Application of a fluorescent technique to the study of the weathering process

Processes and rates of weathering in representative tuff obtained from a Green Tuff region were directly examined using a new fluorescent approach. This approach was developed to visualize microscopically the microcracks and micropores that contribute to deterioration. The following observations were made. Progression of tuff weathering is caused by a delicate balance between chemical alteration and physical disintegration. Weathering occurs in many hidden microcracks and micropores not detected under natural light, but which can be clearly visualized under ultraviolet light. Water pathways, such as microcracks and cavities, accelerated the chemical alteration by increasing the effective surface area of rocks in contact with water. As the reaction proceeds, the constituent materials loosen and alteration products become widespread in the matrix. Secondary amorphous to poorly crystallized materials, such as iron hydroxide and aluminosilicate, precipitate on the fracture surfaces, slowing the progress of weathering. At the ultimate stage of weathering in tuff, all cracks and most of the micropores are filled with secondary materials. These observations on a microscopic scale during tuff weathering agree with the assessment of weathering obtained by measuring porosity, P-wave velocity and tensile strength.     

An experimental study on felsic rock–artificial seawater interaction: implications for hydrothermal alteration and sulfate formation in the Kuroko mining area of Japan

Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlier (devitrification stage) and later smectite formation, whereas Ca incorporated with early smectite formation redissolves with progressive reaction. Barium mobility increases toward the later smectite-forming reactions. Therefore, the large amounts of barite, anhydrite and gypsum in Kuroko ore deposits are considered to have precipitated from hydrothermal solutions derived from the interaction with previously altered felsic rocks during late smectite formation, rather than by the reaction with fresh felsic rocks.Editorial handling: D. Lentz     

Diffuse Emission of CO2 from Showa-Shinzan, Hokkaido, Japan: A Sign of Volcanic Dome Degassing

Two soil CO₂ efflux surveys were carried out in September 1999 and June 2002 to study the spatial distribution of diffuse CO₂ degassing and estimate the total CO₂ output from Showa-Shinzan volcanic dome, Japan. Seventy-six and 81 measurements of CO₂ efflux were performed in 1999 and 2002, respectively, covering most of Showa-Shinzan volcano. Soil CO₂ efflux data showed a wide range of values up to 552 g m^-2 d^-1. Carbon isotope signatures of the soil CO₂ ranged from -0.9‰ to -30.9‰, suggesting a mixing between different carbon reservoirs. Most of the study area showed CO₂ efflux background values during the 1999 and 2002 surveys (B = 8.2 and 4.4 g m^-2 d^-1, respectively). The spatial distribution of CO₂ efflux anomalies for both surveys showed a good correlation with the soil temperature, indicating a similar origin for the extensive soil degassing generated by condensation processes and fluids discharged by the fumarolic system of Showa-Shinzan. The total diffuse CO₂ output of Showa-Shinzan was estimated to be about 14.0–15.6 t d^-1 of CO₂ for an area of 0.53 km².     

A model not requiring continuous lithosphere for anomalous high-frequency arrivals from deep-focus South American earthquakes

Various workers have constructed models to explain a class of anomalous arrivals at Peruvian and Chilean stations from deep-focus South American earthquakes. These arrivals are shear waves with a later arrival time, a higher frequency content, a longer duration and a lower apparent velocity than direct S. Our models assume that there is a sufficiently sharp discontinuity at the upper interface of the descending lithospheric slab between depths of 80 and 250 km to provide efficient reflection (≈0.1) for S-waves incident from below. The observed travel times require a single S-to-S reflection at this interface if the J-B velocity-depth model is modified to allow for 7% higher velocities down to a depth of 300 km (excluding the crust). The locus of required reflection points correlates well with the upper boundary of the observed seismicity (strike and dip angles within 5°) and Q for the proposed path is consistent with the frequency content of the anomalous arrivals. Thus the existence of these arrivals requires a dipping interface down to about 250 km, but, contrary to the wave-guide model of Isacks and Barazangi, cannot be used to infer a continuous lithospheric slab down to the deep-focus earthquakes (h #62; 500 km).     

Research note: deblended-data reconstruction using generalized blending and deblending models

We introduce a concept of generalized blending and deblending, develop its models and accordingly establish a method of deblended-data reconstruction using these models. The generalized models can handle real situations by including random encoding into the generalized operators both in the space and time domain, and both at the source and receiver side. We consider an iterative optimization scheme using a closed-loop approach with the generalized blending and deblending models, in which the former works for the forward modelling and the latter for the inverse modelling in the closed loop. We applied our method to existing real data acquired in Abu Dhabi. The results show that our method succeeded to fully reconstruct deblended data even from the fully generalized, thus quite complicated blended data. We discuss the complexity of blending properties on the deblending performance. In addition, we discuss the applicability to time-lapse seismic monitoring as it ensures high repeatability of the surveys. Conclusively, we should acquire blended data and reconstruct deblended data without serious problems but with the benefit of blended acquisition.     

Mobility-dependent response of aquatic animal species richness to a wetland network in an agricultural landscape

Management of wetland connectivity is important for biodiversity conservation. In the modern agricultural landscape, the natural connections between floodplain wetlands have been greatly altered. Agricultural ditches and channelized streams are widely distributed in floodplains, which may contribute to the maintenance of wetland connectivity and biodiversity. To determine how these watercourse networks affect wetland biodiversity, we examined the relationship between the species richness of aquatic animals and wetland connectivity, with a special focus on species mobility. From July to August 2011, fish and aquatic insects were collected from 24 wetlands in northern Japan. To determine the degree of wetland connectivity, we assessed the relative importance of individual wetlands in maintaining the entire wetland network using two connectivity indices: hydrologic connectivity via watercourses and spatial connectivity defined as Euclidian distances between wetlands using graph theory. We found that only high mobility groups of both taxa could enhance species richness in either a hydrologic (fish) or spatial (insect) wetland network. The species richness of insects with high-flying ability was found to increase as spatial connectivity increased. Furthermore, the species richness of fish with high-swimming ability was positively influenced by hydrologic connectivity, most likely because highly mobile species were able to reach suitable habitats and migrate from source populations in a wetland network owing to their good mobility. Our findings indicate that hydrologic network is important for maintaining biodiversity as well as spatial connectivity. It is important to focus conservation efforts on key wetlands with high hydrologic and spatial connectivity in future wetland management.     

Study on the selection of unsaturated flow model for the different types of soil and soft rock

Precise estimation of unsaturated hydraulic properties of porous media is indispensable in various study areas, such as analyzing the moisture flow, the drying process occurring from the surface, and the pollutant migration beneath the ground surface. Although many empirical/theoretical models describing the unsaturated hydraulic properties have been proposed by several previous researchers, the best model for the different types of soil/rock may not be identical. Thus, the model selection process and the estimation technique of the parameters included in the models should be developed. In the present study, the inverse technique based on the transient evaporation change was investigated to select the model and estimate the model parameters. The experimental work was based on a relatively low permeable soft rock and a relatively high permeable sandy soil (Toyoura standard sand). Experimental equipment was developed to precisely measure the evaporation rate for the high permeable sandy soil. The Genetic Algorithm (GA) was adopted in the inverse technique as an optimization tool. In order to simplify the problem, only the drying process from the saturated condition was considered. It was established that the information concerning the transient evaporation change could be used for the model selection and parameter estimation. Further, the saturation distribution could be used for the selection of the models. The present study provides important information for the development of the model selection process.     

Characteristics of Triassic epithermal Au mineralization at the Q prospect,Chatree mining area,Central Thailand

The Chatree deposit is located in the Loei‐Phetchabun‐Nakhon Nayok volcanic belt that extends from Laos in the north through central and eastern Thailand into Cambodia. Gold‐bearing quartz veins at the Q prospect of the Chatree deposit are hosted within polymictic andesitic breccia and volcanic sedimentary breccia. The orebodies of the Chatree deposit consist of veins, veinlets and stockwork. Gold‐bearing quartz veins are composed mainly of quartz, calcite and illite with small amounts of adularia, chlorite and sulfide minerals. The gold‐bearing quartz veins were divided into five stages based on the cross‐cutting relationship and mineral assemblage. Intense gold mineralization occurred in Stages I and IV. The mineral assemblage of Stages I and IV is characterized by quartz–calcite–illite–laumontite–adularia–chlorite–sulfide minerals and electrum. Quartz textures of Stages I and IV are also characterized by microcrystalline and flamboyant textures, respectively. Coexistence of laumontite, illite and chlorite in the gold‐bearing quartz vein of Stage IV suggests that the gold‐bearing quartz veins were formed at approximately 200°C. The flamboyant and brecciated textures of the gold‐bearing quartz vein of Stage IV suggest that gold precipitated with silica minerals from a hydrothermal solution that was supersaturated by boiling. The δ¹⁸O values of quartz in Stages I to V range from +10.4 to +11.6‰ except for the δ¹⁸O value of quartz in Stage IV (+15.0‰). The increase in δ¹⁸O values of quartz at Stage IV is explained by boiling. P_H2O is estimated to be 16 bars at 200°C. The f_CO2 value is estimated to be 1 bar based on the presence of calcite in the mineral assemblage of Stage IV. The total pressure of the hydrothermal solution is approximately 20 bars at 200°C, suggesting that the gold‐bearing quartz veins of the Q prospect formed about 200 m below the paleosurface.     

满洲里-新巴尔虎右旗斑岩系列矿床石英流体包裹体液相组分的PIXE分析和地质应用

ＰＩＸＥ（质子感应Ｘ射线分析）方法是目前国际上新的流体包裹体成分分析方法。在前人工作的基础上,尝试用ＰＩＸＥ方法分析了满洲里－新巴尔虎右旗斑岩系列多金属矿床石英流体包裹体的液相多元素化学组分,其结果反映了地质矿化规律。该方法对于多金属矿床石英流体包裹体成分研究非常有用。结合其他包裹体研究,提出甲乌拉与直干布拉根矿床流体组分和成矿物理化学条件均不同,初步认为不存在同一矿化中心;还提出了查干布拉根矿床西矿段深部可能存在乌奴格吐山式斑岩型Ｃｕ矿床,应引起注意。