The capacity of marine plankton, macrophytes and particulate matter to adsorb Cu in the presence of Mg

A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu²⁺. Measured adsorption capacities were 0.22 meq g⁻¹ for phytoplankton, 0.3–1.0 meq g⁻¹ for macrophytes, 1.0–2.5 meq g⁻¹ for zooplankton and 0.3 meq g⁻¹ for suspended particulate matter. The capacity of these materials to adsorb Cu²⁺ was reduced significantly in the presence of Mg²⁺ at seawater concentrations. Competition between Mg^t2+ and Cu²⁺ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 10^3.7. This constant is such that very little Cu²⁺ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg²⁺. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.     

The shedding of mesoscale anticyclonic eddies from the Alaskan Stream and westward transport of warm water

The south-flowing waters of the Kamchatka and Oyashio Currents and west-flowing waters of the Alaskan Stream are key components of the western sub-Arctic Pacific circulation. We use CTD data, Argo buoys, WOCE surface drifters, and satellite-derived sea-level observations to investigate the structure and interannual changes in this system that arise from interactions among anticyclonic eddies and the mean flow. Variability in the temperature of the upstream Oyashio and Kamchatka Currents is evident by warming in mesothermal layer in 1994–2005 compared to 1990–1991. A major fraction of the water in these currents is derived directly from the Alaskan Stream. The stream also sheds large anticyclonic (Aleutian) eddies, averaging approximately 300 km in diameter with a volume transport significant in comparison with that of the Kamchatka Current itself. These eddies enclose pools of relatively warm and saline water whose temperature is typically 4 °C warmer and salinity is 0.4 greater than that of cold-core Kamchatka eddies in the same density range. Aleutian eddies drift at approximately 1.2 km d⁻¹ and retain their distinctive warm and salty characteristics for at least 2 years. Selected westward pathways during 1990–2004 are identified. If the shorter northern route is followed, Aleutian eddies remain close to the stream and persist sufficiently long to carry warm and saline water directly to the Kamchatka Current. This was observed during 1994–1997 with substantial warming of the waters in the Kamchatka Current and upstream Oyashio. If the eddies take a more southern route they detach from the stream but can still contribute significant quantities of warm and saline water to the upstream Oyashio, as in 2004–2005. However, the eddies following this southern route may dissipate before reaching the western boundary current region.     

The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.     

Effect of heat treatment on tourmaline from Brazil

The crystal-chemical behaviour of tourmaline from Araçuaí, Minas Gerais state, Brazil, when subjected to heating in air atmosphere has been studied by several techniques, including EMPA, UV–Vis, TGA, and Mössbauer spectroscopy. The tourmaline samples are typically intermediate members of the elbaite-schorl series. The origin of colour and of its change after treatment has been discussed in terms of local disorder, presence of metal transition elements, oxidation of ferrous iron at the octahedral site, and simultaneous trap of the excess electron. These findings may be used to enhance the colour in tourmaline crystals or generate wanted colour changes.     

How U.S. ocean policy and market power can reform the coral reef wildlife trade

As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.     

The agricultural utility of lithic-mulch gardens: Past and present

The mulching of agricultural fields and gardens with stones, pebbles, volcanic ash and similar lithic materials is a variant agricultural strategy uniquely suited to the constraints of a dryland environment. While the agricultural literature contains reports on limited experiments with stone or gravel mulch, data regarding the employment of lithic mulch are lacking. This paper works to bridge this gap by comparing empirical data collected from prehistoric pebble-mulch gardens in the Galisteo Basin (New Mexico) to contemporary agricultural experiments with lithic mulch. Such past-present and experimental-real world comparisons allow us to more fully address the effectiveness of lithic mulching as an agricultural strategy. It is affirmed that lithic mulch is applied to garden plots, especially during periods of drought, in order to reduce soil erosion from wind and water, increase soil temperature to extend the growing season, increase water infiltration, and reduce the evaporative loss of water from wind and sun. The cumulative effect of this soil and water conserving technique is an increase in crop biomass and crop yield.     

The sources and composition of mercury in Pacific Ocean rain

Here we report measurements of total Hg (Hg_T), reactive Hg (Hg_R), and methylmercury (MMHg) in precipitation from the equatorial Pacific Ocean, collected during a cruise in January and February 1990, and from a mid-continental location in the rural temperate lacustrine northcentral Wisconsin environs. The concentrations of Hg_T (14.4±6.5 pM), Hg_R (8.9±4.5 pM) and MMHg (<50 fM) found in equatorial Pacific rain were less than the average concentrations found in Wisconsin. In general, the results indicate that although particulate Hg is a small fraction of the total atmospheric Hg burden, it is the major contributor to Hg in precipitation. Furthermore, deposition could be an important source of Hg_R to the equatorial Pacific Ocean. In contrast, deposition is not a significant source of MMHg to either the equatorial Pacific Ocean or the remote seepage lakes of Wisconsin. This implies that methylated mercury is formedin situ in these systems.     

Multimodel analysis on the response of the AMOC under an increase of radiative forcing and its symmetrical reversal

Climate Dynamics - The response of the Atlantic meridional overturning circulation (AMOC) to an increase of radiative forcing (ramp-up) and a subsequent reversal of radiative forcing (ramp-down) is...     

Bromine cycle in subduction zones through in situ Br monitoring in diamond anvil cells

The geochemical partitioning of bromine between hydrous haplogranitic melts, initially enriched with respect to Br and aqueous fluids, has been continuously monitored in situ during decompression. Experiments were carried out in diamond anvil cells from 890 °C to room temperature and from 1.7 GPa to room pressure, typically from high P, T conditions corresponding to total miscibility (presence of a supercritical fluid). Br contents were measured in aqueous fluids, hydrous melts and supercritical fluids. Partition coefficients of bromine were characterized at pressure and temperature between fluids, hydrous melts and/or glasses, as appropriate: D^Br_fluid/melt = (Br)_fluid/(Br)_melt, ranges from 2.18 to 9.2 ± 0.5 for conditions within the ranges 0.66-1.7 GPa, 590-890 °C; and D^Br_fluid/glass = (Br)_fluid/(Br)_glass ranges from 60 to 375 at room conditions. The results suggest that because high pressure melts and fluids are capable of accepting high concentrations of bromine, this element may be efficiently removed from the slab to the mantle source of arc magmas. We show that Br may be highly concentrated in subduction zone magmas and strongly enriched in subduction-related volcanic gases, because its mobility is strongly correlated with that of water during magma degassing. Furthermore, our experimental results suggest that a non negligible part of Br present in the subducted slab may remain in the down-going slab, being transported toward the transition zone. This indicates that the Br cycle in subduction zones is in fact divided in two related but independent parts: (1) a shallower one where recycled Br may leave the slab with a water and silica-bearing “fluid” leading to enriched arc magmas that return Br to the atmosphere. (2) A deeper cycle where Br may be recycled back to the mantle maybe to the transition zone, where it may be present in high pressure water-rich metasomatic fluids.