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1.
The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2 总被引:2,自引:1,他引:1
Josep M. Soler Marco Boi Jos Luis Mogolln Jordi Cama Carlos Ayora Peter S. Nico Nobumichi Tamura Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions. 相似文献
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A new method which produces energy from the ocean by utilizing the density difference of water, by means of a “chimney effect”, is proposed. Density difference of water in the ocean occurs in two ways, namely differences of consistency and water temperature. For instance, fresh river and melting floes and icebergs are pointed out as some origins of the former, while thermal effects of volcanoes and hot springs may account for the latter. Furthermore, sunlight power transmitted into the sea through glass fibre power lines can be an artificial source in the latter case.This paper concentrates on regions near estuaries where low density river water can be piped into the high density ocean. An analysis estimates that the proposed method extracts energy of several thousands or more kW in the above case. 相似文献
4.
Full-range equation covering all the flow regimes in a wave boundary layer is proposed for the boundary layer thickness. The results are compared with the available experimental data and good agreement has been found. In case of wave boundary layers, there are three definitions of boundary layer thickness in use. Therefore, the full-range equation is derived for three of the definitions. The findings of this study may be useful in calculating suspended sediment transport in coastal environments and studying wave–current combined motion. 相似文献
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Numerical integration of the gravitational N-body problem has been carried out for a variety of photoplanetary clusters in the range N = 100 to 200. Particles are assumed to coagulate at collisions irrespective of relative velocity and mass ratio of the particles. It is shown graphically how the dispersed N-bodies accumulate to a single planet through mutual collisions. The velocity distribution and size distribution of bodies are also investigated as functions of time in the accretion process. The root mean square velocity of bodies in a cluster increases with time in an early stage of accretion but decreases with time in a late stage of accretion. Accretion rates of planets are found to be dependent strongly on the initial number density distribution, the initial size distribution, and the initial velocity distribution of bodies. Formation of satellites of about 10% in the planet mass is common to most cases in the present study. A substantial mass of bodies also escapes from the cluster. Many satellites and escapers formed during the accretion process of planets may be source materials of heavy bombardment in the early history of planets. 相似文献
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Non-volcanic deep low-frequency tremors accompanying slow slips in the southwest Japan subduction zone 总被引:5,自引:1,他引:5
Non-volcanic deep low-frequency tremors in southwest Japan exhibit a strong temporal and spatial correlation with slow slip detected by the dense seismic network. The tremor signal is characterized by a low-frequency vibration with a predominant frequency of 0.5–5 Hz without distinct P- or S-wave onset. The tremors are located using the coherent pattern of envelopes over many stations, and are estimated to occur near the transition zone on the plate boundary on the forearc side along the strike of the descending Philippine Sea plate. The belt-like distribution of tremors consists of many clusters. In western Shikoku, the major tremor activity has a recurrence interval of approximately six months, with each episode lasting over a week. The tremor source area migrates during each episode along the strike of the subducting plate with a migration velocity of about 10 km/day. Slow slip events occur contemporaneously with this tremor activity, with a coincident estimated source area that also migrates during each episode. The coupling of tremor and slow slip in western Shikoku is very similar to the episodic tremor and slip phenomenon reported for the Cascadia margin in northwest North America. The duration and recurrence interval of these episodes varies between tremor clusters even on the same subduction zone, attributable to regional difference in the frictional properties of the plate interface. 相似文献
8.
Masao Komazawa Hitoshi Morikawa Kajuro Nakamura Junpei Akamatsu Keiichi Nishimura Sumio Sawada Ayfer Erken Akin Onalp 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):829-836
The 1999 Kocaeli earthquake brought serious damage to downtown of Adapazari. To study why strong motions were generated at the town, a bedrock structure was investigated on the basis of Bouguer gravity anomaly, and SPAC and H/V analyses of microseisms. It was revealed that, the basin consists of three narrow depressions of bedrock with very steep edges, extending in E–W or NE–SW directions along the North Anatolia faults, and the depth to bedrock reaches 1000 m or more. Downtown of Adapazari is located 1–2 km apart from the basin-edge. It is considered that, the specific configuration of bedrock amplifies ground motions at the downtown area by focusing of seismic waves and/or interference between incident S-waves and surface-waves secondarily generated at the basin-edge. Studying 3D bedrock structure is an urgent issue for microzoning an urban area in a sedimentary basin. 相似文献
9.
Hiroshi Kobayashi Keiichi Tamura Shunsuke Tanimoto 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1135-1141
In order to improve seismic design technology of bridges, it is necessary to evaluate the vibration characteristics of a bridge–soil system that consists of soil, foundation structure, pier and superstructure. However, there have been few experimental studies on seismic behavior of bridge–soil system. In this paper, we conducted the hybrid vibration experiment on seismic behavior of bridge–soil system, and examined the applicability of hybrid vibration experiment to study seismic response of bridge–soil system. Based on the experiment results, seismic response of bridge was quantitatively studied. 相似文献
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