Fluid entrapment and reequilibration during subduction and exhumation: A case study from the high-grade Nestos shear zone, Central Rhodope, Greece

A fluid inclusion study on metamorphic minerals of successive growth stages was performed on highly deformed paragneisses from the Nestos Shear Zone at Xanthi (Central Rhodope), in which microdiamonds provide unequivocal evidence for ultrahigh-pressure (UHP) metamorphism. The correlation of fluid inclusion density isochores and fluid inclusion reequilibration textures with geothermobarometric data and the relative chronology of micro- and macro-scale deformation stages allow a better understanding of both the fluid and metamorphic evolution along the P–T–d path. Textural evidence for subduction towards the NE is recorded by the orientation of intragranular NE-oriented fluid inclusion planes and the presence of single, annular fluid inclusion decrepitation textures. These textures occur within quartz “foam” structures enclosed in an earlier generation of garnets with prolate geometries and rarely within recrystallized matrix quartz, and reequilibrated both in composition and density during later stages of exhumation. No fluid inclusions pertaining to the postulated ultrahigh-pressure stage for microdiamond-bearing garnet–kyanite–gneisses have yet been found. The prolate shape of garnets developed during the earliest stages of exhumation that is recorded structurally by (L  S) tectonites, which subsequently accommodated progressive ductile SW shearing and folding up to shallow crustal levels. The majority of matrix kyanite and a later generation of garnet were formed during SW-directed shear under plane-strain conditions. Fluid inclusions entrapped in quartz during this stage of deformation underwent density loss and transformed to almost pure CO₂ inclusions by preferential loss of H₂O. Those inclusions armoured within garnet retained their primary 3-phase H₂O–CO₂ compositions. Reequilibration of fluid inclusions in quartz aggregates is most likely the result of recrystallization along with stress-induced, preferential H₂O leakage along dislocations and planar lattice defects which results in the predominance of CO₂ inclusions with supercritical densities. Carbonic fluid inclusions from adjacent kyanite–corundum-bearing pegmatoids and, the presence of shear-plane-parallel fluid inclusion planes within late quartz boudin structures consisting of pure CO₂-fluid inclusions with negative crystal shapes, bear witness of the latest stage of deformation by NE-directed extensional shear.This study shows that the textures of early fluid inclusions that formed already during the prograde metamorphic path can be preserved and used to derive information about the kinematics of subduction that is difficult to obtain from other sources. The textures of early inclusions, together with later generations of unaltered primary and secondary inclusions in metamorphic index minerals that can be linked to specific deformation stages and even P–T conditions, are a welcome supplement for the reconstruction of a rather detailed P–T–d path.     

Quaternary geology of the Amazonian Lowland

The Quaternary history of the Amazon lowlands is characterized by deposition of sediments of Andean provenance and by the influences of changing sea levels. Areas well above the present water tables were not reached by Pleistocene high-water stages. These areas have been intensively weathered since the Tertiary, forming hard lateritic weathering horizons. These weathering horizons are best explained by the relatively constant, humid tropical climate throughout the Quaternary. In the western Amazonian Lowland, flood plains corresponding to the different Pleistocene sea-level heights were formed. During low sea level, erosion in the drainage areas increased and the water levels of the central Amazon River system were lowered. Valleys drowned and lakes formed in the lower reaches of rivers and creeks during high sea-level stages. These lakes (ria lakes) remained in the valleys with rivers having a low sediment load. Seismic profiling (3.5 kHz) in some of these lakes clearly showed deposits of the three last periods of Quaternary high sea-level stages.     

Winter-spring phytoplankton blooms in Dabob Bay, Washington

Scientific investigations in Dabob Bay, Washington State, USA, have been extensive since the early 1960s, but phytoplankton blooms have been studied mostly with regard to chlorophyll concentrations and little is known about the phytoplankton species themselves. Here we provide information on the species present, their abundances during blooms, their contribution to organic carbon concentrations and the ability of some phytoplankton species to produce toxic aldehydes that may impact metazoan grazers.Multiple blooms of phytoplankton, dominated by diatoms, occurred in the late winter-early spring period, with depth-integrated chlorophyll levels ranging from <20 to 230 mg m⁻² and peaks in February and April. The major bloom species included Skeletonema costatum, Thalassiosira spp. and Chaetoceros spp; Phaeocystis cf. pouchetii occurred in 2002 and 2004. Other taxa or groups of organisms that were sometimes abundant included unidentified small flagellates <10 μm in size and unidentified heterotrophic dinoflagellates. Large diatoms usually comprised most of the cell carbon, but a large, heterotrophic dinoflagellate, identified only as Gyrodinium “tear” because of its shape, was a major contributor to the microplankton carbon when present even in small numbers. Five Thalassiosira species and S. costatum were found to produce polyunsaturated aldehydes (PUA) that are known to affect copepod reproduction and hatching success. Our findings are similar to the few previous studies in the last four decades that included phytoplankton species and suggest long-term similarities and relative stability in the phytoplankton species present and their timing in Dabob Bay.     

Fast static correction methods for high-frequency multichannel marine seismic reflection data: A high-resolution seismic study of channel-levee systems on the Bengal Fan

Very high-frequency marine multichannel seismic reflection data generated by small-volume air- or waterguns allow detailed, high-resolution studies of sedimentary structures of the order of one to few metres wavelength. The high-frequency content, however, requires (1) a very exact knowledge of the source and receiver positions, and (2) the development of data processing methods which take this exact geometry into account. Static corrections are crucial for the quality of very high-frequency stacked data because static shifts caused by variations of the source and streamer depths are of the order of half to one dominant wavelength, so that they can lead to destructive interference during stacking of CDP sorted traces. As common surface-consistent residual static correction methods developed for land seismic data require fixed shot and receiver locations two simple and fast techniques have been developed for marine seismic data with moving sources and receivers to correct such static shifts. The first method – called CDP static correction method – is based on a simultaneous recording of Parasound sediment echosounder and multichannel seismic reflection data. It compares the depth information derived from the first arrivals of both data sets to calculate static correction time shifts for each seismic channel relative to the Parasound water depths. The second method – called average static correction method – utilises the fact that the streamer depth is mainly controlled by bird units, which keep the streamer in a predefined depth at certain increments but do not prevent the streamer from being slightly buoyant in-between. In case of calm weather conditions these streamer bendings mainly contribute to the overall static time shifts, whereas depth variations of the source are negligible. Hence, mean static correction time shifts are calculated for each channel by averaging the depth values determined at each geophone group position for several subsequent shots. Application of both methods to data of a high-resolution seismic survey of channel-levee systems on the Bengal Fan shows that the quality of the stacked section can be improved significantly compared to stacking results achieved without preceding static corrections. The optimised records show sedimentary features in great detail, that are not visible without static corrections. Limitations only result from the sea floor topography. The CDP static correction method generally provides more coherent reflections than the average static correction method but can only be applied in areas with rather flat sea floor, where no diffraction hyperbolae occur. In contrast, the average static correction method can also be used in regions with rough morphology, but the coherency of reflections is slightly reduced compared to the results of the CDP static correction method.     

A note on the extremal properties of the morison equation

The extremal properties of the Morison equation F(t) = X′(t) + X(t)|X(t)|; for the force on a circular pile in a fluid, are derived by means of a Slepian model for the behaviour of X(t) around its local maxima. The behaviour of X′(t) near large maxima of X(t) is almost deterministic, and hence there is a simple relation between the maxima in X(t) and those in F(t).     

Differential Colonization of Roots of Rhizophora mangle by the Wood Boring Isopod Sphaeroma terebrans as a Mechanism to Increase Root Density

Abstract. The frequency of parasitism of free ending prop roots of the red mangrove, Rhizophora mangle, by the wood boring isopod Sphaeroma terebrans, increased with increasing distance of the endings to established roots. In a field experiment, in which isolated endings were, surrounded by wooden sticks, the endings were colonized by S. terebrans at a lower rate than control endings, thus indicating that the wooden structures in the vicinity of the ending tended to reduce colonization rate by S. terebrans. It is concluded that S. terebrans may cause mangrove root density to increase by colonizing peripheral endings more readily than endings which are near established roots.     

Die Rheingrabenrandverwerfung im Wattkopftunnel bei Ettlingen (Nordschwarzwald)

The Wattkopftunnel, near Ettlingen (Nordschwarzwald), drives through the eastern margin of the Rheingraben. The tunnel passes cenozoic and mesozoic sediments. Early quarternary and tertiary beds are situated west of the main thrust of the Rheingraben. Fossil record indicates upper Oligocene age (Chatt) for parts of the tertiary sediments. At the eastern border of the Rheingraben, wedges of jurassic and middle triassic series are squeezed. East of the Rheingraben the tunnel drives in the lower triassic Bausandstein. The eastern margin of the Rheingraben was investigated in detail during tunneling. Faults of the Rheingraben margin are distributed in an 130 meter wide fault zone in the tunnel. Total stratigraphic separation by the normal faults reaches more than 2 000 meters. The cenozoic sequence suffered synsedimentary to early diagenetic deformation, while the mesozoic series are characterized by ruptural deformation. The fault- and joint system is directed in the rheinische Richtung (SSW-NNE). East of the Rheingraben a second direction occur, running parallel to the lower Albtal (W-E).

     

Site occupation and electric field gradient in acentric neptunite-measurements and evaluations concerning powder- and single crystal – Mössbauer spectroscopy and x-ray diffractometry

Mössbauer measurements on neptunite (KNa₂Li(Fe,Mn,Mg)₂Ti₂Si₈O₂₄) at 400?K reveal the distribution of Fe-ions on the crystallographic sites in agreement with neutron diffraction results published elsewhere. Even the previously postulated small amount of Fe-ions on the Ti(2) site has been detected, combined with a charge transfer which is in agreement with optical absorption investigations by other authors. A qualitative site occupation model is able to explain the different features of our observations. Single crystal Mössbauer measurements with the k-vector of incident γ-rays parallel to the crystallographic b-axis (space group Cc) of neptunite at different temperatures yield the angle β between the main component of the electric field gradient (EFG), V _zz and b. This angle is in close accordance with a calculated value of β for the Fe(1) position from electron density maps. The latter also reveal an absolute value of V _zz which is in satisfactory agreement with V _zz derived from Mössbauer spectroscopy.