Carbon isotope fractionation between graphite and diamond during shock experiments

Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ¹³C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ¹³C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.     

Particulate peptidoglycan in seawater determined by the silkworm larvae plasma (SLP) assay

Peptidoglycan (PG) is a biopolymer found exclusively in the cell wall of bacteria. Recent chemical analysis of particulate organic matter suggests that a major amount of the muramic acid, an amino sugar present only in PG, could not be accounted for in terms of bacterial cells (Benner and Kaiser, 2003); however, data on particulate PG is quite sparse. In the present study, conducted in 1996, the PG was examined at 5 sampling sites in the northwestern Pacific Ocean, and in natural seawater cultures. Particulate PG, which was concentrated using a 96-well filtration plate equipped with Durapore filters (pore size, 0.22 μm), was measured by the silkworm larvae plasma (SLP) assay. The PG concentration generally decreased with depth and correlated significantly with bacterial abundance throughout the entire water column. However, the ratio of particulate PG to bacterial abundance varied with depth. The average ratio was 0.61 ± 0.53 (average ± SD, n = 40) between 50 and 2000 m, which agreed with the bacterial cellular PG content from 0.63 to 1.1 fg cell⁻¹ obtained in seawater cultures. On the other hand, the ratios of PG to bacteria from the surface to 50 m (3.7 ± 2.6, n = 29) and below 2,000 m (2.1 ± 1.7, n = 7) were significantly higher than that between 50 and 2,000 m. These results may suggest that, in the surface and deep layers, a significant fraction of particulate PG was present in bacterial detritus, whereas this fraction was reduced in the middle layer.     

Archeological evidence of Pacific salmon distribution in northern Japan and implications for future global warming

Archeological evidence of Pacific salmon in Hokkaido is reviewed and compared with results from western North America. Salmon remains have been found at 24 sites in Hokkaido from the Early Jomon Period to the Ainu Period (6000–100 years ago). Fish remains at three archeological sites in the Kushiro River basin indicated that Pacific salmon (Oncorhynchus spp.) were distributed and utilized from 6000 years ago. The present Kushiro Wetland was formerly covered with seawater and called the Paleo Kushiro Bay 5000–6000 years ago. Based on the molluscan fossil fauna, seawater temperature at Paleo Kushiro Bay was about 5°C warmer than at present. Warmer conditions for salmon in Kushiro 5000–6000 years ago corresponded with the poor conditions for salmon in the Columbia River basin 6000–7000 years ago. If the future global warming is similar to the conditions that prevailed 5000–6000 years ago, the southern limit of salmon distribution will shift northwards and the salmon production will decrease. However, they will not disappear from either Hokkaido or southwestern North America.     

Numerical study of the summer temperature decrease induced by the enhancement of estuarine circulation in Fukuoka Bay

The Princeton Ocean Model with realistic bottom topography has been used to investigate the summer temperature decrease in the past 25 years in Fukuoka Bay. The vertical mixing of the model is expressed by a scheme that effectively includes the influences of interannual variations of tidal currents and wind. The results show that the historical temperature decrease in summer has been caused by tidal currents and wind weakening in the past 25 years in Fukuoka Bay. The weakening of tidal currents and wind gives rise to weakening of the vertical mixing, and to enhancement of the estuarine circulation in the bay. The enhancement of the estuarine circulation activates the inflow of open-ocean water toward Fukuoka Bay. Coastal water in summer has therefore tended to be colder and more saline in the past 25 years. This interannual variation in coastal waters is called “open-oceanization” in this study. On the basis of the numerical model, it is anticipated that the temperature will decrease by 0.2°C in the next 25 years in Fukuoka Bay if the tide and wind weaken persistently as in the present bay.     

Application of Atomic Force Microscopy to Observation of Marine Bacteria

The atomic force microscopy (AFM) is a recently developed, bench-top instrument that can image the surface structures of biological specimens at high resolution with simultaneous measurement of their size. This paper describes the application of AFM to marine bacteria. Both natural and cultured bacteria were retained on a filter or placed on glass, washed, air-dried and observed by AFM. The instrumental condition, the choice of suitable filter, effect of fixation and filtration, comparison with epifluorescent microscopic (EFM) count, and the size and shape of bacterial cells were investigated. An Isopore filter was best for concentration and subsequent observation because of its surface flatness. Cross section images showed that both rod and coccoid cells were flattened, the former usually having a two-humped shape. Bacterial cells were differentiated from non-living particles based on their cross section shape and size. Bacterial counts by AFM and EFM showed good agreement. Although size measurement is easily done by the instrument, AFM tends to overestimate the size of microspheres. More work is thus needed on the size measurement of living organisms. Because AFM easily provides images of natural bacterial cells at high magnification, it can be used as a new tool to study the fine structures of marine bacteria. This revised version was published online in July 2006 with corrections to the Cover Date.     

Use of an optical oxygen sensor to measure dissolved oxygen in seawater

The use of an optical oxygen sensor to measure dissolved oxygen in seawater was investigated. The sensor is based on the dynamic quenching of an oxygen-sensitive fluorochrome embedded in the tip. Dissolved oxygen in seawater samples collected from eight stations at depths ranging from 3000 to 6000 m was analyzed both with the optical sensor and by the Winkler titration method. The two sets of data did not differ significantly. The stability and simplicity of the method and the good agreement of the results with those of the titration method indicate that the sensor would be useful for fieldwork.     

Ecologic and taxonomic diversification in the Mesozoic brackish-water bivalve faunas in Japan, with emphasis on infaunalization of heterodonts

Mesozoic brackish-water bivalve faunas in Japan diversified in three steps: at the beginning of the Early Jurassic, Early and Late Cretaceous. The Hettangian Niranohama Fauna in northeastern Honshu represents the establishment of a heterodont-dominated brackish-water fauna that persisted until the early Late Cretaceous. No similar composition is known from the Triassic. The infauna consists mostly of non-siphonate and some short-siphonate heterodonts, while the epifauna is represented by diverse pteriomorphian families. In the Early Cretaceous Tetori Group in central Honshu, the long-siphonate heterodonts Tetoria (Corbiculidae) and the semi-infaunal soft-bottom oyster Crassostrea appeared. The evolutionary diversification of the latter, known as the most important element of modern brackish-water faunas, may thus originate at that time. In the early Late Cretaceous (Cenomanian) of the Goshoura and Mifune Groups in west Kyushu, several euryhaline deep-burrowing heterodont families, such as Veneridae and Tellinidae, further diversified in the brackish and marine environments. The Late Cretaceous is characterized by massive shell biolithic beds in which large Crassostrea species are common, a feature common for Cenozoic brackish-water faunas. The long-term changes in the composition of the brackish-water faunas in Japan represents thus an evolutionary record, irrespective of the severe physiological and environmental conditions imposed on the highly conservative nature of the fauna.     

Internal deformation of Sikhote Alin volcanic belt, far eastern Russia: Paleocene paleomagnetic results

We present paleomagnetic results of Paleocene welded tuffs of the 53–50 Ma Bogopol Group from the northern region (46°N, 137°E) of the Sikhote Alin volcanic belt. Characteristic paleomagnetic directions with high unblocking temperature components above 560 °C were isolated from all the sites. A tilt-corrected mean paleomagnetic direction from the northern region is D=345.8°, I=49.9°, α₉₅=14.6° (N=9). The reliability of the magnetization is ascertained through the presence of normal and reversed polarities. The mean paleomagnetic direction from the northern region of the Sikhote Alin volcanic belt reflects a counterclockwise rotation of 29° from the Paleocene mean paleomagnetic direction expected from its southern region. The counterclockwise rotation of 25° is suggested from the paleomagnetic data of the Kisin Group that underlies the Bogopol Group. These results establish that internal tectonic deformation occurred within the Sikhote Alin volcanic belt over the past 50 Ma. The northern region from 44.6° to 46.0°N in the Sikhote Alin volcanic belt was subjected to counterclockwise rotational motion through 29±17° with respect to the southern region. The tectonic rotation of the northern region is ascribable to relative motion between the Zhuravlevka terrane and the Olginsk–Taukhinsk terranes that compose the basements of the Sikhote Alin volcanic belt.     

Sensitivity Analysis of a Feedforward Neural Network for Considering Genetic Mechanisms of Kuroko Deposits

Exploration for volcanogenic massive sulfide deposits of the kuroko-type is underway in many places. Clarifying the spatial patterns of the metals in kuroko deposits will be useful for understanding their genetic mechanisms and for future exploration of such types of deposits. This study represents a spatial distribution analysis on the contents of principal metals of kuroko deposits: Cu, Pb, and Zn, in the Hokuroku district, northern Japan, by a feedforward neural network and 1917 sample data at 143 drillhole sites. The network, which consists of three layers, was trained by the principle of SLANS in which the numbers of neurons in the middle layer and training data are changed to improve estimation accuracy. Using the weight coefficients connecting adjacent neurons, sensitivity analysis of the neural network was carried out to identify factors influencing spatial distributions of the three metals. The coordinates depth (z) direction, Bouguer gravity, and specific lithology such as dacite were determined to be influencing factors. The high frequency of the z coordinate signifies that the metal contents differ to a large extent by depth. The sensitivity vector was defined using sensitivity coefficients for x, y, and z coordinates of an estimation point. We determined that the directions of large vectors were different inside and outside of the Hanawa-Ohdate area. This characteristic is considered to originate from the differences in the permeability of fractures that became the paths for rising ore solutions, and the depths that the solutions mixed with sea water.     

Jurassic Dextral and Cretaceous Sinistral Movements Along the Hida Marginal Belt

The Hida marginal belt (HMB), which consists of various kinds of fault-bound blocks, is located between the continental massif of the Hida belt and the Mesozoic accretionary complex of the Mino belt in Central Japan. Detailed field investigation reveals that the HMB had grown through the two different movements, i.e., Jurassic dextral and Cretaceous sinistral movements. The Jurassic dextral ductile shear zones run in the southern marginal part of the Hida belt and the northern part of the HMB, whereas the Cretaceous sinistral cataclastic shear zones occur in the southern part of the HMB and the northern marginal part of the Mino belt. Geologic map and field evidence seem to suggest that the Jurassic dextral movement form the fault-bound blocks of the HMB to form the basic structure of the Hida marginal belt, i.e., formation of the ‘proto-HMB.’ Following the dextral movement, the sinistral one restructured the ‘proto-HMB’ to complete the present feature of the Hida marginal belt. The Cretaceous sinistral movement might result in the sinistral collision between the proto-HMB and the Mino belt.