Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Oxidation of pyrite during extraction of carbonate associated sulfate

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.     

中朝地台东北缘地区的地震层析成像

根据中朝地台东北缘地区 (东经 1 1 7°0 0′— 1 2 6°0 0′ ,北纬 36°0 0′— 44°0 0′) 1 980— 1 997年的 380 0 0余条P波走时数据 ,利用正交投影法重建了该区地壳和上地幔的三维速度结构 .通过分析及同人工地震测深剖面的详细对比 ,证明了成像结果的可靠性 .结果表明 :中朝地台东北缘地区地壳上地幔介质存在显著的横向不均匀性 ,直至 1 2 0km深度处依然明显 ;地壳上部的速度图像清楚地反映了不同岩石单元的分布与该区不同性质的基岩分布基本吻合 ;从上、中地壳的速度图像中发现了研究区存在海城、朝阳、义县、丹东南、唐山等几个低速异常区(即速度逆反层区 ) ,其中海城、唐山、朝阳等地区的壳内低速层已由深地震测深资料所证实 ;研究区陆地发生的几次强震均发生于壳内低速层上方的高速脆性介质内 ,而渤海发生的强震 ,此现象不明显 ,但都发生于横向介质速度显著突变的位置 ;在地壳不同深度上发现了普兰店至山海关横跨渤海的北西向低速异常带 ;地震层析二维速度图像与深地震测深资料的对比表明 ,研究区利用地震层析成像技术 ,在一定条件下可以获得与人工地震测深相似的效果     

Determination of Gold in Twenty Geochemical Reference Samples by Flameless Atomic Absorption Spectrometry

After acid digestion, gold is extracted with MIBK and determinated by flameless atomic absorption spectrometry. The results for six USGS reference samples and fourteen French geochemical standards are presented and discussed. The agreement with working values for these standards is in the range of pm 5%.     

A ternary solid solution model for omphacite and its application to geothermobarometry of eclogites from the Middle Adula nappe (Central Alps, Switzerland)

A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi₂O₆), diopside (CaMgSi₂O₆) and hedenbergite (CaFeSi₂O₆) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H₂O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21  kbar, c .  700 °C).     

GEOLOGY OF NORTHERN CHIHLI AND EASTERN MONGOLIA.

During the last spring (April-May 1924), we have, F. Licent and I crossed the Northern Chihli and the eastern part of the Inner Mongolia.