H2 in interstellar and extragalactic ices: infrared characteristics, ultraviolet production, and implications

H2 is the most abundant molecule in the universe. We demonstrate that this molecule may be an important component of interstellar and possibly intergalactic ices, both because it can be formed in situ, within the ices, and because gas phase H2 can freeze out onto dust grains in some astrophysical environments. The condensation-sublimation and infrared spectral properties of ices containing H2 are presented. We show that solid H2 in H20-rich ices can be detected by an infrared absorption band at 4137 cm-1 (2.417 micrometers). The surface binding energy of H2 to H2O ice was measured to the delta Hs/k = 555 +/- 35 K. Surface binding energies can be used to calculate the residence times of H2 on grain surfaces as a function of temperature. Some of the implications of these results are considered.     

The condensation and vaporization behavior of ices containing SO2, H2S, and CO2: implications for Io

In an extension of previously reported work on ices containing CO, CO2, H2O, CH3OH, NH3, and H2, measurements of the physical and infrared spectral properties of ices containing molecules relevant to Jupiter's moon Io are presented. These include studies on ice systems containing SO2, H2S, and CO2. The condensation and sublimation behaviors of each ice system and surface binding energies of their components are discussed. The surface binding energies can be used to calculate the residence times of the molecules on a surface as a function of temperature and thus represent important parameters for any calculation that attempts to model the transport of these molecules on Io's surface. The derived values indicate that SO2 frosts on Io are likely to anneal rapidly, resulting in less fluffy, "glassy" ices and that H2S can be trapped in the SO2 ices of Io during night-time hours provided that SO2 deposition rates are on the order of 5 micrometers/hr or larger.     

西藏日喀则地区德村-昂仁蛇绿岩内基性岩的元素与Sr-Nd-Pb同位素地球化学及其揭示的特提斯地幔域特征

系统研究了西藏雅鲁藏布江蛇绿岩带中部日喀则地区德村、吉丁和昂仁蛇绿岩中基性岩石的元素与 Sr-Nd-Pb 同位素地球化学特征。这些基性岩石,包括玄武岩、辉长岩和辉绿岩,属于低钾拉斑玄武岩系列,球粒陨石标准化稀土元素分配模式为轻稀土元素亏损的 N-MORB 型,(La/Yh)_N=0.31～0.65(除样品 DC993为1.17)。在原始地幔标准化微量元素图上,亏损高度不相容元素,与 N-MORB 配分模式一致。相对于 Th,无 Nb、Ta的亏损,显示样品不是产于 SSZ 环境。经构造环境图解判别,样品落入了 N-MORB 区域内;这些元素成分特征表明样品具有洋中脊环境或成熟的弧后盆地环境属性。Sr、Nd 和 Pb同位素组成特征表明特提斯地幔源区以 DM(亏损地幔)为主,同时存在少量 EMⅡ(富集地幔类型Ⅱ)、Sr,Nd 和 Pb 同位素组成特征还表明特提斯地幔域具有印度洋 MORB 型的 Sr-Nd-Pb 同位素组成特征。本文的结果进一步支持 Zhang et al.(2005)的研究结果,现今印度洋不仅在地理位置上占据了曾经是特提斯洋的大部分,而且它的地幔域还继承了曾经特提斯的地幔域的地球化学特征。     

内蒙古温都尔庙和巴彦敖包-交其尔蛇绿岩的元素与同位素地球化学：对古亚洲洋东部地幔域特征的限制

内蒙古中部发育的三条蛇绿岩带是华北板块和西伯利亚板块之间的缝合带。本文系统研究了其中的温都尔庙和巴彦敖包-交其尔两个蛇绿岩带中变质玄武岩的元素和 Sr、Nd、Pb 同位素地球化学。苏右旗温都尔庙碱性玄武岩为轻稀土富集型;岩石具有板内和大陆裂谷区玄武岩的特征,可能代表了600Ma 左右,温都尔庙地区开始发育的新洋盆。采自苏左旗的巴彦敖包-交其尔玄武岩分为两类,一类呈现轻稀土富集型,呈洋岛玄武岩特征;另一类具有明显的 Nb、Ta 负异常,显示大洋岛弧玄武岩特征,洋岛玄武岩的存在表明古亚洲洋曾经发育洋盆,大洋岛弧玄武岩的存在表明古亚洲洋内部有大洋岩石圈之间的俯冲。将本文的古亚洲洋洋岛玄武岩与中国西南地区的特提斯洋岛玄武岩进行系统的元素和同位素地球化学特征对比表明,古亚洲洋的洋岛玄武岩显示高 U/Pb(HU)和北大西洋和太平洋省的特征,而特提斯洋岛玄武岩属于印度洋省。这些说明古亚洲洋地幔域与特提斯地幔域是两个独立的构造域,它们代表了长期演化的两个不同的地幔地球化学域。     

Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

The OSIRIS‐REx target asteroid (101955) Bennu: Constraints on its physical,geological, and dynamical nature from astronomical observations

We review the results of an extensive campaign to determine the physical, geological, and dynamical properties of asteroid (101955) Bennu. This investigation provides information on the orbit, shape, mass, rotation state, radar response, photometric, spectroscopic, thermal, regolith, and environmental properties of Bennu. We combine these data with cosmochemical and dynamical models to develop a hypothetical timeline for Bennu's formation and evolution. We infer that Bennu is an ancient object that has witnessed over 4.5 Gyr of solar system history. Its chemistry and mineralogy were established within the first 10 Myr of the solar system. It likely originated as a discrete asteroid in the inner Main Belt approximately 0.7–2 Gyr ago as a fragment from the catastrophic disruption of a large (approximately 100‐km), carbonaceous asteroid. It was delivered to near‐Earth space via a combination of Yarkovsky‐induced drift and interaction with giant‐planet resonances. During its journey, YORP processes and planetary close encounters modified Bennu's spin state, potentially reshaping and resurfacing the asteroid. We also review work on Bennu's future dynamical evolution and constrain its ultimate fate. It is one of the most Potentially Hazardous Asteroids with an approximately 1‐in‐2700 chance of impacting the Earth in the late 22nd century. It will most likely end its dynamical life by falling into the Sun. The highest probability for a planetary impact is with Venus, followed by the Earth. There is a chance that Bennu will be ejected from the inner solar system after a close encounter with Jupiter. OSIRIS‐REx will return samples from the surface of this intriguing asteroid in September 2023.     

Near-infrared laboratory spectra of solid H2O/CO2 and CH3OH/CO2 ice mixtures

We present near-IR spectra of solid CO₂ in H₂O and CH₃OH, and find they are significantly different from that of pure solid CO₂. Peaks not present in either pure H₂O or pure CO₂ spectra become evident when the two are mixed. First, the putative theoretically forbidden CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹), that is absent from our spectrum of pure solid CO₂, is prominent in the spectra of H₂O/CO₂=5 and 25 mixtures. Second, a 2.74-μm (3650 cm⁻¹) dangling OH feature of H₂O (and a potentially related peak at 1.89 μm) appear in the spectra of CO₂-H₂O ice mixtures, but are probably not diagnostic of the presence of CO₂. Other CO₂ peaks display shifts in position and increased width because of intermolecular interactions with H₂O. Warming causes some peak positions and profiles in the spectrum of a H₂O/CO₂=5 mixture to take on the appearance of pure CO₂. Absolute strengths for absorptions of CO₂ in solid H₂O are estimated. Similar results are observed for CO₂ in solid CH₃OH. Since the CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹) is not present in pure CO₂ but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO₂ is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.     

The mid-infrared transmission spectra of Antarctic ureilites

Abstract— The mid-infrared (4000–450 cm^?1; 2.5–22.2 μm) transmission spectra of seven Antarctic ureilites and 10 Antarctic H-5 ordinary chondrites are presented. The ureilite spectra show a number of absorption bands, the strongest of which is a wide, complex feature centered near 1000 cm^?1 (10 μm) due to Si-O stretching vibrations in silicates. The profiles and positions of the substructure in this feature indicate that Mg-rich olivines and pyroxenes are the main silicates responsible. The relative abundances of these two minerals, as inferred from the spectra, show substantial variation from meteorite to meteorite, but generally indicate olivine is the most abundant (olivine:pyroxene = 60:40 to 95:5). Both the predominance of olivine and the variable olivine-to-pyroxene ratio are consistent with the known composition and heterogeneity of ureilites. The H-5 ordinary chondrites spanned a range of weathering classes and were used to provide a means of addressing the extent to which the ureilite spectra may have been altered by weathering processes. It was found that, while weathering of these meteorites produces some weak bands due to the formation of small amounts of carbonates and hydrates, the profile of the main silicate feature has been little affected by Antarctic exposure in the meteorites studied here. The mid-infrared ureilite spectra provide an additional means of testing potential asteroidal parent bodies for the ureilites. At present, the best candidates include the subset of S-type asteroids having low albedos and weak absorption features in the near infrared.