Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.     

The Nippon/Norway Svalbard Meteor Radar: First results of small-scale structure observations

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The impact of submersed aquatic vegetation on the development of river mouth bars

This work is inspired by the sudden resurgence of the submersed aquatic vegetation (SAV) bed in the Chesapeake Bay (USA). Because the SAV bed occurs at the mouth of the Bay's main tributary (Susquehanna River), it plays a significant role in modulating sediment and nutrient inputs from the Susquehanna to the Bay. Previous model studies on the impact of submersed aquatic vegetation on the development of river mouth bars lacked a complete mechanistic understanding. This study takes advantage of new advances in 3D computational models that include explicit physical-sedimentological feedbacks to obtain this understanding. Specifically, we used Delft3D, a state-of-the-art hydrodynamic model that provides fine-scale computations of three-dimensional flow velocity and bed shear stress, which can be linked to sediment deposition and erosion. Vegetation is modeled using a parameterization of hydraulic roughness that depends on vegetation height, stem density, diameter, and drag coefficient. We evaluate the hydrodynamics, bed shear stresses, and sediment dynamics for different vegetation scenarios under conditions of low and high river discharge. Model runs vary the vegetation height, density, river discharge, and suspended-sediment concentration. Numerical results from the idealized model show that dense SAV on river mouth bars substantially diverts river discharge into adjacent channels and promotes sediment deposition at ridge margins, as well as upstream bar migration. Increasing vegetation height and density forms sandier bars closer to the river mouth and alteration of the bar shape. Thus, this study highlights the important role of SAV in shaping estuarine geomorphology, which is especially relevant for coastal management. © 2019 John Wiley & Sons, Ltd.     

Sediment Accumulation Rates and Submersed Aquatic Vegetation (SAV) Distributions in the Mesohaline Chesapeake Bay, USA

This study assesses spatial and temporal sedimentological trends in four mesohaline Chesapeake Bay submersed aquatic vegetation (SAV) habitats, two with persistent SAV beds and two with ephemeral SAV beds, to determine their relationship to current and historical sediment characteristics??grain size, organic content, and accumulation rates. In general, grain size is similar among all sites, and subsurface sediment differs from surficial sediment only at one site where a thin surficial sand layer (??2?C3?cm) is present. This thin sand layer is not completely preserved in the longer-term sedimentary record even though it is critical to determining whether the sediment is suitable for SAV. Evidence for nearshore fining, similar to that observed in the deeper waters of the Bay, is present at the site where the shoreline has been hardened suggesting that locations with hardened shorelines limit exchange of coarser (sandy) material between the shore and nearshore environments. Whether the fining trend will continue to a point at which the sediment will become unsuitable for SAV in the future or whether some new type of equilibrium will be reached cannot be addressed with our data. Instead, our data suggest that SAV presence/absence is related to changes in sedimentary characteristics??persistent beds have relatively steady sediment composition, while ephemeral beds have finer sediments due to reduced sand input. Additionally, sediment accumulation rates in the persistent beds are ??9?mm/year, whereas rates in the ephemeral beds are ??3?mm/year. Thus, the ephemeral sites highlight two potential sedimentary controls on SAV distribution: the presence of a sufficiently thick surficial sand layer as previously postulated by Wicks (2005) and accumulation rates high enough to bury seeds prior to germination and/or keep up with sea-level rise.     

白云鄂博碳酸岩的方解石-白云石地质温度计

利用方解石-白云石地质温度计对白云鄂博地区碳酸岩的平衡温度进行了测定。出露于东矿下盘的白云岩质火山岩和出露于尖山的方解石-白云石型火山岩获得了较高的温度,分别为681℃和648℃。这些样品中的方解石呈二十微米左右晶形较完整的小片,被稍大粒度的白云石颗粒包裹,未受交代作用影响,推测这种碳酸岩在快速冷却的情况下保存下了其岩浆侵位时的成分特点,从而指示出接近碳酸岩浆侵位时的温度。但本区多数碳酸岩的平衡温度在400～500℃之间,有下列三种情况:(1)具有自形-半自形中粗粒粒状变晶结构的碳酸岩最后的平衡温度为415～496℃;(2)产自东矿的其余样品(火山岩),所测最后平衡温度为431～485℃,在测温的微区范围内可见极细粒白云石方解石与稀土等矿物共生的现象;(3)为交代重结晶结构的碳酸岩明显受到后期热液流体的交代,在流体的作用下共生方解石和白云石在成分上达到新的平衡,平衡温度为432～507℃。本文所分析的样品多数结果(371～507℃)与用白云石(方解石)和磁铁矿氧同位素温度计对白云鄂博碳酸岩的计算结果(360～546℃)十分一致。虽然有研究者对方解石-白云石温度计用于火成碳酸岩表示过质疑,但本文资料表明火成碳酸岩最后的平衡温度是可以运用方解石-白云石温度计法来计算的。     

Clinoform mechanics in the Gulf of Papua, New Guinea

The largest islands of the Indo-Pacific Archipelago are estimated to account for 20–25% of the global sediment discharge to the ocean, and much (>50%) of this sediment is supplied to wide (>150 km) continental shelves. These conditions are conducive to creation of large-scale morphologic features known as clinoforms—sigmoidal-shaped deposits on the continental shelf. The Gulf of Papua (GOP) receives 3.84 ×10⁸ tons of sediment annually from three principal sediment suppliers, the Fly, Kikori and Purari Rivers, and its prograding clinoform is the focus of this study. During three research cruises, 80 cores and 37 CTD/optical backscatter casts were collected, and an instrumented tripod was deployed twice. Sedimentological and radiochemical results indicate that the GOP clinoform has characteristics similar to those seaward of other major rivers (e.g., Amazon, Ganges–Brahmaputra), specifically sand/mud interbedding on the topset, rapidly accumulating muds on the foreset, and siliciclastic mud mixed with carbonate sand on the bottomset.Using core data and field observations, the mechanics of clinoform progradation are examined. Discrete, large sedimentation events are identified as processes building the clinoform feature. X-radiographs from foreset cores reveal thick beds (>5 cm) between bioturbated sections. Detailed ²¹⁰Pb and grain-size data indicate that low activities and increased clay contents are associated with these beds. They are hypothesized to be formed by fluid–mud deposition in response to periods of large wave-tide bed shear stresses, more likely during the SE-tradewind season, and their regular occurrence produces high rates of mean accumulation (4 cm/y). Bed preservation is determined by the rates of sediment accumulation and bioturbation.To assess the influence of physical oceanographic factors on clinoform shape, bottom shear stresses from tides and surface waves were calculated using available wave and tripod data. This effort reveals that the depth range (25–40 m) of the clinoform rollover point (seaward edge of the topset region) is roughly consistent with the sediment-transport regime. Furthermore, calculations corroborate the core data that suggest possible seasonal sediment storage in the inner topset region (<15-m water depth, during the NW-monsoon winds) with subsequent transfer to foreset beds (more probable during SE-tradewind conditions).A 100-yr sediment budget created with accumulation rate data suggests approximately 20% of the total sediment supplied to the GOP accumulates on the clinoform (creating the clinoform morphology). Less than 5% is believed to escape to the adjacent slope, and much of the remaining 75% is likely trapped on the inner-topset region (<20 m water depth) and within the mangrove forests and flood/delta plains of the northern GOP.     

安徽巢湖凤凰山剖面石炭系微相和层序地层特征

应用露头层序地层学基本原理和方法 ,对巢湖凤凰山石炭系剖面进行重新研究。巢湖凤凰山石炭系总厚度为79.0 2 m ,在这个剖面中可以识别出 6种主要岩相、18种微相和 11个三级沉积层序 ,其中六个三级沉积层序属于 I型沉积层序 ,三个属于 II型沉积层序 ,缺失第 9和第 10沉积层序。三级沉积层序在不同的古地理单元和不同的沉积环境中可以进行对比。根据各微相特征和成因 ,揭示了沉积间断面上存在的多期古岩溶现象。阐述了三级层序及其对应的三级海平面升降旋回的特征     

亚得里亚海Po陆架上的现代沉积

在地质年代中,陆缘海是主要的沉积环境,其活跃的沉积作用形成了大量地层保存于古沉积岩中。为了准确解释古地层形成过程与事件,对现代沉积过程（本文定义〈100a）的深刻理解至关重要,因此,对亚得里亚海沉积作用的研究是一次非常有益的探索。     

Seasonal-Scale and Decadal-Scale Sediment-Vegetation Interactions on the Subaqueous Susquehanna River Delta,Upper Chesapeake Bay

Submersed aquatic vegetation (SAV) have been a prominent feature on the Susquehanna Flats, the shallow, subaqueous delta of the Susquehanna River, Maryland. SAV were absent from the Flats between 1972 and 2000, but have since recovered. While it is well established that SAV can improve water quality by promoting sediment and nutrient retention, it is not well understood how SAV on the Flats modulate sediment input from the Susquehanna River into the Upper Chesapeake Bay over different timescales. This study evaluates sedimentation on the Flats over seasonal to decadal timescales, using naturally occurring radioisotopes (⁷Be, ²¹⁰Pb) within the context of SAV biomass and Flats geomorphology. Results indicate that sedimentation on the Flats is both spatially and temporally variable. Although this variability cannot be explained by relationships with grain size and SAV biomass, river discharge, sediment supply, and geometry over the SAV bed likely control sedimentation in this system. Decadal-scale sedimentation is influenced by both flood events and changes in SAV biomass abundance. Average annual sediment accumulation was higher when SAV were present than when SAV were absent. SAV bed area was strongly correlated with average annual accumulation rate. These results suggest that a positive feedback between SAV abundance and accumulation rate exists; however, sediment supply and transport pathways are also important factors.     

A Preliminary Sediment Budget for the Corsica River (MD): Improved Estimates of Nitrogen Burial and Implications for Restoration

The Corsica River, located on Maryland’s eastern shore, has been the site of restoration efforts targeting sediment and nutrient load reductions. Previous work has indicated that agricultural activities supply most of these materials; however, their dynamics and fate are largely unknown. To address these needs, bottom sediments have been collected and analyzed for their chemical and textural properties. Long-term (decadal) accumulation rates are determined with ²¹⁰Pb (half-life 22.3 years), verified with ¹³⁷Cs, and range from 0.18 to 0.84 g/cm²/year in the subtidal region and 0.3–1.89 g/cm²/year in the marshes. These estimates are compared with likely sediment sources to determine the direction of exchange with the adjacent estuary (Chester River), which is a subtributary of Chesapeake Bay, with the Chester River likely supplying 0.94 × 10³ t/year of sediment to the Corsica, ∼16% of the total sediment input. The radiochemical data are used to interpret profiles of grain size and nitrogen and to provide improved estimates of nitrogen burial. Comparison of the Corsica River to similar systems highlights the importance of marshes in trapping sediment and nutrient inputs from the watershed.