The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.     

Crinoid localities of the Devonian of the British Isles

Who collects the Devonian crinoids of south-west England? Since the nineteenth century, almost nobody. Few palaeontologists pursue these fossils, undoubtedly handsome in life, but indifferently preserved. Herein, we make a survey of four of the most important crinoid sites, all of which have the potential to produce new specimens.     

Meteoric fluid‐rock interaction in Variscan shear zones

Variscan shear zones in the Armorican Massif represent sites of strong fluid‐rock interaction. The hydrogen isotope composition of muscovite (δD_Ms) from syntectonic leucogranite allows to determine the source of fluids that infiltrated the footwall of three detachment zones and the South Armorican Shear Zone. Using temperatures of hydrogen isotope exchange estimated from microstructural data, we calculate the hydrogen isotope ratios of water (δD_water) present within the shear zones during high‐temperature deformation. A ~40‰ difference in δD_water values from deep to shallow crustal level reveals a mixing relationship between deep crustal fluids with higher δD values that range from ?34 to ?33‰, and meteoric fluids with δD values as low as ?74‰ in the upper part of detachment footwalls.     

Analytical study of ground motion caused by seismic wave propagation across faulted rock masses

Studying seismic wave propagation across rock masses and the induced ground motion is an important topic, which receives considerable attention in design and construction of underground cavern/tunnel constructions and mining activities. The current study investigates wave propagation across a rock mass with one fault and the induced ground motion using a recursive approach. The rocks beside the fault are assumed as viscoelastic media with seismic quality factors, Q_p and Q_s. Two kinds of interactions between stress waves and a discontinuity and between stress waves and a free surface are analyzed, respectively. As the result of the wave superposition, the mathematical expressions for induced ground vibration are deduced. The proposed approach is then compared with the existing analysis for special cases. Finally, parametric studies are carried out, which includes the influences of fault stiffness, incident angle, and frequency of incident waves on the peak particle velocities of the ground motions.     

Changes in hillslope hydrology in a perched,shallow soil system due to clearcutting and residual biomass removal

Sustainable fuels legislation and volatility in energy prices have put additional pressures on the forestry sector to intensify the harvesting of biomass for “advanced biofuel” production. To better understand how residual biomass removal after harvest affects forest hydrology in relatively low slope terrain, a Before-After-Control-Impact (BACI) study was conducted in the USDA Forest Service's Marcell Experimental Forest, Minnesota, USA. Hydrological measurements were made from 2010–2013 on a forested hillslope that was divided into three treatment blocks, where one block was harvested and residual biomass removed (Biomass Removed), the second was harvested and residual biomass left (Biomass Left), and the last block was left as an Unharvested Control. The pre-harvest period (2 years) was 2010–11 and post-harvest (2 years) was 2012–13. Water table elevation at the upslope and downslope position, subsurface runoff, and soil moisture were measured between May–November. Mixed effect statistical models were used to compare both the before-after and “control” treatment ratios (ratios between harvested hillslopes and the Unharvested Control hillslope). Subsurface runoff significantly increased (p < .05) at both harvested hillslopes but to a greater degree on the Biomass Left hillslope. Greater subsurface runoff volumes at both harvested hillslopes were driven by substantial increases during fall, with additional significant increases during summer on the Biomass Left hillslope. The hydrological connectivity, inferred from event runoff ratios, increased due to harvesting at both hillslopes but only significantly on the Biomass Left hillslope. The winter harvest minimized soil disturbance, resulting in no change to the effective hydraulic conductivity distribution with depth. Thus, the observed hydrological changes were driven by increased effective precipitation and decreased evapotranspiration, increasing the duration that both harvested hillslopes were hydrologically active. The harvesting of residual biomass appears to lessen hydrological connectivity relative to leaving residual biomass on the hillslope, potentially decreasing downstream hydrological impacts of similar forestry operations.     

The mass ratio of Charon to Pluto from Hubble Space Telescope astrometry with the fine guidance sensors

The mass ratio of Charon to Pluto is a basic parameter describing the binary system and is necessary for determining the individual masses and densities of these two bodies. Previous measurements of the mass ratio have been made, but the solutions differ significantly (Null et al., 1993; Young et al., 1994; Null and Owen, 1996; Foust et al., 1997; Tholen and Buie, 1997). We present the first observations of Pluto and Charon with a well-calibrated astrometric instrument—the fine guidance sensors on the Hubble Space Telescope. We observed the motion of Pluto and Charon about the system barycenter over 4.4 days (69% of an orbital period) and determined the mass ratio to be 0.122±0.008 which implies a density of 1.8 to 2.1 g cm⁻³ for Pluto and 1.6 to 1.8 g cm⁻³ for Charon. The resulting rock-mass fractions for Pluto and Charon are higher than expected for bodies formed in the outer solar nebula, possibly indicating significant postaccretion loss of volatiles.     

Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.