Seal integrity and feasibility of CO<Subscript>2</Subscript> sequestration in the Teapot Dome EOR pilot: geomechanical site characterization

This paper reports a preliminary investigation of CO₂ sequestration and seal integrity at Teapot Dome oil field, Wyoming, USA, with the objective of predicting the potential risk of CO₂ leakage along reservoir-bounding faults. CO₂ injection into reservoirs creates anomalously high pore pressure at the top of the reservoir that could potentially hydraulically fracture the caprock or trigger slip on reservoir-bounding faults. The Tensleep Formation, a Pennsylvanian age eolian sandstone is evaluated as the target horizon for a pilot CO₂ EOR-carbon storage experiment, in a three-way closure trap against a bounding fault, termed the S1 fault. A preliminary geomechanical model of the Tensleep Formation has been developed to evaluate the potential for CO₂ injection inducing slip on the S1 fault and thus threatening seal integrity. Uncertainties in the stress tensor and fault geometry have been incorporated into the analysis using Monte Carlo simulation. The authors find that even the most pessimistic risk scenario would require ∼10 MPa of excess pressure to cause the S1 fault to reactivate and provide a potential leakage pathway. This would correspond to a CO₂ column height of ∼1,500 m, whereas the structural closure of the Tensleep Formation in the pilot injection area does not exceed 100 m. It is therefore apparent that CO₂ injection is not likely to compromise the S1 fault stability. Better constraint of the least principal stress is needed to establish a more reliable estimate of the maximum reservoir pressure required to hydrofracture the caprock.     

Tidally incised valleys on tropical carbonate shelves: An example from the northern Great Barrier Reef, Australia

The formation of incised valleys on continental shelves is generally attributed to fluvial erosion under low sea level conditions. However, there are exceptions. A multibeam sonar survey at the northern end of Australia's Great Barrier Reef, adjacent to the southern edge of the Gulf of Papua, mapped a shelf valley system up to 220 m deep that extends for more than 90 km across the continental shelf. This is the deepest shelf valley yet found in the Great Barrier Reef and is well below the maximum depth of fluvial incision that could have occurred under a − 120 m, eustatic sea level low-stand, as what occurred on this margin during the last ice age. These valleys appear to have formed by a combination of reef growth and tidal current scour, probably in relation to a sea level at around 30–50 m below its present position.

Tidally incised depressions in the valley floor exhibit closed bathymetric contours at both ends. Valley floor sediments are mainly calcareous muddy, gravelly sand on the middle shelf, giving way to well-sorted, gravely sand containing a large relict fraction on the outer shelf. The valley extends between broad platform reefs and framework coral growth, which accumulated through the late Quaternary, coincides with tidal current scour to produce steep-sided (locally vertical) valley walls. The deepest segments of the valley were probably the sites of lakes during the last ice age, when Torres Strait formed an emergent land-bridge between Australia and Papua New Guinea. Numerical modeling predicts that the strongest tidal currents occur over the deepest, outer-shelf segment of the valley when sea level is about 40–50 m below its present position. These results are consistent with a Pleistocene age and relict origin of the valley.

Based on these observations, we propose a new conceptual model for the formation of tidally incised shelf valleys. Tidal erosion on meso- to macro-tidal, rimmed carbonate shelves is enhanced during sea level rise and fall when a tidal, hydraulic pressure gradient is established between the shelf-lagoon and the adjacent ocean basin. Tidal flows attain a maximum, and channel incision is greatest, when a large hydraulic pressure gradient coincides with small channel cross sections. Our tidal-incision model may explain the observation of other workers, that sediment is exported from the Great Barrier Reef shelf to the adjacent ocean basins during intermediate (rather than last glacial maximum) low-stand, sea level positions. The model may apply to other rimmed shelves, both modern and ancient.     

Definition and measurement of salinity in salt lakes

Salinity is the most important chemical attribute of athalassic salt lakes. Even so, some confusion persists of what salinity means and how to measure it. For sal lakes, salinity is best defined as the sum total of all ion concentrations, or total ion concentration. Ideally, it is recommended that salinities be expressed on a mass per mass basis and as ppt (parts per thousand). Direct measurements of salinity can only be derived from full ionic analyses. Indirect measurements can be derived by determinations of density, conductivity, freezing point depression and total dissolved solids or matter.     

Variations in water clarity and chlorophylla in Tampa Bay, Florida, in response to annual rainfall, 1985–2004

In the Tampa Bay region of Florida, extreme levels of annual and seasonal rainfall are often associated with tropical cyclones and strong El Niño episodes. We used stepwise multiple regression models to describe associations between annual and seasonal rainfall levels and annual, bay-segment mean water clarity (as Secchi depth [m]), chlorophylla (μg I^?1), color (pcu), and turbidity (ntu) over a 20-yr period (1985–2004) during which estimated nutrient loadings have been dominated by non-point sources. For most bay segments, variations in annual mean water clarity were associated with variations in chlorophylla concentrations, which were associated in turn with annual or seasonal rainfall. In two bay segments these associations with annual rainfall were superimposed on significant long-term declining trends in chlorophylla. Color was significantly associated with annual rainfall in all bay segments, and in one segment variations in color were the best predictors of variations in water clarity. Turbidity showed a declining trend over time in all bay segments and no association with annual rainfall, and was significantly associated with variations in water clarity in only one bay segment. While chlorophylla, color, and turbidity a affected water clarity to varying degrees, the effects of extreme rainfall events (El Niño events in 1998 and 2003, and multiple tropical cyclone events in 2004) on water clarity were relatively short-lived, persisting for periods of months rather than years. During the 20-yr period addressed in these analyses, declining temporal trends in chlorophylla and turbidity, produced in part by a long-term watershed management program that has focused on curtailing annual loadings of nitrogen and other pollutants, may have helped to prevent the bay as a whole from responding more adversely to the high rainfall periods that occurred in 1998 and 2003–2004.     

Large-scale mass wasting in ancient volcanic materials

Giant landslides are significant hazards associated with many active volcanic edifices. We describe a similar feature on ancient (>4 Ma) volcanic deposits subject to active tectonism. The landslide is approximately 3 km long by 1 km wide, with an estimated depth of 400 m. Side margins are straight and parallel, mimicking regional structure; narrow valleys incised down these margins provide low-strength side-release surfaces. Between these is a giant slump consisting of at least four, largely intact, discrete blocks that have moved down-dip a distance of >500 m. A series of flows with areal extents ranging from 0.01 to 0.5 km² extends from the front of the failure. The materials represent an eroded sequence of andesite flows on the flanks of a stratovolcano. These have undergone two phases of hydrothermal alteration, and are deeply weathered to low-density (1040±80 kg m⁻³) silt (59%) and clay (35%) materials with strength properties typical of weathered silts (c=26±3 kN m⁻²; φ=42±8°). The size and location of this landslide preclude detailed geotechnical investigation of the failure. The worth of numerical stability analysis as an alternative technique in assessing the nature of the failure and hence the risk it poses to nearby communities is investigated. Sensitivity analysis identified likely conditions under which initial failure may have occurred: analyses for sensitivity to strength and earthquake acceleration needed conversion to critical combinations (F=1.0) of water table and strength/acceleration to remove the overriding influence of water table fluctuations. Failure was likely initiated either by a high water table level (83-84%), or some combination of intensity VII-IX earthquake waves together with water table heights of 40-80%. A general hazard assessment indicates that the risk associated with creep and catastrophic failure of the main mass is small, whereas the risk from flow failures near the toe of the landslide may be high. Important parameters (hydrological regime, flow failure morphology, age of initiation, and rates of movement) requiring closer investigation are identified. Development of a model is crucial to assessing the hazard associated with a feature such as that described here. With limited resources, a detailed stability analysis is a powerful tool as an initial stage in hazard analysis.     

Palaeomagnetic study of Archaean Banded Hematite Jasper Rocks from the Singhbhum-Orissa Craton, India

The Banded Hematite Jasper Formation within the Iron Ore Supergroup of the Singhbhum Craton in eastern India comprises fine alternating layers of jasper and specularite. It was deposited at 3000 Ma and deformed by a mobile episode at 2700 Ma. Hematite pigment (<1 μm) mixed with cryptocrystalline silica and specularite (> 10 μm) is chiefly responsible for red to brown rhythmic bands in the hematite jasper facies although thermomagnetic study also shows that minor amounts (1–2%) of magnetite are present. Palaeomagnetic study identifies a dual polarity remanence resident in hematite (D/I = 283/60°, α₉₅ = 12°) which predates deformation. Studies of the fabric of magnetic susceptibility and rock magnetic results suggest a diagenetic origin for this magnetisation with the hematite formed from oxidation of primary magnetite. The palaeopole (32°E, 24°N, dp/dm = 14/18°) records the earliest post-metamorphic magnetisation event in the Orissa Craton. A minimum apparent polar wander motion of the Orissa-Singhbhum craton of through 80° is identified during Late Archaean times (2900-2600 Ma).     

Geological controls on rock mass classification of coal from Huntly East Mine, New Zealand

Rock Mass Rating (RMR) measurements from 65 sites within Huntly East underground coal mine are presented. All measurements are in coal, for which the dominant discontinuities are vertical cleat. Basic RMR values using two discontinuity spacings are presented: overall RMR based on the average spacing of all individual discontinuities; and cleat zone RMR based on the average spacing between zones of cleat. Cleat orientations are highly variable, but on average approximately parallel horizontal stress axes (face cleat follows maximum horizontal stress axis, butt cleat follows minimum horizontal stress axis).Contours of RMR variations throughout the mine are used to compare rock mass conditions with geological structure. It is apparent that: (1) RMR is least within downthrown fault blocks, and particularly immediately on the downthrown sides of faults, and greatest in upthrown fault blocks; and (2) RMR contours parallel horizontal stress axes within fault-bounded blocks, and bend to parallel faults at block boundaries. From similar contours for parameters contributing to RMR, the Rock Quality Designation (RQD), groundwater rating, and discontinuity condition rating create most of the observed variations in RMR. RQD is determined from the measured discontinuity frequency and hence is a measure of the degree of fracturing of the rock mass. This is interpreted as influencing the groundwater and condition parameters directly by allowing greater water ingress. Discontinuity frequency is greatest (least spacing) in the immediate vicinity of faults, and in downthrown fault blocks, generating low RMR values. Within fault blocks RQD varies little, so RMR contours align with cleat orientations.As RMR contours, faults, stress field and cleat orientation are clearly interrelated, there is unequivocally a connection between RMR and structural geology; this allows some predictive capacity in terms of ground conditions. If geological features can be accurately defined through either drilling programs or seismic surveys, then ground conditions may be predicted before panels are driven.     

Quantifying microartifacts using a personal computer

Microartifact analysis is a worthwhile endeavor in archaeological research. A recurring problem, however, has been the time invested in sample quantification. In this paper we offer an interactive way to quantify microartifact samples using a computer program called MMCOUNT. When the technique is applied during the point counting process, the time required to acquire reliable proportions of material classes can be reduced to approximately 25 minutes per sample, significantly less than usual counting times reported in other studies.     

Assessment of episodic acidification in Sierra Nevada,California

Monte-Carlo simulations were used to assess the extent of shortterm alkalinity depressions occuring in Sierra Nevada lakes due to acidic deposition events. The Episodic Event Model (EEM) was used to simulate spring snowmelt events. Snow course data, precipitation data and lake acidification surveys were used to derive values for the EEM parameters. Spring snowmelt events were shown to have great impacts on the water quality of Sierran lakes. Lakes are likely to be most affected by the early-spring snowmelt event because the epilimnion depth is at a minimum, which indicates minimum dilution. Under annual average loading conditions, no Sierran lake has been reported as acidic although 29% of the lakes have alkalinities less than 40 µeq/L indicating a sensitivity to acidification. In simulations of early-spring snowmelt events, using present-day acidic loading conditions, it was estimated 79% ± 9% of the lakes would experience shortterm lake alkalinity depressions to levels less than 40 µeq/L. The results provided by the model simulations are valuable in establishing upper and lower limits on the extent of possible episodic acidification to lake-resources-at-risk. The most critical parameters controlling the magnitude of lake alkalinity depressions during snowmelt episodic events are a) the lake area to watershed area ratio — a measure of input loading, and b) the epilimnion volume — a measure of dilution and mixing.