Holocene permafrost history and cryostratigraphy in the High‐Arctic Adventdalen Valley,central Svalbard

This paper presents the history and cryostratigraphy of the upper permafrost in the High‐Arctic Adventdalen Valley, central Svalbard. Nineteen frozen sediment cores, up to 10.7 m long, obtained at five periglacial landforms, were analysed for cryostructures, ice, carbon and solute contents, and grain‐size distribution, and were ¹⁴C‐ and OSL‐dated. Spatial variability in ice and carbon contents is closely related to the sedimentary history and mode of permafrost aggradation. In the valley bottom, saline epigenetic permafrost with pore ice down to depths of 10.7 m depth formed in deltaic sediments since the mid‐Holocene; cryopegs were encountered below 6 m. In the top 1 to 5 m, syngenetic and quasi‐syngenetic permafrost with microlenticular, lenticular, suspended and organic‐matrix cryostructures developed due to loess and alluvial sedimentation since the colder late Holocene, which resulted in the burial of organic material. At the transition between deltaic sediments and loess, massive ice bodies occurred. A pingo developed where the deltaic sediments reached the surface. On hillslopes, suspended cryostructure on solifluction sheets indicates quasi‐syngenetic permafrost aggradation; lobes, in contrast, were ice‐poor. Suspended cryostructure in eluvial deposits reflects epigenetic or quasi‐syngenetic permafrost formation on a weathered bedrock plateau. Landform‐scale spatial variations in ground ice and carbon relate to variations in slope, sedimentation rate, moisture conditions and stratigraphy. Although the study reveals close links between Holocene landscape evolution and permafrost history, our results emphasize a large uncertainty in using terrain surface indicators to infer ground‐ice contents and upscale from core to landform scale in mountainous permafrost landscapes.     

The surface properties of small asteroids: Peculiar Betulia—A case study

We present the results of extensive thermal-infrared observations of the C-type near-Earth Asteroid (1580) Betulia obtained in June 2002 with the 3-m NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii. Betulia is a highly unusual object for which earlier radiometric observations, interpreted on the basis of simple thermal models, indicated a surface of high thermal inertia. A high thermal inertia implies a lack of thermally insulating regolith. Radiometric observations of other asteroids of comparable size indicate that regolith is present in nearly all cases. Knowledge of the surface thermal properties of small near-Earth asteroids is crucial for meaningful calculations of the Yarkovsky effect, which is invoked to explain the delivery of collisional fragments from the main belt into near-Earth orbits, and apparently has a significant influence on the orbital evolution of potentially hazardous near-Earth asteroids. Furthermore, apart from being an indicator of the presence of thermally insulating regolith on the surface of an asteroid, the thermal inertia determines the magnitude of the diurnal temperature variation and is therefore of great importance in the design of instrumentation for lander missions to small asteroids. In the case of Betulia our database is sufficiently broad to allow the use of more sophisticated thermal models than were available for earlier radiometric observations. The measured fluxes have been fitted with thermal-model emission continua to determine the asteroid's size and geometric albedo, pv. Fits obtained with a new thermophysical model imply an effective diameter of 4.57±0.46 km and an albedo of 0.077±0.015 and indicate a moderate surface thermal inertia of around 180 J m⁻² s^−0.5 K⁻¹. It is difficult to reconcile our results with earlier work, which indicate a larger diameter for Betulia and a high-thermal-inertia surface of bare rock.     

A high resolution relative paleointensity record from the Gerlache-Boyd paleo-ice stream region, northern Antarctic Peninsula

Herein we document and interpret an absolute chronological dating attempt using geomagnetic paleointensity data from a post-glacial sediment drape on the western Antarctic Peninsula continental shelf. Our results demonstrate that absolute dating can be established in Holocene Antarctic shelf sediments that lack suitable material for radiocarbon dating. Two jumbo piston cores of 10-m length were collected in the Western Bransfield Basin. The cores preserve a strong, stable remanent magnetization and meet the magnetic mineral assemblage criteria recommended for reliable paleointensity analyses. The relative paleomagnetic intensity records were tuned to published absolute and relative paleomagnetic stacks, which yielded a record of the last ∼8500 years for the post-glacial drape. Four tephra layers associated with documented eruptions of nearby Deception Island have been dated at 3.31, 3.73, 4.44, and 6.86 ± 0.07 ka using the geomagnetic paleointensity method. This study establishes the dual role of geomagnetic paleointensity and tephrochronology in marine sediments across both sides of the northern Antarctic Peninsula.     

Sources of Sediment in Lake Pepin on the Upper Mississippi River in Response to Holocene Climatic Changes

Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 ¹⁴C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation, snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America.     

Formation of Paleoproterozoic eclogitic mantle, Slave Province (Canada): Insights from in-situ Hf and U–Pb isotopic analyses of mantle zircons

In-situ Hf isotope analyses and U–Pb dates were obtained by laser ablation-MC-ICP-MS for a zircon-bearing mantle eclogite xenolith from the diamondiferous Jericho kimberlite located within the Archean Slave Province (Nunavut), Canada. The U–Pb zircon results yield a wide range of ages (2.0 to 0.8 Ga) indicating a complex geological history. Of importance, one zircon yields a U–Pb upper intercept date of 1989 ± 67 Ma, providing a new minimum age constraint for zircon crystallization and eclogite formation. In contrast, Hf isotope systematics for the same zircons display an intriguing uniformity, and corresponding Hf depleted mantle model ages range between 2.1 ± 0.1 and 2.3 ± 0.1 Ga; the youngest Hf model age is within error to the oldest U–Pb date.

The Jericho eclogites have previously been interpreted as representing remnants of metamorphosed oceanic crust, and their formation related to Paleoproterozoic subduction regimes along the western margin of the Archean Slave craton during the Wopmay orogeny. Hf isotope compositions and U–Pb results for the Jericho zircons reported here are in good agreement with a Paleoproterozoic subduction model, suggesting that generation of oceanic crust and eclogite formation occurred between 2.0 and 2.1 Ga. The slightly older Hf depleted mantle model ages (2.1 to 2.3 Ga) may be reconciled with this model by invoking mixing between ‘crustal’-derived Hf from sediments and more radiogenic Hf associated with the oceanic crust during the 2 Ga subduction event. This results in intermediate Hf isotope compositions for the Jericho zircons that yield ‘fictitiously’ older Hf model ages.     

Recent trends in vegetation dynamics in the African Sahel and their relationship to climate

Contrary to assertions of widespread irreversible desertification in the African Sahel, a recent increase in seasonal greenness over large areas of the Sahel has been observed, which has been interpreted as a recovery from the great Sahelian droughts. This research investigates temporal and spatial patterns of vegetation greenness and rainfall variability in the African Sahel and their interrelationships based on analyses of Normalized Difference Vegetation Index (NDVI) time series for the period 1982–2003 and gridded satellite rainfall estimates. While rainfall emerges as the dominant causative factor for the increase in vegetation greenness, there is evidence of another causative factor, hypothetically a human-induced change superimposed on the climate trend.     

The origin of Vesta’s crust: Insights from spectroscopy of the Vestoids

High quality VNIR spectra of 15 Vestoids, small asteroids that are believed to originate from Vesta, were collected and compared to laboratory spectra and compositional data for selected HED meteorites. A combination of spectral parameters such as band centers, and factors derived from Modified Gaussian Model fits (band centers, band strengths, calculation of the low to high-Ca pyroxene ratio) were used to establish if each Vestoid appeared most like eucrite or diogenite material, or a mixture of the two (howardite). This resulted in the identification of the first asteroid with a ferroan diogenite composition, 2511 Patterson. This asteroid can be used to constrain the size of diogenite magma chambers within the crust of Vesta. The Vestoids indicate that both large-scale homogeneous units (>5 km) and smaller-scale heterogeneity (<1 km) exist on the surface of Vesta, as both monomineralogic (eucrite or diogenite material alone) and mixed (both eucrite and diogenite) spectra are observed. The small-scale of the variation observed within the Vestoid population is predicted by the partial melting model, which has multiple intrusions penetrating into the crust of Vesta. It is much more difficult to reconcile the observations here with the magma ocean model, which would predict much more homogeneous layers on a large-scale both at the surface and with depth.     

Oxidation of CO on surface hematite in high CO2 atmospheres

We propose a mechanism for the oxidation of gaseous CO into CO₂ occurring on the surface mineral hematite (Fe₂O₃(s)) in hot, CO₂-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of tropospheric CO₂ on Venus and could at least partly address the CO₂ stability problem in Venus’ stratosphere, since our results suggest that atmospheric CO₂ is produced from CO oxidation via surface hematite at a rate of 0.4 petagrammes (Pg) CO₂ per (Earth) year on Venus which is about 45% of the mass loss of CO₂ via photolysis in the Venusian stratosphere. We also investigated CO oxidation via the hematite mechanism for a range of planetary scenarios and found that modern Earth and Mars are probably too cold for the mechanism to be important because the rate-limiting step, involving CO(g) reacting onto the hematite surface, proceeds much slower at lower temperatures. The mechanism may feature on extrasolar planets such as Gliese 581c or CoRoT-7b assuming they can maintain solid surface hematite which, e.g. starts to melt above about 1200 K. The mechanism may also be important for hot Hadean-type environments and for the emerging class of hot Super-Earths with planetary surface temperatures between about 600 and 900 K.