Evolution of electron and proton temperatures in a flaring loop

We have investigated numerically how a temperature difference between electrons and protons is produced in a flaring loop by adopting a one-fluid, two-temperature model instead of a single-temperature model. We have treated a case in which flare energy is released in the form of heating of electrons located in the top part of the loop.In this case, a large temperature difference (T _e/T _p 10) appears in the corona in the energy-input phase of the flare. When the material evaporated from the chromosphere fills the corona, the temperature difference in the loop begins to shrink rapidly from below. Eventually, in the loop apex, the proton temperature exceeds the electron temperature mainly due to cooling of the electrons by conduction down the loop and heating of the protons by compression of the ascending material. In the late phase of the flare (t 15 min from the flare onset), the temperature difference becomes less than 2% of the mean temperature of electrons and protons at every point in the loop.     

Depth distribution of radiolarians from the Chukchi and Beaufort Seas, western Arctic

The depth distributions of the radiolarian fauna in the Chukchi and Beaufort Seas, marginal seas of the western Arctic Ocean, were examined quantitatively in depth-stratified plankton tows from 4 or 5 intervals above 500 m and in surface sediments from various depths between 163 and 2907 m. The radiolarian assemblage from the water column in September 2000 was dominated by Amphimelissa setosa and followed by the Actinomma boreale/leptoderma group, Pseudodictyophimus gracilipes and Spongotrochus glacialis. These species are related to the Arctic Surface Water shallower than 150 m. This assemblage is similar to that in the Greenland Sea relating to the ice edge, but did not contain typical Pacific radiolarians in spite of the flow of water of Pacific origin in this region. The living depth of Ceratocyrtis historicosa was restricted to the relatively warm water between 300 and 500 m corresponding to the upper Arctic Intermediate Water (AIW) originating from the Atlantic Ocean. Radiolarian assemblages in the surface sediments are similar to those in the plankton tows, except for common Cycladophora davisiana in sediment samples below 500 m. C. davisiana is probably a deep-water species adapted to the lower AIW or the Canadian Basin Deep Water ventilated from the shelves.     

Excess CO2 and pHexcess in the Intermediate Water Layer of the Northwestern Pacific

Excess CO₂ and pH_excess showing an increase in dissolved inorganic carbon and a decrease in pH from the beginning of the industrial epoch (middle of the 19th century) until the present time have been calculated in the intermediate water layer of the northwestern Pacific and the Okhotsk Sea. It is concluded that: (1) The Kuril Basin (Okhotsk Sea) and the Bussol' Strait areas are characterized by the greatest concentrations of excess CO₂ at isopycnal surfaces due to the processes of formation and transformation of intermediate water mass. (2) The largest difference in excess CO₂ concentration between the Okhotsk Sea and the western subarctic Pacific (about 8 µmol/kg) is found at the = 27.0. (3) The difference in excess CO₂ between the western subarctic Pacific and subtropical regions is significant only in the upper part of the intermediate water layer ( = 26.7–27.0). (4) About 10% of the excess CO₂ accumulation in the subtropical north Pacific is determined by water exchange with the subarctic Pacific and the Okhotsk Sea.     

Air-Sea Gas Transfer Velocity in Stormy Winter Estimated from Radon Deficiency

Thirteen vertical profiles of ²²⁶Ra and ²²²Rn in the near-surface water were obtained in the western North Pacific in winter, and the gas transfer velocities across the air-sea interface were estimated. The transfer velocities found by applying a steady state model varied widely from 2.1 to 30.2 m day⁻¹ with a mean of 9.4 m day⁻¹. The mean value is almost 5 times higher than that in summer in other oceans, and the maximum value is a record high for world oceans. This is partly due to the inadequacy of the steady state model, which overestimates when stronger winds blow in more recent days than the ²²²Rn half-life of about 4 days. In fact, a strong low pressure zone passed through the station about 2 days earlier, which was one of the low pressure zones that with a period of develop once a week or so in the northwestern North Pacific in winter. Instead of steady-state removal, if half of the radon removal occurred sporadically every 7 days, and the last removal took place two days before the observation, the transfer velocity would be 26 m day⁻¹. Our mean transfer velocity, which is less than 20% different from the steady state value including both overestimated and underestimated values, 9.4 ± 4.8 m day⁻¹, seems to represent the mean state of this region in winter. This suggests that the gas exchange fluxes under extremely rough conditions in the open ocean are larger than those estimated by using a transfer velocity equation with a linear or quadratic relationship with wind speed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

Measuring the k–S–p relations on DNAPLs migration

Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions.     

Structural modifications of CaGeO3-wollastonite under room temperature pressurization

 In-situ X-ray diffraction measurements of CaGeO₃-wollastonite at high pressure at room temperature have been performed using a diamond anvil cell with an X-ray source. A new structural modification of CaGeO₃-wollastonite is observed at about 6GPa and the characteristic reflections of the high pressure form are preserved on decompression to an ambient pressure. A rhodonite-like structure is proposed as a high pressure form from the crystal chemical consideration. The rhodonite-like phase is further transformed into a perovskite-form at about 15 GPa. The rhodonite-like-form of CaGeO₃ seems not to be a stable phase from the heating experiments under high pressures. The metastable transition path from the wollastonite to the perovskite polymorph through the rhodonite-like structure is kinetically favored under room temperature pressurization. No pressure-induced amorphization is observed during the transition into the perovskite-form, although the transition is accompanied by the coordination change of Ge atoms from fourfold to sixfold. Received: July 19, 1995 / Revised, accepted: August 1996     

面向21世纪的煤化工

煤炭是中国的主要能源和资源，但同时也是主要的污染源。从保护环境、合理利用有限的化石资源的角度和中国的具体国情考虑，应该大力开发温和化高效煤的新工艺，使煤炭资源逐步由能源型利用转化为材料型利用，近年来，我们在煤的溶剂萃取，脱硫降灰机理，煤相关模型化合物反应，煤焦油中稠环芳香族化合物的分离精制，功能性高分子单体合成及一氧化碳高效吸附剂的制备等方面做了大量的研究工作，结合这些研究工作，本文介绍了煤化工的     

Neodymium isotopic variations in Northwest Pacific waters

Four vertical profiles of the concentration and isotopic composition of Nd in seawater were obtained in the western North Pacific. Two profiles from the Kuroshio Current regime showed congruently that although the Nd concentration increases gradually with depth, its isotopic composition varies significantly with depth depending upon the water mass occupying the water column. The high-salinity Kuroshio waters originating from the North Pacific Tropical Water (NPTW) carry the least radiogenic Nd (?_Nd = −7.4 to −8.7) to this region at ∼250 m from the western margin continental shelves, most likely from the East China Sea. The Nd isotopic compositions in the North Pacific Intermediate Water (NPIW) that occurs at 600 to 1000 m in the subtropical region are fairly uniform at ?_Nd = −3.7. The profile data from the ∼38° to 40°N Kuroshio/Oyashio mixed water region off Sanriku of Honshu, Japan, also suggest that the newest NPIW with ?_Nd = −3.2 is formed there by the mixing of various source waters, and the radiogenic component of Nd is derived mainly from the Oyashio waters.In the Pacific Deep Water (PDW) below ∼1000 m, the Nd isotopic composition is neither vertically nor horizontally homogeneous, suggesting that it serves as a useful tracer for sluggish deep water circulation as well. Two profiles from the Izu-Ogasawara Trench showed a minimum ?_Nd value at ∼2000 m, suggesting that there exists a horizontal advective flow in the vicinity of Honshu, Japan. There is some evidence from other chemical properties to support this observation. The waters below 4000 m including those within the trench in the subtropical region have ?_Nd values of around −5, suggesting that the deep waters are fed from the south along the western boundary, ultimately from the Antarctic Bottom Water (AABW) in the South Pacific. This extends up to ∼40°N along the Japanese Islands. In the subarctic region (>∼42°N), the waters have more radiogenic Nd with ?_Nd > −4.0 throughout the water column, presumably due to the supply of Nd by weathering in such igneous provinces as the Kuril-Kamchatska-Aleutian Island chain. The lateral inhomogeneity of the Nd isotopic composition in PDW suggests that there may be different circulation and mixing regimes in the North Pacific Basin.     

Different thermal preferences for brooding and larval dispersal of two neighboring shrimps in deep‐sea hydrothermal vent fields

Temperature is an important factor affecting the distributions and life‐history traits of marine animals. Deep‐sea hydrothermal vents are suitable environments to examine ecologic differences related to temperature, due to the steep temperature gradients around the vents. Rearing experiments under various temperature conditions (5–30 °C) at atmospheric pressure demonstrated a difference in thermal effects on egg hatching and larva in two co‐occurring, vent‐associated alvinocaridid shrimps – the peripherally distributed Alvinocaris longirostris and the centrally distributed Shinkaicaris leurokolos. The duration before hatching became shorter as temperature increased, while the maximum hatching rate occurred at higher temperatures in S. leurokolos (10–20 °C) than in A. longirostris (10 °C). Hatched larvae of both species were negatively buoyant, and larva with normal abdominal length could actively swim and stay suspended in the mid‐ or surface water layers of the culture plates under our experimental conditions. However, no larvae settled or metamorphosed into juveniles under the rearing conditions used in this study. Larvae with shortened abdomens occurred under most of the experimental conditions, although they were less frequent at 10 °C in A. longirostris and 20 °C in S. leurokolos. The maximum survival periods at these temperatures were 88 days in A. longirostris and 30 days in S. leurokolos. These characteristics may cause differences in the distributional ranges of the two species. The present results indicate that temperature is an important factor controlling life‐history traits of vent shrimps.