Fluid Geochemistry as Indicator of Tectonically-Related,Deep Water Circulations in the Sardinian Rift-Campidano Graben (Italy): New Insights from Environmental Isotopes

The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and discharging groundwaters belonging to the Na–HCO₃ and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform (MCP). The high CO₂ contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains. The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today. At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly variable δ¹³C_TDIC values suggest the presence of two distinct CO₂ sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO₂ and He indicates an increased mantle signature in uprising CO₂-rich fluids.     

Laboratory simulation of geogas microbubble flow

Preliminary laboratory tests provided first data on the behavior of gas microbubbles through porous media in the framework of the geogas theory. Under experimented conditions with laboratory equipment arranged for pressure controlled gas-tracer injection and sampling, gas microbubbles moved up to ten times faster than singlephase flow in dry media under the same injection pressure. Microbubbles were determined to be very sensitive to changes in injection pressure and their terminal velocity seems to be described with good approximation by the Stokes formula. The capability of microbubbles to pick up and transport upward for short distances solid ultra-small particles (metallic and radionuclide compounds) has been proved. Results are consistent with a time-dependent process linked to the transport properties of microbubbles (e.g., flotation), such as that reported by some authors.     

Multifrequency behayiour of the dwarf nova SS Cygni

Several years of coordinated multifrequency observations of the dwarf nova SS Cygni have been performed in order to study the accretion behaviour of this system in particular, and in general to clarify this crucial problem for the cataclysmic variables.From IUE measurements, together with those from optical and IR ground based telescopes, we have found orbital modulations in the continuum and in the equivalent widths of the emission lines. During quiescent phases the behaviour of SS Cygni are dependent on the type of the preceding outburst (long-type or short-type).In this paper we will discuss the physical implications one can derive from these results.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.Based on the observations performed with IUE (VILSPA) satellite, and with the telescopes of the Loiano and Roque de los Muchachos Observatories.     

Carbon dioxide and radon gas hazard in the Alban Hills area (central Italy)

The sudden and catastrophic, or slow and continuous, release at surface of naturally occurring toxic gases like CO₂, H₂S and Rn poses a serious health risk to people living in geologically active regions. In general this problem receives little attention from local governments, although public concern is raised periodically when anomalous toxic-gas concentrations suddenly kill humans or livestock. For example, elevated CO₂ concentrations have been linked to the death of at least 10 people in the central Italian region of Lazio over the last 20 years, while it was the CO₂ asphyxiation of 30 cows in a heavily populated area near Rome in 1999 which prompted the present soil-gas study into the distribution of the local health risk. A detailed geochemical survey was carried out in an area of about 4 km² in the Ciampino and Marino districts, whereby a total of 274 soil-gas samples were collected and analysed for more than 10 major and trace gas species. Data were then processed using both statistical and geostatistical methods, and the resulting maps were examined in order to highlight areas of elevated risk. General trends of elevated CO₂ and Rn concentrations imply the presence of preferential pathways (i.e. faults and fractures) along which deep gases are able to migrate towards the surface. The CO₂ and Rn anomalous trends often correspond to and are usually elongated parallel to the Apennine mountain range, the controlling structural feature in central Italy. Because of this fundamental anisotropy in the factors controlling the soil-gas distribution, it was found that a geostatistical approach using variogram analysis allowed for a better interpretation of the data. With regard to the health risk to local inhabitants, it was found that although some high risk areas had been zoned as parkland, others had been heavily developed for residential purposes. For example, many new houses were found to have been built on ground which has soil-gas CO₂ concentrations of more than 70% and radon values of more than 250 kBq m⁻³. It is recommended that land-use planners incorporate soil-gas and/or gas flux measurements in environmental assessments in areas of possible risk (i.e. volcanic or structurally active areas).     

Effects of ocean acidification and high temperatures on the bryozoan Myriapora truncata at natural CO2 vents

There are serious concerns that ocean acidification will combine with the effects of global warming to cause major shifts in marine ecosystems, but there is a lack of field data on the combined ecological effects of these changes due to the difficulty of creating large‐scale, long‐term exposures to elevated CO₂ and temperature. Here we report the first coastal transplant experiment designed to investigate the effects of naturally acidified seawater on the rates of net calcification and dissolution of the branched calcitic bryozoan Myriapora truncata (Pallas, 1766). Colonies were transplanted to normal (pH 8.1), high (mean pH 7.66, minimum value 7.33) and extremely high CO₂ conditions (mean pH 7.43, minimum value 6.83) at gas vents off Ischia Island (Tyrrhenian Sea, Italy). The net calcification rates of live colonies and the dissolution rates of dead colonies were estimated by weighing after 45 days (May–June 2008) and after 128 days (July–October) to examine the hypothesis that high CO₂ levels affect bryozoan growth and survival differently during moderate and warm water conditions. In the first observation period, seawater temperatures ranged from 19 to 24 °C; dead M. truncata colonies dissolved at high CO₂ levels (pH 7.66), whereas live specimens maintained the same net calcification rate as those growing at normal pH. In extremely high CO₂ conditions (mean pH 7.43), the live bryozoans calcified significantly less than those at normal pH. Therefore, established colonies of M. truncata seem well able to withstand the levels of ocean acidification predicted in the next 200 years, possibly because the soft tissues protect the skeleton from an external decrease in pH. However, during the second period of observation a prolonged period of high seawater temperatures (25–28 °C) halted calcification both in controls and at high CO₂, and all transplants died when high temperatures were combined with extremely high CO₂ levels. Clearly, attempts to predict the future response of organisms to ocean acidification need to consider the effects of concurrent changes such as the Mediterranean trend for increased summer temperatures in surface waters. Although M. truncata was resilient to short‐term exposure to high levels of ocean acidification at normal temperatures, our field transplants showed that its ability to calcify at higher temperatures was compromised, adding it to the growing list of species now potentially threatened by global warming.     

Helium-3 anomalies and crust-mantle interaction in Italy

The distribution of primordial ³He in the crust of Italy has been investigated through a survey of groundwaters, hot-springs, exploration and production geothermal wells. The mantle-derived component varies from 0% to > 60% and reaches a maximum at Vulcano in the Eolian Islands. ³He anomalies occur where the conductive heat flow is relatively high, but the relationships between heat flow and anomaly are uncertain.The distribution of ³He in the main reservoir and cap rock to the Larderello geothermal system shows that the mantle-derived ³He varies from ~5% to ~40% of total He and reaches a maximum in fluids extracted from a depth of ca. 3 km within the basement. Bomb-produced tritiogenic ³He appears to make a near-negligible contribution. Well 107 at Larderello has been monitored over a period of 17 months and the ${}^3\text{He}{}^4\text{He}$ ratio (R) varies from 1.4 to 1.6 times the atmospheric ratio (Ra) whilst He/Ne varies from 9 to 160. A model is proposed for the Larderello geothermal system whereby mantle-derived heat and volatiles are advected to shallow (6–8 km) depths in association with melts and released into the main geothermal reservoir at Larderello in a non-uniform manner possibly associated with fracturing. Isotopic and elemental equilibrium of gaseous species (C, O, H) appears to have taken place in the basement to the main reservoir from where fluid with R/Ra ≥ 3.2 has been extracted.     

Sulfur isotopic evidence for the supergene origin of alunite deposits,Tolfa district,Italy

Sulfur isotope abundance data for minerals of the historically important alunite deposits of the Tolfa district indicate (1) compositional similarity between sulfates and sulfides (mean S³⁴ values of +5.5⁴ and +6.3⁴ permil respectively), (2) negligible fractionation factors (0.995 to 1.004) for sulfate-sulfide mineral pairs, (3) two distinct sulfide isotopic populations characterized by pyrite (+8.3⁴ permil) and marcasite (–1.0⁵ permil) and with associated alunite displaying a covariant isotopic shift, and (4) possible contamination of the hydrothermal system by evaporite sulfate (+25.1 permil) because hypogene pyrite, galena, and cinnabar are enriched in S³⁴ (+6.1 to +10.3 permil). We suggest that alunite, barite, and possibly marcasite are of supergene origin and that the sulfate-sulfur was derived from the surficial oxidation of sulfides. Our conclusion is compatible with the geologic evidence and confirms the supergene hypothesis for the genesis of Tolfa alunites proposed by Fuchs and De Launay (1893) and De Launay (1906; 1913).

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Zusammenfassung Die Schwefel-Isotopen-Häufigkeiten von Mineralen der historisch wichtigen Alunit-Vorkommen des Gebietes um Tolfa zeigen (1) eine große Ähnlichkeit der Isotopen-Zusammensetzungen zwischen Sulfaten und Sulfiden (Mittelwerte für S³⁴ von +5,5₄ bzw. +6,3₄), (2) höchstens sehr geringe Fraktionierungs-Faktoren (0,995 bis 1,004) für Mineralpaare von Sulfat und Sulfid, (3) zwei verschiedene Gruppen von Isotopenverhältnissen bei den Sulfiden, und zwar für Pyrit (+8,3₄) und Markasit (–1,0₅), wobei der jeweils begleitende Alunit ähnliche Unterschiede aufweist, und (4) eine mögliche Beeinflussung des hydrothermalen Systems durch Sulfat aus Salzlagerstätten (+25,1), weil hypogener Pyrit, Galenit und Zinnober eine Anreicherung von S³⁴ zeigen (+6,1 bis +10,3). Wir nehmen an, daß Alunit, Baryt und möglicherweise auch Markasit supergen gebildet wurden, und daß der Sulfat-Schwefel durch die Oxydation von Sulfiden an der Erdoberfläche entstand. Unsere Schlußfolgerung ist mit den geologischen Befunden vereinbar und bestätigt die supergene Hypothese für die Bildung der Alunitvorkommen von Tolfa, wie sie von Fuchs und De Launay (1893) und De Launay (1906; 1913) vertreten wurde.

     

Liquefaction of soil in the Emilia-Romagna region after the 2012 Northern Italy earthquake sequence

At the end of May 2012, the Po plain region in northern Italy was shaken by a long sequence of seismic events. The 2012 Northern Italy earthquake sequence counted two mainshocks, about 1,600 aftershocks and lasted for several weeks. Although the mainshocks, which occurred on May 20 and May 29, 2012, registered a moment magnitude of 5.9 and 5.8, respectively, these two events caused widespread soil liquefaction and substantial damages to the built environment. This paper reports lessons learnt from a field investigation conducted in the areas affected by the earthquake sequence. Based on the field observations, it was concluded that despite the relatively low magnitudes of the shocks, most of the damages occurred as a consequence of liquefaction phenomena and/or absence of retrofitting of historical structures. The latter comprise churches, tower bells, towers, castles and fortresses. It was found that the occurrence of liquefaction was mainly associated with the presence of saturated alluvial soil deposits which were characterised by high liquefaction susceptibility. It was noted that these highly liquefiable soils were mainly located in proximity of ancient river courses that were artificially diverted in the eighteenth century to mitigate flooding and other hydrological risks.     

The astroclimatological comparison of the Paranal Observatory and El Roque de Los Muchachos Observatory

The new extremely large telescope projects need accurate evaluation of the candidate sites. In this paper, we present the astroclimatological comparison between the Paranal Observatory, located on the coast of the Atacama Desert (Chile), and the Observatorio del Roque de Los Muchachos (ORM), located in La Palma (Canary Islands). We apply a statistical analysis using long-term data bases from Paranal and Carlsberg Automatic Meridian Circle (CAMC) weather stations. The monthly, seasonal and annual averages of the main synoptical parameters in the two sites are computed. We compare the long-term trends in order to understand the main differences between the two sites. Significant differences between the two analysed sites have been found. Temperature has increasing trends in both observatories with somewhat higher evidence at the ORM. Seasonal variations of pressure at Paranal have been highly decreasing since 1989, and we do not see the same phenomenon at the ORM. The two sites are dominated by high pressure. In cold seasons, relative humidity (RH) is lower than 60 per cent at CAMC and 15 per cent at Paranal. In warm seasons, RH is lower than 40 per cent at CAMC and 20 per cent at Paranal. The analysis of the dew point has shown better conditions at Paranal with respect to CAMC in winter, autumn and spring before 2001, while the two sites are becoming similar afterwards. Winds at the ORM are subject to pronounced local variations.     

A multiphysics and multiscale software environment for modeling astrophysical systems

We present MUSE, a software framework for combining existing computational tools for different astrophysical domains into a single multiphysics, multiscale application. MUSE facilitates the coupling of existing codes written in different languages by providing inter-language tools and by specifying an interface between each module and the framework that represents a balance between generality and computational efficiency. This approach allows scientists to use combinations of codes to solve highly coupled problems without the need to write new codes for other domains or significantly alter their existing codes. MUSE currently incorporates the domains of stellar dynamics, stellar evolution and stellar hydrodynamics for studying generalized stellar systems. We have now reached a “Noah’s Ark” milestone, with (at least) two available numerical solvers for each domain. MUSE can treat multiscale and multiphysics systems in which the time- and size-scales are well separated, like simulating the evolution of planetary systems, small stellar associations, dense stellar clusters, galaxies and galactic nuclei. In this paper we describe three examples calculated using MUSE: the merger of two galaxies, the merger of two evolving stars, and a hybrid N-body simulation. In addition, we demonstrate an implementation of MUSE on a distributed computer which may also include special-purpose hardware, such as GRAPEs or GPUs, to accelerate computations. The current MUSE code base is publicly available as open source at http://muse.li.