The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.     

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.     

Fully coupled elastoplastic hydro-mechanical analysis of unsaturated porous media using a meshfree method

This paper presents the first application of an advanced meshfree method, ie, the edge-based smoothed point interpolation method (ESPIM), in simulation of the coupled hydro-mechanical behaviour of unsaturated porous media. In the proposed technique, the problem domain is spatially discretised using a triangular background mesh, and the polynomial point interpolation method combined with a simple node selection scheme is adopted for creating nodal shape functions. Smoothing domains are formed on top of the background mesh, and a constant smoothed strain, created by applying the smoothing operation over the smoothing domains, is assigned to each smoothing domain. The deformation and flow models are developed based on the equilibrium equation of the mixture, and linear momentum and mass balance equations of the fluid phases, respectively. The effective stress approach is followed to account for the coupling between the flow and deformation models. Further coupling among the phases is captured through a hysteretic soil water retention model that evolves with changes in void ratio. An advanced elastoplastic constitutive model within the context of the bounding surface plasticity theory is employed for predicting the nonlinear behaviour of soil skeleton. Time discretisation is performed by adopting a three-point discretisation method with growing time steps to avoid temporal instabilities. A modified Newton-Raphson framework is designed for dealing with nonlinearities of the discretised system of equations. The performance of the numerical model is examined through a number of numerical examples. The state-of-the-art computational scheme developed is useful for simulation of geotechnical engineering problems involving unsaturated soils.     

High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.     

Experience with a Water Detector in the Study of the Permafrost Structure

Geomagnetism and Aeronomy - The results of a study of the geoelectric section of the upper layers of the Earth at observation sites in Yakutia via vertical electrical sounding and surface impedance...     

Implementation of a coupled plastic damage distinct lattice spring model for dynamic crack propagation in geomaterials

This paper studies dynamic crack propagation by employing the distinct lattice spring model (DLSM) and 3‐dimensional (3D) printing technique. A damage‐plasticity model was developed and implemented in a 2D DLSM. Applicability of the damage‐plasticity DLSM was verified against analytical elastic solutions and experimental results for crack propagation. As a physical analogy, dynamic fracturing tests were conducted on 3D printed specimens using the split Hopkinson pressure bar. The dynamic stress intensity factors were recorded, and crack paths were captured by a high‐speed camera. A parametric study was conducted to find the influences of the parameters on cracking behaviors, including initial and peak fracture toughness, crack speed, and crack patterns. Finally, selection of parameters for the damage‐plasticity model was determined through the comparison of numerical predictions and the experimentally observed cracking features.     

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Changes in hillslope hydrology in a perched,shallow soil system due to clearcutting and residual biomass removal

Sustainable fuels legislation and volatility in energy prices have put additional pressures on the forestry sector to intensify the harvesting of biomass for “advanced biofuel” production. To better understand how residual biomass removal after harvest affects forest hydrology in relatively low slope terrain, a Before-After-Control-Impact (BACI) study was conducted in the USDA Forest Service's Marcell Experimental Forest, Minnesota, USA. Hydrological measurements were made from 2010–2013 on a forested hillslope that was divided into three treatment blocks, where one block was harvested and residual biomass removed (Biomass Removed), the second was harvested and residual biomass left (Biomass Left), and the last block was left as an Unharvested Control. The pre-harvest period (2 years) was 2010–11 and post-harvest (2 years) was 2012–13. Water table elevation at the upslope and downslope position, subsurface runoff, and soil moisture were measured between May–November. Mixed effect statistical models were used to compare both the before-after and “control” treatment ratios (ratios between harvested hillslopes and the Unharvested Control hillslope). Subsurface runoff significantly increased (p < .05) at both harvested hillslopes but to a greater degree on the Biomass Left hillslope. Greater subsurface runoff volumes at both harvested hillslopes were driven by substantial increases during fall, with additional significant increases during summer on the Biomass Left hillslope. The hydrological connectivity, inferred from event runoff ratios, increased due to harvesting at both hillslopes but only significantly on the Biomass Left hillslope. The winter harvest minimized soil disturbance, resulting in no change to the effective hydraulic conductivity distribution with depth. Thus, the observed hydrological changes were driven by increased effective precipitation and decreased evapotranspiration, increasing the duration that both harvested hillslopes were hydrologically active. The harvesting of residual biomass appears to lessen hydrological connectivity relative to leaving residual biomass on the hillslope, potentially decreasing downstream hydrological impacts of similar forestry operations.     

Solution for a plane strain rough‐walled hydraulic fracture driven by turbulent fluid through impermeable rock

The impact of turbulent flow on plane strain fluid‐driven crack propagation is an important but still poorly understood consideration in hydraulic fracture modeling. The changes that hydraulic fracturing has experienced over the past decade, especially in the area of fracturing fluids, have played a major role in the transition of the typical fluid regime from laminar to turbulent flow. Motivated by the increasing preponderance of high‐rate, water‐driven hydraulic fractures with high Reynolds number, we present a semianalytical solution for the propagation of a plane strain hydraulic fracture driven by a turbulent fluid in an impermeable formation. The formulation uses a power law relationship between the Darcy‐Weisbach friction factor and the scale of the fracture roughness, where one specific manifestation of this generalized friction factor is the classical Gauckler‐Manning‐Strickler approximation for turbulent flow in a rough‐walled channel. Conservation of mass, elasticity, and crack propagation are also solved simultaneously. We obtain a semianalytical solution using an orthogonal polynomial series. An approximate closed‐form solution is enabled by a choice of orthogonal polynomials embedding the near‐tip asymptotic behavior and thus giving very rapid convergence; a precise solution is obtained with 2 terms of the series. By comparison with numerical simulations, we show that the transition region between the laminar and turbulent regimes can be relatively small so that full solutions can often be well approximated by either a fully laminar or fully turbulent solution.     

Active capture and anomalous adsorption: New mechanisms for the incorporation of heavy noble gases

Abstract— Active capture is a new process for the incorporation of large quantities of heavy noble gases into growing surfaces. Adsorption in the conventional sense involves surface bonding by polarization (Van der Waals forces). What is referred to as “anomalous adsorption” of heavy noble gases involves chemical bonds and can occur when other (more chemically active) species are not available to preempt sites with unfilled bonds. Anomalous adsorption has been observed under conditions of fracture, vacuum deposition and ionizing radiation. Active capture depends upon anomalous adsorption to retain noble gases on a surface long enough to be captured in a growing surface film as it is deposited. The fundamental principle may be the impingement onto the growing film with sufficient energy to liberate surface electrons (work function energy of a few electronvolts) so that they are retained by anomalous adsorption long enough to be entrapped in the growing surface. Trapping efficiencies of ?1% have been observed for Kr and Xe in laboratory experiments, implying a fundamentally new mechanism for the incorporation of heavy noble gases onto surfaces. It may play a role in explaining the large concentrations of planetary noble gases contained in phase‐Q.