Distribution of calcareous nannoplankton in surface sediments along the northern KwaZulu-Natal Bight,South Africa

The coccolith assemblages from seafloor sediments over the inner shelf in the northern region of the KwaZulu- Natal Bight on the east coast of South Africa were identified and their distribution determined. In all, 29 Recent species and taxonomic groups, as well as 29 reworked species were recorded. The distribution of the Recent species appears to be governed by environmental features that have been documented in other studies: temperature, salinity, nutrient concentration and water circulation pattern, which reveals the long-term existence of a circulation cell in the sector between Durban Bay and the Thukela River. The outer edge of the cell consists of nutrient-enriched mixed layers and is characterised by an enhanced abundance of Gephyrocapsa oceanica, whereas the central region consists of a stratified nutrient-depleted water mass with elevated abundance of Umbilicosphaera sibogae, Florisphaera profunda, and a group of umbelliform species. The elevated levels of G. oceanica, coupled with the rarity of U. sibogae, F. profunda and the umbelliform species, confirm the presence of a permanent upwelling cell off Richards Bay. The maximum abundance of F. profunda found between Richards Bay and Lake Nhlabane indicates a region of nutrient-depleted (except for nitrite) conditions.     

Early Proterozoic,basaltic andesite tuff-breaccia: downslope,subaqueous mass transport of phreatomagmatically-generated tephra

At Bear Lake, in the Flin Flon-Snow Lake greenstone belt of Manitoba, 400⁺ m of thick-to very thick-bedded, generally ungraded, basaltic andesite tuff-breccia, breccia, and lapilli-tuff are intercalated with pillowed lava flows in the upper part of an early Proterozoic submarine basaltic andesite shield volcano. The fragmental rocks comprise angular, amygdaloidal blocks and lapilli, many with partial chilled selvages, in a matrix of blocky, non-amygdaloidal to highly amygdaloidal vitric basaltic andesite ash and small lapilli. Minor thin-to medium-bedded, commonly normally graded tuff occurs in the upper part of the sequence. Clasts in fragmental beds consistently have higher amygdule contents than intercalated lava flows. Although similar to pillow-fragment breccias, the Bear Lake fragmental rocks were produced by extended surtseyan-type, phreatomagmatic eruptions, with associated fire fountain activity, at a progressively subsiding, shallow water vent. Periodic tephra slumping generated debris flows that transported particles down the uppe, gentle slope of the volcano to a depositional site at a water depth of less than 1 km. Turbidity currents probably carried much fine tephra to deeper water; tuff was deposited in the preserved section only after explosive volcanism ceased.     

Mechanisms of mud extrusion on the Mediterranean Ridge Accretionary Complex

 Drilling two mud domes on the Mediterranean Ridge during ODP Leg 160 has demonstrated that the eruption of mud breccia began at least 1.5 Ma ago. An evolution through extrusive building of a cone, followed by successive eruptions of clast-bearing mud debris flows and subsequent subsidence can be deduced for both domes. Results from permeability and shear strength tests, grain size analyses, sedimentary textures, and clast provenance provide clues concerning the mechanism of mud volcanism. The collision of Africa with Eurasia resulted in backthrusting of the evaporite-dominated accretionary wedge against a rigid backstop. This allowed egress of overpressured fluid-rich mud of presumed Messinian age from the décollement, although many of the clasts may have originated from the overlying accretionary wedge.     

Structural features and mechanical behaviour of a pyroclastic weak rock

The results of an extensive programme of laboratory testing on intact and reconstituted samples of a pyroclastic weak rock from the volcanic complex of the Colli Albani (Central Italy) are presented. The deposit is known as Pozzolana Nera and may be assimilated to a bonded coarse grained material. The nature of bonds and the micro‐structural features were examined by means of diffractometry, optical and electron microscopy. As bonds are made of the same constituents of grains and aggregates of grains, bond deterioration and particles breakage upon loading are indistinguishable features of the mechanical behaviour. The testing programme consisted mainly of one‐dimensional and drained and undrained triaxial compression tests in a wide range of confining pressures up to 58 MPa. As confining stress increases, the mechanical behaviour of the material changes from brittle and dilatant to ductile and contractant; for both brittle and ductile behaviour failure is associated with the formation of shear surfaces separating the sample in several parts at the end of test. The experimental stress–dilatancy relationships are compared with the classical stress–dilatancy theories for a purely frictional material and for a material with friction and cohesion between particles. The analysis of the data indicates that peak strength results from the interplay between degradation of inter‐particle bonds, increasing friction between particles and increasing rate of dilation. Copyright © 2001 John Wiley & Son, Ltd.     

A comparison of the fabric and permeability anisotropy of consolidated and sheared silty clay

This paper reports the geotechnical aspects of an experimental programme investigating the permeability of shear zones in clay-rich sediments. Oedometric and ring shear permeameters were used to investigate and compare permeability anisotropy in consolidated and sheared silty clay, to simulate the behaviour of wall-rock sediments and shear zone sediments respectively. In line with other studies, consolidated silty clay was found to have no significant permeability anisotropy, although clay fabric anisotropy was well developed. However, sheared silty clay showed an increase in permeability anisotropy (r_k = 3−16) with decreasing void ratio (e = 0.8−0.4), corresponding to effective stresses of 100 kPa to 4 MPa. This level of anisotropy was retained during shearing along the unloading path, and no significant dilation or enhancement of permeability was observed.     

Forced imbibition into a limestone: measuring P‐wave velocity and water saturation dependence on injection rate

Quantitative interpretation of time‐lapse seismic data requires knowledge of the relationship between elastic wave velocities and fluid saturation. This relationship is not unique but depends on the spatial distribution of the fluid in the pore‐space of the rock. In turn, the fluid distribution depends on the injection rate. To study this dependency, forced imbibition experiments with variable injection rates have been performed on an air‐dry limestone sample. Water was injected into a cylindrical sample and was monitored by X‐Ray Computed Tomography and ultrasonic time‐of‐flight measurements across the sample. The measurements show that the P‐wave velocity decreases well before the saturation front approaches the ultrasonic raypath. This decrease is followed by an increase as the saturation front crosses the raypath. The observed patterns of the acoustic response and water saturation as functions of the injection rate are consistent with previous observations on sandstone. The results confirm that the injection rate has significant influence on fluid distribution and the corresponding acoustic response. The complexity of the acoustic response —‐ that is not monotonic with changes in saturation, and which at the same saturation varies between hydrostatic conditions and states of dynamic fluid flow – may have implications for the interpretation of time‐lapse seismic responses.     

Effect of supercritical CO2 on carbonates: Savonnières sample case study

CO₂ geosequestration is an efficient way to reduce greenhouse gas emissions into the atmosphere. Carbonate rock formations are one of the possible targets for CO₂ sequestration due to their relative abundance and ability to serve as a natural trapping reservoir. The injected supercritical CO₂ can change properties of the reservoir rocks such as porosity, permeability, tortuosity, and specific surface area due to dissolution and precipitation processes. This, in turn, affects the reservoir characteristics, i.e., their elastic properties, storage capacity, stability, etc. The tremendous progresses made recently in both microcomputed X‐ray tomography and high‐performance computing make numerical simulation of physical processes on actual rock microstructures feasible. However, carbonate rocks with their extremely complex microstructure and the presence of microporosity that is below the resolution of microcomputed X‐ray tomography scanners require novel, quite specific image processing and numerical simulation approaches. In the current work, we studied the effects of supercritical CO₂ injection on microstructure and elastic properties of a Savonnières limestone. We used microtomographic images of two Savonnières samples, i.e., one in its natural state and one after injection and residence of supercritical CO₂. A statistical analysis of the microtomographic images showed that the injection of supercritical CO₂ led to an increase in porosity and changes of the microstructure, i.e., increase of the average volume of individual pores and decrease in the total number of pores. The CO₂ injection/residence also led to an increase in the mean radii of pore throats, an increase in the length of pore network segments, and made the orientation distribution of mesopores more isotropic. Numerical simulations showed that elastic moduli for the sample subjected to supercritical CO₂ injection/residence are lower than those for the intact sample.     

Constraints on the Sealing Capacity of Faults with Clay Smears from Discrete Element Models Validated by Laboratory Experiments

Prediction of hydrocarbon column heights in structural traps critically depends on proper analysis of the sealing capacity of faults. Entrainment of clay in fault zones in upper crustal levels may lead to the development of continuous clay smears that dramatically increase the sealing capacity of faults. In this study, direct shear experiments on large-scale samples of layered sandstone–claystone–sandstone are simulated using two-dimensional discrete element numerical models to study the development of clay smears for different claystone types and normal stress conditions. Analysis of clay smear structures in terms of drag, slicing, wear and flow of clay reveals that drag is dominant at low shear displacements and high local stress concentrations, slicing and wear become important at higher shear displacement and low stresses at source bed near the fault zone. Correlation between critical fault displacements in the experiments and local stress ratios (shear stress divided by normal stress) in the models is used to determine smear failure and leakage for all claystones and normal stresses. A smear breach diagram with sealing/leaking conditions for faults containing clay smears shows that clay smears may be sealing at larger displacements than predicted by other fault seal algorithms, such as shale gouge ratio, in particular for low shale content and high normal stress.