新疆希勒库都克铜钼矿区岩浆混合作用: 来自锆石U-Pb年代学的证据

新疆北部富蕴县内希勒库都克铜钼矿区的花岗闪长岩及其包体岩相学、矿物化学和岩石地球化学特征及野外地质特征显示其为岩浆混合作用的结果。本文获得花岗闪长岩及其中暗色微粒包体玄武安山玢岩、细粒辉长闪长岩锆石U-Pb年龄为326.8±2.1Ma、327.6±2.4Ma、329.3±2.3Ma,年龄值基本一致,这一结果从年代学角度为花岗闪长岩及其中暗色微粒包体的岩浆混合作用成因提供证据。偏酸性的花岗闪长质与偏基性玄武安山质岩浆混合作用形成了331.9±2.1Ma的安山玢岩脉。     

The Southwest Indian Ridge: Remelting the Gondwanan Mantle

<正>The Southwest Indian Ridge is an ultraslow spreading ridge(~14-mm/yr)that formed~150 Ma with the breakup of Gondwana.It extends 7700 km from the Bouvet to the Rodriguez Triple Junction,crossing over the flank of the large southern Geoid high centered over Marion and Crozet islands and the Conrad Rise.There is a     

Quaternary Antarctic Bottom-Water history: Deep-sea benthonic foraminiferal evidence from the southeast Indian Ocean

Distinct assemblages of Recent deep-sea benthonic foraminifera from the southeast Indian Ocean have been shown to be associated with Antarctic Bottom Water (AABW) and Indian Bottom Water (IBW). The AABW assemblage is divided into two groups. One is dominated by Epistominella umbonifera and is associated with AABW having temperatures between ?0.2° and 0.4°C. The second group is dominated by Globocassidulina subglobosa and is associated with AABW having temperatures between 0.6° and 0.8°C. The IBW assemblage is marked by the strong dominance of Uvigerina spp. and Epistominella exigua. The faunal-water-mass relationships have been used to infer the history of bottom-water circulation over the last 500,000 yr in this region using faunal data from four Eltanin cores. One core was taken from the Southeast Indian Ridge in association with IBW, and three were taken from the flank of the ridge associated with AABW flowing within a western boundary contour current in the South Australian Basin. Little faunal variation exists in the core beneath IBW (E48-22), indicating that IBW was present on the Southeast Indian Ridge during the last 300,000 yr. A record of the intensity of AABW circulation during the last 500,000 yr is inferred from the benthonic foraminiferal data in the three cores located within the western boundary contour current. Marked oscillations in the relative proportions of AABW and IBW faunal assemblages are found in one core, E48-03. The faunal variations are inferred to have resulted from variation in intensity of AABW circulation between 500,000 and 195,000 yr B.P. In E48-03, the AABW assemblage was present most of the time between 500,000 and 195,000 yr B.P., with low intensity of AABW circulation occurring primarily during the equivalent of stages 8 and 7 (t = 305,000 to 195,000 yr B.P.). The intensity of AABW circulation varied, with a maximum occurring during the equivalent of stage 11 (t = 420,000 yr B.P.). Two additional cores, E45-27 and E45–74, show relatively constant intensity of AABW circulation from 195,000 yr B.P. to the present. The intensity of AABW circulation at the present appears to be intermediate between a maximum during the equivalent of stage 11 (t = 420,000 yr B.P.) and the minimum during the equivalent of stage 8 (t = 275,000 yr B.P.). AABW production has occurred during both glacial and interglacial episodes. Bottom-water productivity has been suggested to play an important role in glacial/interglacial oscillations during the late Quaternary (Weyl, 1968; Newell, 1974). In this study, the relationship between bottom-water circulation and climatic fluctuations appears to be more complex than had been previously suggested, since a simple relationship between Quaternary bottom-water circulation and paleoclimatic fluctuations is not shown.     

Compositions of deep-sea ash layers derived from north pacific volcanic arcs: variations in time and space

Glass separates from 115 ash layers derived from the Kamchatkan (DSDP Site 192; 34 layers), the eastern Aleutian (DSDP Site 183; 56 layers) and the Alaska Peninsula (DSDP Site 178; 25 layers) volcanic arcs have been analyzed for up to 28 elements. In addition, the abundance and diversity of associated mafic phenocrysts have been evaluated. The resulting data set has made possible an evaluation of the late Miocene to Recent changes in composition of ashes derived from North Pacific volcanic arcs and of the factors controlling the evolution of highly siliceous magmas.We find no evidence for a general transition from arc tholeiite to calc-alkalic magma parentage of ashes derived from the volcanic arcs during the last 10 m.y., but instead find 0.1- to 0.5-m.y. intervals during which particular types of volcanism are prevalent. Most convincing is the transition from arc tholeiite to calc-alkalic for ashes derived from Kamchatka during the last 0.8 m.y., a change believed to be associated with a landward shift in the site of magma generation. Considered together, ashes derived from North Pacific volcanic arcs have been becoming more siliceous during the last 1.5 m.y. and may be associated with accelerated subduction during the same time interval.Hydrous phenocrysts (e.g., biotite) are typically associated with low-silica deep-sea ashes, but not with terrestrial volcanic rocks of comparable silica contents, suggesting the important role of water in the evolution of siliceous magma. REE patterns and relative abundances of mafic phenocrysts demonstrate the importance of fractional crystallization in controlling the evolution of highly siliceous arc magmas. REE increase with increasing silica, but become less concentrated in ashes with SiO₂ > 64%. Eu anomalies increase throughout the SiO₂ range. Initial fractionation is dominated by clinopyroxene and plagioclase with amphibole strongly influencing fractionation above 64% SiO₂.     

Benthonic foraminiferal faunal and isotopic data for the postglacial evolution of the Champlain Sea

Benthonic foraminiferal faunal and isotopic data from Champlain Sea sediments (approximately 12,500 to 10,000 yr B.P. in age) in two piston cores from Lake Champlain provide a detailed, apparently continuous record of the evolution of the Champlain Sea. Cassidulina reniforme and Islandiella helenae are the dominant benthonic foraminifera during the initial phase of the Champlain Sea, and are replaced by Elphidium excavatum forma clavatum and Protelphidium orbiculare as the dominant species during the remainder of the sea's history. The oxygen-isotopic data show a gradual decrease in δ¹⁸O between approximately 12,500 and 10,900 yr B.P., followed by a more rapid decrease during the interval 10,900 to 10,000 yr B.P. The δ¹³C data have a similar trend as δ¹⁸O, with generally decreasing values up the section. The isotopic and faunal data suggest that nearly marine conditions were present in the initial plase of the Champlain Sea, followed by gradually decreasing salinities and increasing temperatures as the sea evolved. The beginning of the rapid isotopic decrease at approximately 10,900 yr B.P. marks the onset of the largest environmental change in the history of the Champlain Sea, probably reflecting a major pulse of meltwater from the Laurentide Ice Sheet.     

On the formation of metal-rich deposits at ridge crests

Data from the hot springs at the Galapagos spreading center (T = 3–13°C) show depletions of the exiting waters in Cu, Ni, Cd, Se, Cr and U relative to ambient seawater. Manganese is strongly enriched. Iron shows highly variable behavior between vent fields but is in general low. The data confirm the occurrence of extensive subsurface mixing between the primary high-temperature, acid, reducing hydrothermal fluids and “groundwater”. The composition of the latter is indistinguishable from that of the free water column adjacent to the ridge axis. The final solutions are on the boundary between those forming MnO₂ crusts and those producing iron-manganese rich sediments. The suite of metal rich deposits observed at ridge crests — Mn-O, Fe-Mn-O, Fe-S — can be explained as the manifestation of the degree of subsurface mixing, decreasing from 100 : <1 to <1 : 1 across the series (assuming an end-member temperature of 350°C).     

Lattice dynamics and inelastic neutron scattering from forsterite,Mg2SiO4: Phonon dispersion relation,density of states and specific heat

Magnesium-rich olivine (Mg_0.9Fe_0.1)₂SiO₄ is considered to be a major constituent of the Earth's upper mantle. Because of its major geophysical importance, the temperature and pressure dependence of its crystal structure, elastic and dielectric constants, long-wavelength phonon modes and specific heat have been measured using a variety of experimental techniques. Theoretical study of lattice dynamics provides a means of analyzing and understanding a host of such experimental data in a unified manner. A detailed study of the lattice dynamics of forsterite, Mg₂SiO₄, has been made using a crystal potential function consisting of Coulombic and short-range terms. Quasiharmonic lattice dynamical calculations based on a rigid molecular-ion model have provided theoretical estimates of elastic constants, long-wavelength modes, phonon dispersion relation for external modes along the three high symmetry directions in the Brillouin zone, total and partial density of states and inelastic neutron scattering cross-sections. The neutron cross-sections were used as guides for the coherent inelastic neutron scattering experiment on a large single crystal using a triple axis spectrometer in the constant Q mode. The observed and predicted phonon dispersion relation show excellent agreement. The inelastically scattered neutron spectra from a powder sample have been analyzed on the basis of a phonon density of states calculated from a rigid-ion model, which includes both external and internal modes. The experimental data from a powder sample show good agreement with the calculated spectra, which include a multiphonon contribution in the incoherent approximation. The computed phonon densities of states are used to calculate the specific heat as a function of temperature using both the rigid molecular-ion and rigid ion models. These results are in very good agreement with the calorimetric measurement of the specific heat. The interatomic potential developed here can be used with some confidence to study physical properties of forsterite as a function of pressure and temperature.     

The chemistry of hydrothermal mounds near the Galapagos Rift

Samples dredged from the sediment mounds have a unique chemistry and mineralogy which reveals details of the hydrothermal processes that produce these deposits. The mounds form primarily by deposition of Fe, Mn and Si from hydrothermal fluids which circulate through the basalt crust and the overlying sediments. The Mn, Fe and Si are strongly fractionated in the process; the Fe and Si precipitate within the mounds under slightly reducing conditions as nontronite, while the Mn is deposited as Mn oxyhydroxides at the seawater-sediment interface. The nontronite is exceptionally well crystallized, and contains less than 200 ppm Al. The Mn minerals, todorokite and birnessite, also have exceptional crystallinity and the distribution of trace elements Cu, Ni, Zn, Co, Ca and Ba in these phases agrees with predictions made on the basis of models of their crystal structure. The environment of deposition which produces this suite of minerals — slow percolation of hydrothermal fluids through pelagic sediments — may not be unique to the Galapagos Rift, as the same suite of minerals has been found in similar setting in the Gulf of Aden and on the Mid-Atlantic Ridge.     

History of metalliferous sedimentation at deep sea drilling site 319 in the South Eastern Pacific

Marked variations in the chemical and mineralogical composition of sediments at Site 319 have occurred during the 15 M.y. history of sedimentation at this site. The change in composition through time parallels the variability observed in surface sediments from various parts of the Nazca Plate and can be related to variations in the proportion of hydrothermal, hydrogenous, detrital and biogenous phases reaching this site at different times. Metal accumulation rates at Site 319 reach a maximum near the basement for most elements, suggesting a strong hydrothermal contribution during the early history of this site. The hydrothermal contribution decreased rapidly as Site 319 moved away from the spreading center, although a subtle increase in this source is detectable about the time spreading began on the East Pacific Rise. The most recent sedimentation exhibits a strong detritalhydrogenous influence. Post-depositional diagenesis of amorphous phases has converted them to ironrich smectite and well-crystallized goethite without significantly altering the bulk composition of the sediment.     

Characteristics and landcover of estuarine boundaries: implications for the delineation of the South African estuarine functional zone

This study investigated whether the current lateral boundary for estuaries in South Africa, i.e. the estuarine functional zone (EFZ), includes all estuarine habitats. The EFZ covers 173 930 ha in 304 estuaries/outlets nationally. Field surveys and analysis of available aerial images showed that 82 (12 956.70 ha) of these estuaries (26%) had estuarine habitats occurring outside of this boundary. As a result of mapping scale, the National Vegetation Map does not represent habitats that are associated with small estuaries (approximately 50% of South Africa's estuaries). For estuaries in the Western and Eastern Cape provinces, most habitats have been lost due to urban development, whereas in subtropical areas (northern Eastern Cape and KwaZulu-Natal), cultivation has removed estuarine habitat. Although delineation of boundaries can be complicated by landcover changes, the estuarine lateral boundary in Cape estuaries could be identified based on sediment characteristics (moisture content, organic content, electrical conductivity), groundwater characteristics (salinity, conductivity and depth) and plant species. The delineation of the EFZ needs to be consistent, inclusive of all estuarine physical and biological processes, and cost-effective to identify so that it can protect estuarine habitats.