CO2 transfer between the upper mantle and the atmosphere: temporary storage in the lower continental crust

The CO₂ atmospheric content has shown large variations over geological times. High contents (up to one order of magnitude more than present-day values) ultimately correspond to discrete episodes of mantle degassing, either juvenile, or subduction-related (carbon recycling). A number of arguments (e.g. the continuous volume increase of carbonate-bearing sediments with time) suggest that, throughout the Earth's history, juvenile CO₂ has formed a major contribution to the global carbon budget of the Earth.
The absence of a direct relationship between major volcanic episodes and the average CO₂ atmospheric content suggests that volcanoes might not be the only way by which mantle CO₂ is transported to the surface. It is proposed that large quantities of juvenile CO₂ could temporarily be stored in the lower continental crust during major episodes of granulite formation. These are primarily caused by magmatic underplating and they result in a vertical accretion of the crust by accumulation of CO₂-bearing, mantle-derived magmas. Most of the CO₂ migrates through the crust during post-metamorphic evolution and isostatic restoration of the normal continental thickness. However, large quantities of CO₂ can still be present in some areas, notably as high-density fluids enclosed in minerals.     

Fractures: Finite-size scaling and multifractals

The distributions of contact area and void space in single fractures in granite rock have been determined experimentally by making metal casts of the void spaces between the fracture surfaces under normal loads. The resulting metal casts on 52 cm diameter core samples show a complex geometry for the flow paths through the fracture. This geometry is analyzed using finite-size scaling. The spanning probabilities and percolation probabilities of the metal casts are calculted as functions of observation scale. Under the highest stresses of 33 MPa and 85 MPa there is a significant size-dependence of the geometric flow properties for observation scales smaller than 2 mm. Based on this data, the macroscopic percolation properties of the extended fracture can be well represented by relatively small core samples, even under normal stresses larger than 33 MPa. The metal casts also have rich multifractal structure that changes with changing stress.     

Inflation along Kilauea's Southwest Rift Zone in 2006

We report on InSAR and GPS results showing the first crustal inflation along the southwest rift zone at Kilauea volcano in over 20 years. Two independent interferograms (May 2–August 2, 2006 and June 22–Nov 7, 2006) from the ALOS PALSAR instrument reveal domal uplift located southwest of the main caldera. The uplift is bounded on the northeast by the caldera and follows the southwest rift zone for about 12 km. It is approximately 8 km wide. We use data derived from permanent GPS stations to calibrate the InSAR displacement data and estimate uplift of 7.7 cm during the first interferogram and 8.9 cm during the second with line-of-sight volumes of 2.8 × 10⁶ m³ and 3.0 × 10⁶ m³ respectively. The earthquake record for the periods before, during, and after inflation shows that a swarm of shallow earthquakes (z < 5 km) signaled the beginning of the uplift and that elevated levels of shallow seismicity along the rift zones occurred throughout the uplift period. GPS data indicate that the inflation occurred steadily over nine months between mid-January and mid-October, 2006 making injection of a sill unlikely. We attribute the inflation to recharge of a shallow ductile area under the SWRZ.     

Field test of sub‐basalt hydrocarbon exploration with marine controlled source electromagnetic and magnetotelluric data

The recent use of marine electromagnetic technology for exploration geophysics has primarily focused on applying the controlled source electromagnetic method for hydrocarbon mapping. However, this technology also has potential for structural mapping applications, particularly when the relative higher frequency controlled source electromagnetic data are combined with the lower frequencies of naturally occurring magnetotelluric data. This paper reports on an extensive test using data from 84 marine controlled source electromagnetic and magnetotelluric stations for imaging volcanic sections and underlying sediments on a 128‐km‐long profile. The profile extends across the trough between the Faroe and Shetland Islands in the North Sea. Here, we focus on how 2.5D inversion can best recover the volcanic and sedimentary sections. A synthetic test carried out with 3D anisotropic model responses shows that vertically transverse isotropy 2.5D inversion using controlled source electromagnetic and magnetotelluric data provides the most accurate prediction of the resistivity in both volcanic and sedimentary sections. We find the 2.5D inversion works well despite moderate 3D structure in the synthetic model. Triaxial inversion using the combination of controlled source electromagnetic and magnetotelluric data provided a constant resistivity contour that most closely matched the true base of the volcanic flows. For the field survey data, triaxial inversion of controlled source electromagnetic and magnetotelluric data provides the best overall tie to well logs with vertically transverse isotropy inversion of controlled source electromagnetic and magnetotelluric data a close second. Vertical transverse isotropy inversion of controlled source electromagnetic and magnetotelluric data provided the best interpreted base of the volcanic horizon when compared with our best seismic interpretation. The structural boundaries estimated by the 20‐Ω·m contour of the vertical resistivity obtained by vertical transverse isotropy inversion of controlled source electromagnetic and magnetotelluric data gives a maximum geometric location error of 11% with a mean error of 1.2% compared with the interpreted base of the volcanic horizon. Both the model study and field data interpretation indicate that marine electromagnetic technology has the potential to discriminate between low‐resistivity prospective siliciclastic sediments and higher resistivity non‐prospective volcaniclastic sediments beneath the volcanic section.     

Joint cross-well and single-well seismic studies of CO2 injection in an oil reservoir

A series of time‐lapse seismic cross‐well and single‐well experiments were conducted in a diatomite reservoir to monitor the injection of CO₂ into a hydrofracture zone, based on P‐ and S‐wave data. A high‐frequency piezo‐electric P‐wave source and an orbital‐vibrator S‐wave source were used to generate waves that were recorded by hydrophones as well as 3‐component geophones. During the first phase the set of seismic experiments was conducted after the injection of water into the hydrofractured zone. The set of seismic experiments was repeated after a time period of seven months during which CO₂ was injected into the hydrofractured zone. The questions to be answered ranged from the detectability of the geological structure in the diatomic reservoir to the detectability of CO₂ within the hydrofracture. Furthermore, it was intended to determine which experiment (cross‐well or single‐well) is best suited to resolve these features. During the pre‐injection experiment, the P‐wave velocities exhibited relatively low values between 1700 and 1900 m/s, which decreased to 1600–1800 m/s during the post‐injection phase (?5%). The analysis of the pre‐injection S‐wave data revealed slow S‐wave velocities between 600 and 800 m/s, while the post‐injection data revealed velocities between 500 and 700 m/s (?6%). These velocity estimates produced high Poisson's ratios between 0.36 and 0.46 for this highly porous (～50%) material. Differencing post‐ and pre‐injection data revealed an increase in Poisson's ratio of up to 5%. Both velocity and Poisson's ratio estimates indicate the dissolution of CO₂ in the liquid phase of the reservoir accompanied by an increase in pore pressure. The single‐well data supported the findings of the cross‐well experiments. P‐ and S‐wave velocities as well as Poisson's ratios were comparable to the estimates of the cross‐well data. The cross‐well experiment did not detect the presence of the hydrofracture but appeared to be sensitive to overall changes in the reservoir and possibly the presence of a fault. In contrast, the single‐well reflection data revealed an arrival that could indicate the presence of the hydrofracture between the source and receiver wells, while it did not detect the presence of the fault, possibly due to out‐of‐plane reflections.     

Time-lapse crosswell seismic and VSP monitoring of injected CO<Subscript>2</Subscript> in a brine aquifer

Seismic surveys successfully imaged a small scale CO₂ injection (1,600 ton) conducted in a brine aquifer of the Frio Formation near Houston, Texas. These time-lapse borehole seismic surveys, crosswell and vertical seismic profile (VSP), were acquired to monitor the CO₂ distribution using two boreholes (the new injection well and a pre-existing well used for monitoring) which are 30 m apart at a depth of 1,500 m. The crosswell survey provided a high-resolution image of the CO₂ distribution between the wells via tomographic imaging of the P-wave velocity decrease (up to 500 m/s). The simultaneously acquired S-wave tomography showed little change in S-wave velocity, as expected for fluid substitution. A rock physics model was used to estimate CO₂ saturations of 10–20% from the P-wave velocity change. The VSP survey resolved a large (∼70%) change in reflection amplitude for the Frio horizon. This CO₂ induced reflection amplitude change allowed estimation of the CO₂ extent beyond the monitor well and on three azimuths. The VSP result is compared with numerical modeling of CO₂ saturations and is seismically modeled using the velocity change estimated in the crosswell survey.     

应用高分辨率质谱分析苏丹高酸值原油成因

苏丹Muglad和Melut盆地是苏丹乃至整个中、西非剪切带最富含油气的盆地,所发现的原油主要为中质油(重度为20°～34°API),其次为重质油(重度小于20°API),普遍高含沥青质、高含蜡、高酸值、低含硫。为了探讨高酸值原油的成因,选择了苏丹地区18个不同酸值的原油样品,尝试高分辨率质谱分析上述原油有机酸的组成。结果表明,高酸值原油的有机酸主要由环烷酸组成;环烷酸的平均相对分子质量随降解作用程度增加而增大,分子碳原子数分布范围变宽;环烷酸以一环、二环、三环环烷酸为主。生物降解作用是形成高酸值原油的主要原因。