Constraints from Moho geometry and crustal thickness on the geodynamic origin of the Vrancea Seismogenic Zone (Romania)

Reprocessing of industry deep seismic reflection data (Ramnicu Sarat and Braila profiles) from the SE Carpathian foreland of Romania provides important new constraints on geodynamic models for the origin of the intermediate depth Vrancea Seismogenic Zone (VSZ). Mantle (70–200 km) earthquakes of the VSZ are characterized by high magnitudes (greater than 6.5), frequent occurrence rates (approximately 25 years), and confinement in a very narrow (30 × 70 × 200 km³) near vertical zone atypical for a Wadati–Benioff plane, located in front of the orogen. These two deep (20 s) seismic reflection profiles (70 km length across the foreland) reveal (1) a high-amplitude, gently east-dipping reflection across most of the section from what we interpret to be the Moho at  15 s (40–42 km) on the Ramnicu Sarat line to  16 s (47–48 km) on the Braila line, (2) a thick sedimentary cover increasing in thickness from east (1 s;  800 m) to west (7.5 s; 14 km), (3) an eastward increase in crustal thickness from 38 km (near VSZ) to  45 km, (4) seismic and topographic evidence for a newly imaged, possibly seismically active basement fault with a surface offset of 30 m observed on the Ramnicu Sarat line, (5) a lack of notable west-dipping structures in the crust and across the Moho, and (6) variable displacements on Peceneaga–Camena Fault of  5 km at Moho and  200 m at the basement–sedimentary cover contact.These observations appear to argue against recent models for west-dipping subduction of oceanic lithosphere at or in the vicinity of the Vrancea Seismogenic Zone given the lack of west-dipping fabrics in the lower crust and across the crust–mantle boundary. Consequently, one possible explanation for the geodynamic origin of VSZ could be partial delamination of the continental lithosphere in an intra-plate setting along a sub-horizontal lithospheric interface in the Carpathian hinterland that likely involves remnant lithospheric coupling between the crust and uppermost mantle in the foreland.     

Retrieval of the boundary layer height from active and passive remote sensors. Comparison with a NWP model

In this study, we used boundary layer heights derived from lidar in Romania to validate the Weather Research Forecast (WRF) model improved by ARIA Technologies SA in the framework of ROMAIR LIFE project. Lidar retrievals were also compared to the retrievals from meteorological data, both modeled (Global Data Assimilation System; GDAS) and measured (microwave radiometry). Both the gradient and the wavelet covariance methods were used to compute the boundary layer height (BLH) from the range corrected lidar signal, and their equivalence was shown. The analysis was performed on 102 datasets, spread over all seasons and 3 years (2009–2011). A good agreement was found for the remote sensors (lidar and microwave radiometer) which are co-located and measure simultaneously. The correlation of the measured boundary layer height and the modelled one was 0.66 for the entire dataset, and 0.73 when considering daytime data, i.e., for a well defined boundary layer. A systematic underestimation of the boundary layer height by the WRF during non-convective periods (nocturne, stable atmosphere) was found.     

Petrophysical characterization of the South Georgia Rift Basin for supercritical CO2 storage: a preliminary assessment

The Triassic–Jurassic South Georgia Rift (SGR) Basin, buried beneath Coastal Plain sediments of southern South Carolina, southeastern Georgia, western Florida, and southern Alabama, consists of an assemblage of continental rift deposits (popularly called red beds), and mafic igneous rocks (basalt flows and diabase sills). The red beds are capped by basalts and/or diabase sills, and constitute the target for supercritical CO₂ storage as part of a Department of Energy funded project to study the feasibility for safe and permanent sequestration. The purpose of this research is to evaluate subsurface suitability for underground CO₂ storage in terms of the local and regional distribution of porous and permeable reservoirs. In addition, unlike shale-capped CO₂ reservoirs, very little is known about the ability of basalts and diabase sills to act as viable seals for CO₂ storage. New results demonstrate the presence of confined porous rocks that may be capable of storing significant quantities of supercritical CO₂. Reservoir thicknesses as high as 420 m and an average porosity as high as 14 % were obtained. The SGR Basin manifests distinct porosity–permeability regimes that are influenced by the depositional environments. These are: a high-porosity, medium/low-permeability zone associated with lacustrine deposits, a medium/low-porosity, low-permeability zone dominated by fluvial fine- to very fine-grained sandstone, and an extremely low porosity and permeability zone characterized by fluvial and alluvial-fan deposits. Analyses further show that the basalt flows and diabase sills are characterized by low porosity as well as high seismic velocities and densities that are favorable to caprock integrity.     

A framework for addressing health disparities in vulnerable populations with the help of Esri Community Analyst

Increasingly, health outcomes are tied to nutritional opportunities based on the availability of foods and cultural patterns of consumption. This paper demonstrates how Esri Community Analyst can help in identifying at-risk communities. The methodology that results argues a means by which national data made available by Esri in a “one-stop shop” can be utilized in a simplified, user-friendly way to identify specific populations with higher prevalence of certain diseases and areas where nutritional needs are likely unmet. For demonstration purposes, this paper presents a case study for South Carolina, USA.     

Crustal constraints on the origin of mantle seismicity in the Vrancea Zone, Romania: The case for active continental lithospheric delamination

The Vrancea zone of Romania constitutes one of the most active seismic zones in Europe, where intermediate-depth (70–200 km) earthquakes of magnitude in excess of M_w = 7.0 occur with relative frequency in a geographically restricted area within the 110° bend region of the southeastern Carpathian orogen. Geologically, the Vrancea zone is characterized by (a) a laterally restricted, steeply NW-dipping seismogenic volume (30 × 70 × 200 km), situated beneath (b) thickened continental crust within the highly arcuate bend region of the Carpathian orocline, and (c) miscorrelation of hypocenters with the position of known or inferred suture zones in the Carpathian orogenic system. Geologic data from petroleum exploration in the Eastern Carpathians, published palinspastic reconstructions, and reprocessing of industry seismic data from the Carpathian foreland indicate that (1) crust of continental affinity extends significantly westward beneath the external thrust nappes (Sub-Carpathian, Marginal Folds, and Tarcau) of the Eastern Carpathians, (2) Cretaceous to Miocene strata of continental affinity can be reconstructed westward to a position now occupied by the Transylvanian basin, and (3) geologic structure in the Carpathian foreland (including the Moho) is sub-horizontal directly to the east and above the Vrancea seismogenic zone. Taken together, these geologic relationships imply that the Vrancea zone occupies a region overlain by continental crust and upper mantle, and does not appear to originate from a subducted oceanic slab along the length of the Carpathian orogen. Accordingly, the Vrancea zone appears to potentially be an important place to establish evidence for active lithospheric delamination.     

A micro-XAS/XRF and thermodynamic study of Ce speciation after long-term aqueous alteration of simulated nuclear waste glass: Relevance for predicting Pu behavior?

In the present study, the dissolution and mobilization of Ce introduced in a simulated nuclear waste glass (MW) as a surrogate of Pu was investigated after leaching in pure water over 12 a at 90 °C and pH ∼ 9.6. The microscopic distribution and oxidation state of Ce in the altered glass were studied using micro-X-ray fluorescence (micro-XRF) mapping techniques and micro-X-ray near-edge absorption spectroscopy (micro-XANES). Distribution maps of Ce^III and Ce^IV were obtained by recording the L_α fluorescence emission at two different incident X-ray energies, coinciding with the maximum contrast between Ce^III and Ce^IV fluorescence intensities. The micro-XRF maps revealed that Ce was dominantly present as oxidized species (Ce^IV) in the original glass. After dissolution from the glass matrix, Ce^IV was partly reduced and re-immobilized as Ce^III at grain boundaries or in the interstitial spaces between the glass particles. The concentration of Ce^III was found to correlate with the spatial distribution of secondary Mg-clay formed during the aqueous corrosion as the main glass alteration product. Micro-XANES spectra collected at locations representative of both altered and non-altered glass domains confirmed the findings obtained by the redox mapping. Because redox-sensitive elements in the pristine MW glass (Fe, Cr, Se) occur almost exclusively as oxidized species, reduction of Ce^IV was probably mediated by an external source of reductants, such as Fe(0) from the steel reaction vessel.     

Optimal filtering high-resolution seismic reflection data using a weighted-mode empirical mode decomposition operator

Gas-hydrate related processes in deep-water marine settings exist on spatial scales that challenge conventional seismic reflection profiling to successfully image them. The conventional approach to acoustic identification of buried hydrates is to use advanced, cost-prohibitive survey techniques and highly customized software to define subsurface structure wherein compositional changes may be modeled and/or interpreted. This study adopts a different approach derived from recent theoretical advancements in signal processing. The method consists in optimal filtering high resolution, single-channel seismic reflection data using the Empirical Mode Decomposition (EMD). The time series is decomposed in sub-components and the noisy portions are suppressed adopting the technique that we referred as Weighted Mode(s) EMD. The optimal filtering greatly improves the resolution and fidelity of the seismic data set.High Resolution single channel seismic profiles, acquired over a carbonate\hydrates site in the northern Gulf of Mexico, manipulated in such way, show a complex, shallow subsurface, and suggest potential evidence for buried gas hydrates.     

Optical properties of long-range transported volcanic ash over Romania and Poland during Eyjafjallajökull eruption in 2010

After Eyjafjallajökull volcano eruption on 14 April 2010, due to a complex air mass circulation, Romania was exposed to volcanic ash and its mixture with continental aerosols. Ash particles with an average Ångström (UV-VIS) exponent of 1.4 ± 0.2 and (VIS-IR) of 1.2 ± 0.3, a color ratio (VIS-UV) of 0.54 and (IR-VIS) of 0.49, an average particle depolarization value ～9.4%, and a lidar ratio of 50 sr were retrieved on 18 April from multiwavelength Raman lidar measurements in Bucharest. Mixed volcanic ash with mineral dust particles advected from Sahara, depolarization ～12%, Ångström (UV-VIS) exponent of 1.25 ± 0.25 and (VIS-IR) of 1.45 ± 0.25, an increased color ratio (VIS-UV) of 0.61, (IRVIS) of 0.39 and lidar ratio of 53 sr were identified on 28 April. From observations in Poland conducted by an elastic lidar at 532 nm and a ceilometer at 1064 nm we retrieved an average backscatter related Ångström (VIS-IR) exponent of 1.25 ± 0.35, and a color ratio (IR-VIS) of 0.53 in the layer at about 5.5 km during the night of 16/17 April, indicating fresh ash over Warsaw.