Pore-water pressure development in a frozen saline clay under isotropic loading and undrained shearing

Acta Geotechnica - A systematical testing program on frozen Onsøy clay under isotropic loading and undrained shearing at different temperatures...     

New developments with design and construction of a thermal/vacuum qualified photogrammetric system

In the frame of the development of a photogrammetric system to be used in thermal/vacuum chambers at the European Space Research and Technology Centre (ESTEC) of European Space Agency (ESA) and other sites across Europe, the design of a network using micro-cameras was specified by ESA-ESTEC. A thermal/vacuum qualified photogrammetric system, which is able to work and acquire images in vacuum and at cryo-temperatures, was constructed by ESA-ESTEC Test Centre Division. The current system uses four space qualified one-mega pixel cameras and is able to measure large space structures in vacuum and at temperatures down to ?170 ^°C with a global accuracy better than 1 part per 100,000 in object space. Several tests aiming at the qualification of the sensors and system in terms of operation and accuracy have been carried out. Special measures have been developed and special attention has been taken into account specifically for the first application of the photogrammetric system. It is to verify the ESA’s Herschel Telescope Flight Model alignment positioning.     

Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.     

Kinetic and equilibrium study of Ni(II) sorption from aqueous solutions onto Peganum harmala-L

In this study, the adsorption behavior of Ni(II) in an aqueous solution system using natural adsorbent Peganum harmala-L was measured via batch mode. The prepared sorbent was characterized by scanning electron microscope, Fourier transform infrared spectroscopy, N₂ adsorption–desorption and pH_zpc. Adsorption experiments were carried out by varying several conditions such as contact time, metal ion concentration and pH to assess kinetic and equilibrium parameters. The equilibrium data were analyzed based on the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms. Kinetic data were analyzed using the pseudo-first-order, pseudo-second-order and intra-particular diffusion models. Experimental data showed that at contact time 60 min, metal ion concentration 50 mg/L and pH 6, a maximum amount of Ni(II) ions can be removed. The experimental data were best described by the Langmuir isotherm model as is evident from the high R ² value of 0.988. The adsorption capacity (q _m) obtained was 68.02 mg/g at an initial pH of 6 and a temperature of 25 °C. Kinetic studies of the adsorption showed that equilibrium was reached within 60 min of contact and the adsorption process followed the pseudo-first-order model. The obtained results show that P. harmala-L can be used as an effective and a natural low-cost adsorbent for the removal of Ni(II) from aqueous solutions.     

Geodynamic Evolution of Northeastern Tunisia During the Maastrichtian–Paleocene Time: Insights from Integrated Seismic Stratigraphic Analysis

The Maastrichtian–Paleocene El Haria formation was studied and defined in Tunisia on the basis of outcrops and borehole data; few studies were interested in its three-dimensional extent. In this paper, the El Haria formation is reviewed in the context of a tectono-stratigraphic interval using an integrated seismic stratigraphic analysis based on borehole lithology logs, electrical well logging, well shots, vertical seismic profiles and post-stack surface data. Seismic analysis benefits from appropriate calibration with borehole data, conventional interpretation, velocity mapping, seismic attributes and post-stack model-based inversion. The applied methodology proved to be powerful for charactering the marly Maastrichtian–Paleocene interval of the El Haria formation. Migrated seismic sections together with borehole measurements are used to detail the three-dimensional changes in thickness, facies and depositional environment in the Cap Bon and Gulf of Hammamet regions during the Maastrichtian–Paleocene time. Furthermore, dating based on their microfossil content divulges local and multiple internal hiatuses within the El Haria formation which are related to the geodynamic evolution of the depositional floor since the Campanian stage. Interpreted seismic sections display concordance, unconformities, pinchouts, sedimentary gaps, incised valleys and syn-sedimentary normal faulting. Based on the seismic reflection geometry and terminations, seven sequences are delineated. These sequences are related to base-level changes as the combination of depositional floor paleo-topography, tectonic forces, subsidence and the developed accommodation space. These factors controlled the occurrence of the various parts of the Maastrichtian–Paleocene interval. Detailed examinations of these deposits together with the analysis of the structural deformation at different time periods allowed us to obtain a better understanding of the sediment architecture in depth and the delineation of the geodynamic evolution of the region.     

Extraction of forward-directivity velocity pulses using S-Transform-based signal decomposition technique

Robust methods for time-frequency analysis of time series, which provide local information of signals, allow earthquake engineers to study both the input and output of dynamic time history analysis with more reliability. Moreover, time-frequency representations (TFRs) have a major role in the analysis of non-stationary seismic signals exhibiting significant time variation of frequency content. S-Transform (ST) is a modern TFR, which can measure local characteristics of a signal such as amplitude, frequency, and phase at any time instant. This paper presents a new method for decomposition of ground motion signals. A modified version of ST-based technique, originally employed to decompose signals of gearbox vibration, is introduced and applied to the extraction and characterization of pulse-like part of near-fault velocity records, which is contributed to the directivity effects. In addition, a new definition based on ST analysis is used to identify pulse period. The results of implementation of proposed procedure on a database of pulse-like ground motion recordings belonging to the different ranges of magnitude demonstrate the efficiency of proposed method compared with other available approaches. The results, also, indicate that simple approximation of distinct pulses using single-period waveforms, unlike the extracted pulses, cannot represent the impulsive nature of real records adequately.     

Dominant pulse simulation of near fault ground motions

In this study, a new mathematical model is developed composed of two parts, including harmonic and polynomial expressions for simulating the dominant velocity pulse of near fault ground motions. Based on a proposed velocity function, the corresponding expressions for the ground acceleration and displacement time histories are also derived. The proposed model is then fitted using some selected pulse-like near fault ground motions in the Next Generation Attenuation (NGA) project library. The new model is not only simple in form but also simulates the long-period portion of actual velocity near fault records with a high level of precision. It is shown that the proposed model-based elastic response spectra are compatible with the near fault records in the neighborhood of the prevailing frequency of the pulse. The results indicate that the proposed model adequately simulates the components of the time histories. Finally, the energy of the proposed pulse was compared with the energy of the actual record to confirm the compatibility.     

Resonantly damped oscillations of elliptically shaped stratified emerging coronal loops

The effects of both elliptical shape and stage of emergence of the coronal loop on the resonant absorption of standing kink oscillations are studied. To do so, a typical coronal loop is modeled as a zero-beta longitudinally stratified cylindrical magnetic flux tube. We developed the connection formulae for the resonant absorption of standing transversal oscillations of a coronal loop with an elliptical shape, at various stages of its emergence. Using the connection formulae, the dispersion relation is derived and solved numerically to obtain the frequencies and damping rates of the fundamental and first-overtone kink modes. Our numerical results show that both the elliptical shape and stage of emergence of the loop alter the frequencies and damping rates of the tube as well as the ratio of frequencies of the fundamental and its first-overtone modes. However, the ratio of the oscillation frequency to the damping rate is not affected by the tube shape and stage of its emergence and also is independent of the density stratification parameter.     

Non-adiabatic interactions in excitedC 2 H molecules and their relationship toC 2 formation in comets

A unified picture of the photodissociation of theC ₂ H radical has been developed using the results from the latest experimental and theoretical work. This picture shows that a variety of electronic states ofC ₂ are formed during the photodissociation of theC ₂ H radical even if photoexcitation accesses only one excited state. This is because the excited states have many avoided corssings and near intersections where two electronic states come very close to one another. At these avoided crossings and near intersections, the excited radical can hop from one electronic state to another and access new final electronic states of theC ₂ radical. The complexity of the excited state surfaces also explains the bimodal rotational distributions that are observed in all of the electronic states studied. The excited states that dissociate through a direct path are limited by dynamics to produceC ₂ fragments with a modest amount of rotational energy, whereas those that dissociate by a more complex path have a greater chance to access all of phase space and produce fragments with higher rotational excitation. Finally, the theoretical transition moments and potential energy curves have been used to provide a better estimate of the photochemical lifetimes in comets of the different excited states of theC ₂ H radical. The photochemically active states are the 2²₊, 2²II, 3²II, and 3²₊, with photodissociation rate constants of 1.0×10^–6, 4.0×10^–6, 0.7×10^–6, and 1.3×10^–6s^–1, respectively. These rate constants lead to a total photochemical lifetime of 1.4×10⁵ s.     

Chloride transfer in cement‐based materials. Part 1. Theoretical basis and modelling

In this first part of the work, we develop macroscopic models for migration and diffusion–migration of ionic species in saturated porous media, based on periodic homogenization. The prior application is chloride transport in cementitious materials. The dimensional analysis of Nernst–Planck equation lets appear to dimensionless numbers characterizing the ionic transfer in the porous medium. Using experimental data obtained from electrodiffusion tests on cement‐based materials (Part II), these dimensionless numbers are linked to the perturbation parameter ?. For a strong imposed electrical field, the asymptotic expansion of Nernst–Planck equation leads to a macroscopic model where the migration is predominant. For a weak imposed electrical field or in natural diffusion, we obtain a macroscopic model coupling diffusion and migration at the same order. In both models, the expression of the homogenized diffusion tensor is identical and only involves the geometric properties of the material microstructure. Copyright © 2012 John Wiley & Sons, Ltd.