H2) and 1 (H1) and these differences are most readily explained by changes in the contribution of different IRD sources to the core site. Some IRD within the main Heinrich layers show magnetic signatures that are similar to IRD derived from the Laurentide ice sheet found in cores from within the main North Atlantic IRD‐belt. In contrast, other IRD‐rich layers, both prior to and within the main Heinrich layers, demonstrate different magnetic behaviour, suggesting a contribution from a non‐Laurentide sourced IRD, most likely derived from ice streams discharging from northeast Atlantic ice sheets such as the British and Fennoscandian ice sheets. These data are consistent with published compositional data from the same core and, given the rapid, highly sensitive and non‐destructive nature of the method, suggest that environmental magnetic analysis has considerable potential for characterising IRD materials within Heinrich layers for the purposes of defining provenance. Copyright © 2006 John Wiley & Sons, Ltd.     

Cristobalite in the 2011–2012 Cordón Caulle eruption (Chile)

Cristobalite is a low-pressure high-temperature polymorph of SiO₂ found in many volcanic rocks. Its volcanogenic formation has received attention because (1) pure particulate cristobalite can be toxic when inhaled, and its dispersal in volcanic ash is therefore a potential hazard; and (2) its nominal stability field is at temperatures higher than those of magmatic systems, making it an interesting example of metastable crystallization. We present analyses (by XRD, SEM, EPMA, Laser Raman, and synchrotron μ-cT) of representative rhyolitic pyroclasts and of samples from different facies of the compound lava flow from the 2011–2012 eruption of Cordón Caulle (Chile). Cristobalite was not detected in pyroclasts, negating any concern for respiratory hazards, but it makes up 0–23 wt% of lava samples, occurring as prismatic vapour-deposited crystals in vesicles and/or as a groundmass phase in microcrystalline samples. Textures of lava collected near the vent, which best represent those generated in the conduit, indicate that pore isolation promotes vapour deposition of cristobalite. Mass balance shows that the SiO₂ deposited in isolated pore space can have originated from corrosion of the adjacent groundmass. Textures of lava collected down-flow were modified during transport in the insulated interior of the flow, where protracted cooling, additional vesiculation events, and shearing overprint original textures. In the most slowly cooled and intensely sheared samples from the core of the flow, nearly all original pore space is lost, and vapour-deposited cristobalite crystals are crushed and incorporated into the groundmass as the vesicles in which they formed collapse by strain and compaction of the surrounding matrix. Holocrystalline lava from the core of the flow achieves high mass concentrations of cristobalite as slow cooling allows extensive microlite crystallization and devitrification to form groundmass cristobalite. Vapour deposition and devitrification act concurrently but semi-independently. Both are promoted by slow cooling, and it is ultimately devitrification that most strongly contributes to total cristobalite content in a given flow facies. Our findings provide a new field context in which to address questions that have arisen from the study of cristobalite in dome eruptions, with insight afforded by the fundamentally different emplacement geometries of flows and domes.     

再论花岗岩按照Sr-Yb的分类:标志

2006年作者曾经按照Sr=400×10~(-6)和Yb=2×10~(-6)作为标志将花岗岩分为埃达克岩、喜马拉雅型花岗岩、浙闽型花岗岩和广西型花岗岩,在浙闽型中又分出南岭型(Sr100×10~(-6)和Yb2×10~(-6)),于是花岗岩被分为5类。Sr=400×10~(-6)和Yb=2×10~(-6)是根据阿留申群岛中的Adak岛的资料得出来的。本文统计了全球花岗岩6000多个数据(其中,埃达克型花岗岩为2810个,喜马拉雅型花岗岩636个,浙闽型花岗岩1183个,南岭型花岗岩1518个,广西型花岗岩142个,总共6289个),统计的结果,各类花岗岩的地球化学特征大致如下:(1)埃达克型花岗岩富Al_2O_3和Sr,贫Y和Yb,具较高和变化的铕异常,绝大多数样品的Sr300×10~(-6),Yb2.5×10~(-6)(当Sr=400×10~(-6)～600×10~(-6)时Yb值最大,Sr超过600×10~(-6),Yb降低至2×10~(-6)),Al_2O_3在14%～18%之间,Eu/Eu~*大多在0.6～1.2范围;(2)喜马拉雅型花岗岩贫Sr和Yb,具中等的Al_2O_3和变化的Eu/Eu~*,Sr300×10~(-6)和Yb2×10~(-6)(少数Sr300×10~(-6)),Al_2O_3为13%～17%,Eu/Eu~*为0.2～1.0;(3)浙闽型花岗岩贫Sr富Yb,Sr在40×10~(-6)～400×10~(-6)之间,Yb1.5×10~(-6),Al_2O_3和Eu/Eu~*的变化类似喜马拉雅型花岗岩,Al_2O_3为12%～17%,Eu/Eu~*为0.4～1.0;(4)南岭型花岗岩以很低的Sr、Al_2O_3和Eu/Eu~*以及很高的Yb而不同于上述各类花岗岩,通常Yb1.5×10~(-6),Sr100×10~(-6)(Yb变化大,绝大多数2×10~(-6);当Yb在2×10~(-6)～8×10~(-6)时,部分样品Sr可100×10~(-6),但很少200×10~(-6));Al_2O_314%,集中在11%～13%之间,Eu/Eu~*0.7,大多0.4;Yb越大,Sr越低,负铕异常越明显。文中讨论了花岗岩Sr-Yb分类的意义,指出本分类适用于产于大陆和海洋的绝大多数中酸性岩浆岩(可能不适用于一部分特别富铁和钾的花岗岩,如具有高Sr和Yb特征的广西型花岗岩)。不同类型的花岗岩主要反映了源区压力的不同,而源区成分、温度、部分熔融程度、水和挥发分的加入以及岩浆混合等的影响可能是次要的。文中指出,该分类的依据、其实质,是熔体与残留相平衡的理论。与浙闽型花岗岩平衡的残留相是斜长石,与喜马拉雅型花岗岩平衡的是斜长石+石榴石,与埃达克型花岗岩平衡的是石榴石,与南岭型花岗岩平衡的是富钙的斜长石。文中指出,加强实验岩石学研究,将年代学和地球化学研究密切结合起来是深化花岗岩研究的关键。